| 1 | Kinetic and products study of the gas-phase reaction of Lewisite with ozone under atmospheric conditions显示文摘The rate constant for the gas-phase reaction of O_3 and Lewisite was studied in air using the smog chamber technique. The experiments were carried out under pseudo-first-order reaction conditions with [O_3] [Lewisite]. The observed rate constant of O_3 with Lewisite was(7.83 ± 0.38) × 10^(-19)cm^3/(molecule·sec) at 298 ± 2 K. Lewisite was discussed in terms of reactivity with O_3 and its relationship with the ionization potential. Our results show that the rate constant for the gas-phase reaction of O_3 with Lewisite is in line with the trend of the rate constants of O_3 with haloalkenes. | Haitao Wang Yuanpeng Zhang Xiaodi Guo Yusheng Shao Runli Gao Dejian Liang Hao Sun | 2016 | Journal of Environmental Sciences2016，28，2： | 0 |
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