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您的检索式：作者名="Pui Ching Lan"
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| 1 | In Situ Formation of Frustrated Lewis Pairs in a Zirconium Metal-Organic Cage for Sustainable CO_(2)Chemical Fixation显示文摘Sustainable CO_(2)fixation represents a facile and promising approach to constructing various valueadded chemicals.Herein,we contribute a robust metal-organic cage(MOC),denoted as TCPB-1,comprising a bulky Lewis acid functionalized linker,which can in situ form frustrated Lewis pairs(FLPs)upon the addition of Lewis basic substrates to efficiently drive CO_(2)transformation.Significantly,the incorporation of Lewis acidic boron sites within TCPB-1 promotes the efficient CO_(2)conversion to potentially medicinal benzimidazole derivatives via an FLPmediated pathway,and boosts the stability/durability of the FLP catalyst.In addition,the underlying catalysis mechanism has been established by combined experimental and molecular simulation studies.This work not only advances FLP/MOC as a new type of highly efficient catalyst for CO_(2)chemical fixation,but also opens a new avenue to design heterogeneous FLP-based catalysts for small molecule activation and beyond. | Cheng-Xia Chen Hassan Rabaâ Haiping Wang Pui Ching Lan Yang-Yang Xiong Zhang-Wen Wei Abdullah M.Al-Enizi Ayman Nafady Shengqian Ma | 2023 | CCS Chemistry2023，5，9： | 0 |
| 2 | Beyond confined catalysis in porous materials显示文摘The assembly of active species into porous material has been extensively investigated in the past decades [1].Especially with the utilization of MetalOrganic Frameworks (MOFs), the techniques of encapsulating active species have been widely explored, which is beneficial to the unique aspects of MOFs,like tunable porosity, high capacity, open active sites and crystallinity nature, etc. | Xiaoliang Wang Pui Ching Lan Sai Wang Shengqian Ma | 2020 | National Science Review2020，7，6： | 0 |
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