| 11 | Study on Laccase-Catalyzed Oxidation of Disubstituted Ferrocene and π-arene-π- cyclopentadienyliron Derivatives显示文摘It is studied that Rhus vernicifera laccase cata ly zed oxidation of 26 disubstituted ferrocene and its metal complexes, π-arene- π-cyclopentadienyli ron derivatives and metal meso-(tetra-4-sulfanatophenyl)porphyrin in the di ethylene glycol monobutyl ether (DGBE)/phosphate buffer (V/V,1/5).It is foun d th at 1,1’-bishydroxylmethy1 ferrocene etc 16 compounds are new substrates of lacc ase. The relation of structure and function of substrates is discussed. T he affective factors of laccase-catalyzed oxidation of 1,1’-bishydroxylmethyl ferrocene——pH, temperature, substrate concentration, laccase quantity and surf actant were investigated further. | Ji Li-cai1, Hu Pei-zhi2, Jin Chang-hua3 , Ding Zi-rong2 1. College of Adult Education, Wuhan University, Wuhan 430072, China 2. Col lege of Chemistry and Environment Science, Wuhan University, Wuhan 430072, C hina 3,Yiping Plant of Chemistry and Industry at Zhong Qing City, Zhong Qing 631323, China | 2000 | Wuhan University Journal of Natural Sciences2000，5，3： | 0 |
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