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| 1 | Comparative analysis of significant wave height between a new Southern Ocean buoy and satellite altimeter显示文摘中国于2019年第35次南极考察中,首次在南大洋布放了锚系实时综合观测浮标(西风带海洋环境监测浮标,WEMB),为深入了解此海区的海洋环境变化提供了宝贵资料.国家海洋技术中心WEMB研究团队基于AVISO公开发布的多颗卫星高度计L3产品,通过数据配对,误差统计和最小二乘线性拟合等方法,对西风带海洋环境监测浮标的有效波高数据误差进行了分析与校正.校正后的浮标有效波高统计显示西风带常年处于大浪以上海况,观测期间内57%处于巨浪海况,并且伴随有高度相关的大风天气. | Jianjun Kang Runyu Mao Yiting Chang Hongli Fu | 2021 | Atmospheric and Oceanic Science Letters2021，14，5： | 3 |
| 2 | A flexible design strategy to modify Ti3C2Tx MXene surface terminations via nucleophilic substitution for long-life Li-S batteries显示文摘MXene-based materials have gained considerable attention for lithium-sulfur(Li-S)batteries cathode materials due to their superior electric conductivity and high affinitive to polysulfides.However,there are still challenges in modifying the surface functional groups of MXene to further improve the electrochemical performance and increase the structure variety for MXene-based sulfur host.Herein,we report an efficient and flexible nucleophilic substitution(S_(N))strategy to modify the Ti_(3)C_(2)T_(x) surface terminations and purposefully designed Magnolol-modified Ti_(3)C_(2)T_(x)(M-Ti_(3)C_(2)T_(x))as powerful cathode host materials.Benefiting from more C-Ti-O bonds forming and diallyl groups terminations reducing after the dehalogenation and nucleophilic addition reactions,the given M-Ti_(3)C_(2)T_(x) electrode could effectively suppress the lithium polysulfides shuttling via chemisorption and C—S covalent bond formation.Besides,the Magnolol-modified Ti_(3)C_(2)T_(x) significantly accelerates polysulfide redox reaction and reduces the activation energy of Li_(2) S decomposition.As a result,the as-prepared M-Ti_(3)C_(2)T_(x) electrode displays an excellent rate capability and a high reversible capacity of 7.68 mAh cm^(-2)even under 7.2 mg cm^(-2)S-loaded with a low decay rate of 0.07%(from 2 nd cycle).This flexible surface-modified strategy for MXene terminations is expected to be extended to other diverse MXene applications. | Tianpeng Zhang Wenlong Shao Siyang Liu Zihui Song Runyue Mao Xin Jin Xigao Jian Fangyuan Hu | 2022 | Journal of Energy Chemistry2022，31，11： | 1 |
| 3 | MXenes for metal-ion and metal-sulfur batteries:Synthesis,properties,and electrochemistry显示文摘In 2011,a new class of 2D materials was discovered;after 2012,they began to be concerned;in 2017,the“gold rush”of the materials was triggered,and they are exactly MXenes.2D MXenes,a new class of transition metal carbides,carbonitrides and nitrides,have become the star and cutting-edge research materials in the field of emerging batteries systems due to their unique 2D structure,abundant surface chemistry,and excellent physical and electrochemical properties.This review focuses on the MXene materials and summarizes the recent advancements in the synthesis techniques and properties,in addition to a detailed discussion on the electrochemical energy storage applications,including alkali-ion(Li^(+),Na^(+),K^(+))storage,lithium-sulfur(Li–S)batteries,sodiumsulfur(Na–S)batteries,and metal anode protection.Special attentions are given to the elaborate design of nano-micro structures of MXenes for the various roles as electrodes,multifunctional components,S hosts,modified separators,and metal anode protective layers.The paper ends with a prospective summary of the promising research directions in terms of synthesis,structure,properties,analysis,and production on MXene materials. | Siyang Liu Zihui Song Xin Jin Runyue Mao Tianpeng Zhang Fangyuan Hu | 2022 | Materials Reports(Energy)2022，2，1： | 0 |
| 4 | Sulfur polymerization strategy based on the intrinsic properties of polymers for advanced binder-free and high-sulfur-content Li–S batteries显示文摘Lithium-sulfur(Li-S)batteries are the promising next-generation secondary energy storage systems,because of their advantages of high energy density and environmental friendliness.Among numerous cathode materials,organosulfur polymer materials have received extensive attentions because of their controllable structure and uniform sulfur distribution.However,the sulfur content of most organosulfur polymer cathodes is limited(S content<60%)due to the addition of large amounts of conductive agents and binders,which adversely affects the energy density of Li-S batteries.Herein,a hyperbranched sulfur-rich polymer based on modified polyethyleneimine(Ath-PEI)named carbon nanotubeentangled poly(allyl-terminated hyperbranched ethyleneimine-random-sulfur)(CNT/Ath-PEI@S)was prepared by sulfur polymerization and used as a Li-S battery cathode.The high intrinsic viscosity of Ath-PEI provided considerable adhesion and avoided the addition of PVDF binder,thereby increasing the sulfur content of cathodes to 75%.Moreover,considering the uniform distribution of elemental sulfur by the polymer,the utilization of sulfur was successfully improved,thus improving the rate capability and discharge capacity of the battery.The binder-free,sulfur-rich polymer cathode exhibited ultra-high initial discharge capacity(1520.7 mAh g^(−1) at 0.1 C),and high rate capability(804 mAh g^(−1) at 2.0 C).And cell-level calculations show that the electrode exhibits an initial capacity of 942.3 mAh g^(−1) electrode,which is much higher than those of conventional sulfur-polymer electrodes reported in the literature. | Zihui Song Tianpeng Zhang Siyang Liu Wenlong Shao Wanyuan Jiang Runyue Mao Xigao Jian Fangyuan Hu | 2023 | SusMat2023，3，1： | 0 |
| 5 | A semi-immobilized sulfur-rich copolymer backbone with conciliatory polymer skeleton and conductive substrates for high-performance Li-S batteries显示文摘Sulfur-rich polymers have gained a great deal of attention as the next-generation active materials in lithium-sulfur(Li-S)batteries due to their low cost,environmental compatibility,naturally sulfur uniform dispersion,and distinctive structure covalently bonding with sulfur atoms.However,the poor electrical conductivity and undesirable additional shuttle effect still hinder the commercial application of sulfur-rich polymers.Herein,we report a flexible semi-immobilization strategy to prepare allylterminated hyperbranched poly(ethyleneimine)-functionalized reduced graphene oxide(A-PEI-EGO)as sulfur-rich copolymer backbone.The semi-immobilization strategy can effectively reconcile the demand for polymer skeleton and conductive substrates through forming quaternary ammonium groups and reducing oxygen-containing functional groups,resulting in enhanced skeleton adsorption capacity and substrate electronic conductivity,respectively.Furthermore,the stable covalent bonding connection based on polymer molecules(A-PEI)not only completely prevents the additional shuttle effect of lithiation organic molecules and even sulfur-rich oligomers,but provides more inverse vulcanization active sites.As a result,the as-prepared A-PEI-EGO-S cathodes display an initial discharge capacity of1338 m A h g^(-1)at a rate of 0.1 C and an outstanding cycling stability of 0.046%capacity decay per cycle over 600 cycles.Even under 6.2 mg cm^(-2)S-loaded and sparing electrolyte of 6μL mg^(-1),the A-PEI-EGO-S cathode can also achieve a superior cycling performance of 98%capacity retention after 60 cycles,confirming its application potential. | Tianpeng Zhang Zihui Song Jinfeng Zhang Wanyuan Jiang Runyue Mao Borui Li Siyang Liu Xigao Jian Fangyuan Hu | 2023 | Journal of Energy Chemistry2023，，6： | 0 |
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