| 8 | Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution显示文摘A new series of polymers comprising four terpolymers was synthesized via Mannich polycondensation of benzene1,4diamine,formaldehyde and piperazine by varying the benzene1,4diamine and piperazine ratio.The new polyamines(labeled Dipip)were characterized using 13C solidstate NMR,FTIR,TGA,DSC,XRD,SEM and EDX.The adsorptive performances of the synthesized polymers for Erichrome Black T(EBT)uptake from aqueous solution were investigated under batch process.Equilibrium,kinetic,and thermodynamic studies were conducted to determine the influence of different operational parameters of the adsorption process.The two most promising polymers among the series show an excellent EBT removal efficiency of~100%and~95%with high adsorption capacities of 775 mgg 1 and 917 mgg 1,respectively at a meager dosage of 5 mg.The sorption of EBT on the polymers was well described by RedlichPeterson&Langmuir model while the kinetic studies indicate that pseudosecond order model was followed.For the thermodynamic studies,the negative AG and positive AH values obtained suggest a spontaneity of the sorption process which was endothermic in nature.The results of reusability test of the resins were promising even at the fourth cycle,showcasing the potentials of the new polymers in dyes contaminated water treatment. | Mohammad Saood Manzar Shamsuddeen A.Haladu Mukarram Zubair Nuhu Dalhat Mu’azu Aleem Qureshi Nawaf I.Blaisi Thomas FGarrison Othman Charles S.Al Hamouz | 2021 | Chinese Journal of Chemical Engineering2021，34，4： | 0 |
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