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| 1 | One-pot synthesis of the highly efficient bifunctional Ni-SAPO-11 catalyst显示文摘Hydro isomerization of linear alkanes to branched isomers is an important petrochemical process for production of gasoline with high octane number.Non-noble metal bifunctional catalysts used in this process always suffer from low metal dispersion and poor metal-acid synergy.Herein,a facile one-pot synthesis method was used to simultaneously regulate metal particle sizes and acidity of the Ni-SAPO-11 hydroisomerization catalyst.The physicochemical properties are investigated using XANES,EXAFS,TEM/STEM,FT-IR,XPS,UV-vis and NH_3-TPD.Apart from the highly dispersed nickel nanoparticles with an average diameter of 8 nm,the framework Ni~(2+)ions are generated via substituting framework Al~(3+)ions of the SAPO-11.The formed NiP-OH structures have lower deprotonation energy(DPE)than the SiAl-OH ones,contributing more and stronger acid sites to the Ni-SAPO-11 catalyst.The great metal-acid synergy including high metal to acid sites ratio(n_(Ni)/n_A)and close intimacy is obtained for the Ni-SAPO-11 catalyst.The Ni-SAPO-11 catalyst outperforms the counterpart prepared by the impregnation method and exhibits comparable activity and isomers selectivity to the Pt/SAPO-11 catalyst in the n-hexane hydroisomerization. | Yuchao Lyu Weilong Zhan Zhumo Yu Xinmei Liu Ye Yang Xiaoxing Wang Chunshan Song Zifeng Yan | 2021 | Journal of Materials Science & Technology2021，，17： | 4 |
| 2 | An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel显示文摘 | Chunshan Song | 2003 | Catalysis Today2003，，1： | 3 |
| 3 | CO2 capture over molecular basket sorbents:Effects of SiO2 supports and PEG additive显示文摘The objective of this work is to study the influences of silica supports and PEG additive on the sorption performance of molecular basket sorbent(MBS) for CO_2 capture consisting of polyethylenimine and one of the following supports: SBA-15(2-D structure), TUD-1(3-D sponge-like structure) and fumed silica HS-5(3-D disordered structure). Effects of the supports regarding pore structures and pore properties, the PEI loading amount as well as the sorption temperature were examined. Furthermore, polyethylene glycol(PEG) was introduced as an additive into the sorbents and its effect was investigated at different PEI loadings and sorption temperatures. The results suggest that the pore properties of MBS(after PEI loading) play a more important role in the CO_2 sorption capacity, rather than those of the supports alone.MBS with 3D pore structure exhibits higher CO_2 sorption capacity and amine efficiency than those with 2D-structured support. Among the sorbents studied, fumed silica(HS-5) based MBS showed the highest CO_2 sorption capacity in the temperature range of 30-95 °C, probably due to its unique interstitial pores formed by the aggregation of polymer-loaded SiO_2 particles. It was found that the temperature dependence is directly related to the PEI surface coverage layers. The more PEI surface coverage layers, the higher diffusion barrier for CO_2 and the stronger temperature dependence of CO_2 capacity. 3D MBS exceeds 2D MBS at the same PEI coverage layers due to lower diffusion barrier. Adding PEG can significantly enhance the CO_2 sorption capacity and improve amine efficiency of all MBS, most likely by alleviating the diffusion barrier within PEI bulk layers through the inter-molecular interaction between PEI and PEG. | Lin Zhang Xiaoxing Wang Mamoru Fujii Linjun Yang Chunshan Song | 2017 | Journal of Energy Chemistry2017，26，5： | 3 |
| 4 | Al2O3 and CeO2-promoted MgO sorbents for CO2 capture at moderate temperatures显示文摘 | Huimei Yu Xiaoxing Wang Zhu Shu Mamoru Fujii Chunshan Song | 2018 | Frontiers of Chemical Science and Engineering2018，12，1： | 2 |
| 5 | The template-assisted zinc ion incorporation in SAPO-34 and the enhanced ethylene selectivity in MTO reaction显示文摘The SAPO-34 catalyst was fine-tuned with zinc cations through a straightforward template-assisted ion incorporation (TH) process, without the necessary template pre-removal and the preparation of NH4- SAPO-34 intermediate, which is more facile, efficient and cost-effective than the conventional ion exchange process. The template-assisted zinc cations incorporated SAPO-34 catalysts were characterized by XRD, XRF, N2 adsorption-desorption, XPS, SEM, EDX,NMR, respectively. Enhanced selectivity to ethylene and ratio of ethylene to propylene in MTO reaction are observed over the zinc cations modified SAPO-34 catalysts, due to the facilitated formation of lower methylbenzenes that favour the ethylene gen eration, as well as the increased diffusion hindrance originated from the zinc cations incorporation and the facil让ated generation of aromatics compound. | Jiawei Zhong Jingfeng Han Yingxu Wei Shutao Xu Tantan Sun Xinwen Guo Chunshan Song Zhongmin Liu | 2019 | Journal of Energy Chemistry2019，28，5： | 2 |
| 6 | Impacts of nano-scale pore structure and organic amine assembly in porous silica on the kinetics of CO_(2) adsorptive separation显示文摘Nano structure including pore structure and amine assembly is critical for improving sorption and desorption kinetics for adsorptive CO_(2) separation.The present work delineates(1)the influence of the nano-scale pore structure of amine-functionalized solid sorbents,and(2)effect of changing the assembly of amine molecules on surface of nano-porous SiO_(2) on the rates of adsorption and desorption of CO_(2).50PEI-MSN sorbent with inverted cone-shaped pores was prepared by using mesoporous silica nanospheres(MSN)with inverted cone-shaped pores for the loading of polyethyleneimine(PEI).Co-structure-directing(CSD)method was used to synthesize the sorbent with arranged amine assembly at nano-scale(2N-CSD).By comparison with 50PE卜SBA15 as a benchmark sorbent,both sorbents have improved sorption and desorption kinetics.There are significant effects of nano pore structure and amine assembly on the sorption and desorption kinetics.The inverted cone-shaped pores in MSN allow loading polymeric amines in their narrower ends and leaving larger pore mouths open for the transport of CO_(2);50PEI-MSN shows a maximum sorption rate of 81.4 mg·g^(-1)·min^(-1) with average sorption rate of 25.4mg·g^(-1)·min^(-1) at 80℃ which are 34%and 59%higher than the corresponding values for 50PEI-SBA15;a maximum desorption rate of 38.4mg·g^(-1)·min^(-1) with average desorption rate of 11.8 mg·g^(-1)·min^(-1) ramping from 30 to 95℃ which are 37%and 156%higher than the corresponding values for 50PEI-SBA15.The arranged monolayer-like amine assembly on surface of nanoporous SiO_(2) likely provides high amine sorption sites through improved accessibility of amine,and 2N-CSD shows a maximum sorption rate of 60.5 mg·g^(-1)·min^(-1),with average sorption rate of 12.8mg·g^(-1)·min^(-1) at 300C which are 108%and 205%higher than the corresponding values for 50PEI-SBA15;a lower maximum desorption rate of 9.7 mg g'1min'1 and average desorption rate of 9.8mg·g^(-1)·min^(-1) ramping from 30 to 95℃ which is 250%higher than the corresponding value for 50PEI-SBA15.The present work demonstrates the importance of tailoring nano-scale pore structure and amine assembly for significantly improving sorption and desorption kinetics of adsorptive CO_(2) separation. | Feijian Lou Guanghui Zhang Limin Ren Xinwen Guo Chunshan Song | 2021 | Nano Research2021，14，9： | 2 |
| 7 | Effects of oxidative modification of carbon surface on the adsorption of sulfur compounds in diesel fuel显示文摘 | Anning Zhou Xiaoliang Ma Chunshan Song | 2008 | Applied Catalysis B, Environmental2008，，3： | 1 |
| 8 | Effects of aomatics, diesel additives, nitrogen compounds, and mois- ture on adsorptive desulfurization of diesel fuel over activa- ted carbon 显示文摘 | Xiao Jing Song Chunshan Ma Xiaoliang | 2012 | Industrial & Engineering Chemistry Research2012，51，8： | 1 |
| 9 | New design approaches to ultraclean diesel fuels by deep desulfurization and deep dearomatization 显示文摘 | Song Chunshan Ma Xiaoliang | 2003 | Applied Catalysis B : Environmental2003，41，： | 1 |
| 10 | An overview of new approaches to deep desulfurization for uhra-clean gasoline, diesel fuel and jet fuel显示文摘 | CHUNSHAN SONG | 2003 | Catalysis Today2003，86，14： | 1 |
| 11 | New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization显示文摘 | SONG Chunshan MA Xiaoliang | 2003 | Appl Catal2003，41，： | 1 |
| 12 | A new approach to deep desulfurization of gasoline,dieselfuel and jet fuel by selective adsorption for ultra-clean fuels and for fuel cell applications显示文摘 | Lu Sun Chunshan Song | 2002 | Catalysis Today2002，77，： | 1 |
| 13 | Zeolite -based adsorbent for desulfurization of jet fuel by selective adsorption 显示文摘 | Sun Lu Ma Xiaoliang Song Chunshan | 2002 | Fuel Chem2002，47，2： | 1 |
| 14 | New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization显示文摘 | Chunshan Song Xiaoliang Ma | 2002 | Applied Catalysis B, Environmental2002，，1： | 1 |
| 15 | An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel and jiet fuel 显示文摘 | Song Chunshan | 2003 | Catalysis Today2003，86，： | 1 |
| 16 | Shapeselective isopropylation of naphthalene over mordenite catalysts: computational analysis using MOPAC显示文摘 | Song Chunshan Ma Xiaoliang Schmitz A D | 1999 | Applied Catalysis A: General1999，182，： | 1 |
| 17 | A new approach to deep desulfurization of gasline, diesel fuel and jet fuel by selective ad- sorption for ultra -clean fuels and for fuel cell applications显示文摘 | Ma Xiaoliang Sun Lu Song Chunshan | 2002 | Catalysis Today2002，77，12： | 1 |
| 18 | An overview of new approaches to deep desufurization for ultra - clean gasoline, diesel and jet fuel 显示文摘 | Chunshan Song | 2003 | Catalysis Today2003，86，： | 1 |
| 19 | An overview of new approaches to deep desul furization for ultra-clean gasoline,diesel fuel and jet fuel 显示文摘 | SONG Chunshan | 2003 | Catalysis Today2003，86，14： | 1 |
| 20 | A new approach to deep desulfurization of gasoline,diesel fuel and jet fuel by selective adsorption for ultra-clean fuels and for fuel cell applications显示文摘 | Xiaoliang Ma La Sun Chunshan Song | 2002 | Catalysis Today2002，77，： | 1 |
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