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1篇 您的检索式:作者名="Roberta Properzi"
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1Visible-light-driven intramolecular xanthylation of remote unactivated C(sp^(3))-H bonds显示文摘Visible light-mediated site-specific C(sp^(3))-H xanthylation of amides has been accomplished using N-xanthylamides.The N-centered radicals generated by light initiation of N-xanthylamide substrates undergo 1,5-hydrogen atom transfer to form benzylic or alkyl radical intermediates under metal-and catalyst-free conditions.This method exhibits a broad substrate scope,high functional group tolerance,and high regioselectivity.Furthermore,this strategy provides straightforward access to a range of derivatives through the subsequent elaboration of the xanthate group.Hang Chen Yang Zhou Panpan Lei Haifeng Wang Qiongjiao Yan Roberta Properzi Wei Wang Linhai Jing Fener Chen 2023Green Synthesis and Catalysis2023,4,4:0
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