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| 1 | Geochemistry and possible origin of the hydrocarbons from Wells Zhongshen1 and Zhongshen1C, Tazhong Uplift显示文摘In 2013, a great breakthrough of deep petroleum exploration was achieved in the Cambrian pre-salt intervals of Wells Zhongshen1(ZS1) and Zhongshen1C(ZS1C), Tazhong Uplift. However, the hydrocarbon discovery in the Cambrian pre-salt intervals has triggered extensive controversy regarding the source of marine oils in the Tarim Basin. The geochemistry and origin of the Cambrian pre-salt hydrocarbons in Wells ZS1 and ZS1 C were investigated using GC, GC-MS and stable carbon isotope technique. These hydrocarbons can be easily distinguished into two genetic families based on their geochemical and carbon isotopic compositions. The oil and natural gases from the Awatage Formation of Well ZS1 are derived from Middle-Upper Ordovician source rocks. In contrast, the condensate and gases from the Xiaoerbulake Formation of Wells ZS1 and ZS1 C probably originate from Cambrian source rocks. The recent discovery of these hydrocarbons with two different sources in Wells ZS1 and ZS1 C suggests that both Middle-Upper Ordovician-sourced hydrocarbons and Cambrian-sourced petroleums are accumulated in the Tazhong Uplift, presenting a great exploration potential. | SONG DaoFu WANG TieGuan LI MeiJun | 2016 | Science China Earth Sciences2016，59，4： | 12 |
| 2 | Geochemical studies of the Silurian oil reservoir in the Well Shun-9 prospect area, Tarim Basin, NW China显示文摘Commercial oil flow has been obtained from the sandstone reservoir of the Lower Silurian Kelpintag Formation in the Well Shun-9 prospect area.In the present studies,10 Silurian oil and oil sand samples from six wells in the area were analyzed for their molecular and carbon isotopic compositions,oil alteration(biodegradation),oil source rock correlation and oil reservoir filling direction.All the Silurian oils and oil sands are characterized by low Pr/Ph and C21/C23 tricyclic terpane(<1.0) ratios,'V'-pattern C27-C29 steranes distribution,low C28-sterane and triaromatic dinosterane abundances and light δ13C values,which can be correlated well with the carbonate source rock of the O3 l Lianglitage Formation.Different oil biodegradation levels have also been confirmed for the different oils/oil sands intervals.With the S1k2 seal,oils and oil sands from the S1k1 interval of the Kelpintag Formation have only suffered light biodegradation as confirmed by the presence of 'UCM' and absence of 25-norhopanes,whereas the S1k3-1 oil sands were heavily biodegraded(proved by the presence of 25-norhopanes) due to the lack of the S1k2 seal,which suggests a significant role of the S1k2 seal in the protection of the Silurian oil reservoir.Based on the Ts/(Ts+Tm) and 4-/1-MDBT ratios as reservoir filling tracers,a general oil filling direction from NW to SE has been also estimated for the Silurian oil reservoir in the Well Shun-9 prospect area. | Song Daofu Li Meijun Wang T.–G | 2013 | Petroleum Science2013，10，4： | 4 |
| 3 | Discovery of cutinitic liptobiolith in northwestern China and a comparative study with Luquan Devonian coal显示文摘Devonian cutinitic liptobiolith is a special cuticle-rich coal formed during the early stage of land plant evolution. In China, this special coal has previously only been reported in the Yangtze area, with the Luquan Devonian cutinitic liptobiolith of Yunnan Province being the most well-known. Recently, this type of coal was first discovered in the Bulonggoer Sag, to the northwest of the Junggar Basin, NW Xinjiang. Its geological age is regarded as the Givetian period of the late Middle Devonian,which is equivalent to the age of the Luquan Devonian coal. The cutinitic liptobiolith from NW Xinjiang has a distinct sheet-like texture resembling a stack of paper or leaf sheets in appearance, and so it is commonly called 'paper coal' or 'leaf coal'. Ribbonlike cutinite(thick-walled type) is the most abundant maceral in the coal(>60% and up to 80%, on a mineral-free basis), followed by ribbon-like collotelinite. The NW Xinjiang and Luquan cutinitic liptobioliths share similar maceral compositions;while their coal-forming plants and depositional conditions are distinct. The NW Xinjiang cutinitic liptobiolith was deposited in a regional fluvial or flood plain condition, with lycopsids as the dominant coal-forming plants. In contrast, the Luquan cutinitic liptobiolith formed in a coastal-lagoon environment, with primitive ferns as the predominant coal-forming plants, followed by lycopsids. The saturated fractions of the NW Xinjiang and Luquan liptobioliths are mainly composed of tetracyclic diterpanes. However, the tetracyclic diterpane compositions in the NW Xinjiang cutinitic liptobiolith are distinct from those in the Luquan Devonian coal:The former is dominated by atisanes and the latter is mainly composed of phyllocladanes. Different coal-forming plants may have contributed to the distinct tetracyclic diterpane compositions. | Daofu SONG Tieguan WANG Ningning ZHONG Yuan CHEN Dengfa HE Di LI | 2021 | Science China Earth Sciences2021，64，4： | 2 |
| 4 | Source of the condensates from the Hetianhe Field and the genetic relationship between the condensates and their associated gases显示文摘A detailed correlation of Hetianhe condensates versus typical source rocks from the Tarim Basin was established. Moreover, the genetic relationship between the condensates and their associated gases was also studied based on their geochemical compositions and fluid inclusion data. Hetianhe condensates are characterized by high pristine/phytane(Pr/Ph) ratios, high relative abundances of C28 regular steranes, C26–C27 triaromatic steroids, and triaromatic dinosteranes, and relatively heavy stable carbon isotopic compositions. They geochemically correlate well with the Cambrian source rocks, indicating that these condensates are derived from the Cambrian rocks. Based on several molecular maturity parameters, the condensates are recognized as being moderately to highly mature, which are too low in maturity to extensively crack into gases. The gases and condensates of the Hetianhe Field are derived from the same source rocks and the gases are from oil-cracking; however, clear evidence indicates that the gases were not cracked from their associated condensates and that the gas generation from oil-cracking did not occur in the present reservoirs. The liquid condensates produced from wellheads were likely dissolved in their associated gases underground and carried into the reservoirs by the gases. | SONG DaoFu WANG TieGuan LI MeiJun NI ZhiYong | 2015 | Science China Earth Sciences2015，58，9： | 0 |
| 5 | Origin,Distribution and Geochemical Significance of Isopropyltoluene Isomers in Crude Oil显示文摘With comprehensive two-dimensional gas chromatography linked to time-of-flight mass spectrometry(GC × GC-TOFMS),ten light hydrocarbon(LH) compounds were qualitatively and quantitatively studied in light hydrocarbons(LHs) components of crude oils.For significant differences in the concentrations of 3-isoproyltoluene(3-iPT),4-isoproyltoluene(4-iPT) and 2-isoproyltoluene(2-iPT) in crude oils,and the 2-iPT probably derived mainly from similar skeleton monocyclic terpenoids via dehydrogenation and aromatization,the ratios of(3+4)-/2-iPT(iPTr),3-/2-iPT(iPTr1) and 4-/2-iPT(iPTr2) are proposed to distinguish the organic matter origin of crude oils.Relatively higher iPTr(>8.0),iPTr1(>7.0) and iPTr2(>4.0) values indicate that crude oils are sourced from the co-contribution of lower aquatic organisms,bacteria,algae,and terrestrial higher plants,whereas lower iPTr(<5.0),iPTr1(<3.0),iPTr2(<2.0) values suggest that crude oils originated from terrestrial higher plants.The iPTr,iPTr1,and iPTr2 values show notable distinction which is mainly controlled by 2-iPT concentrations,while the concentrations of 3-iPT and 4-iPT have similar distribution range in all studied oils.The 2-iPT depleted in marine oils from the Tarim Basin and lacustrine oils from the Beibuwan Basin is less than 0.30 mg/g LHs,whereas 2-iPT enriched in swamp oils from the Tarim Basin is greater than 0.50 mg/g LHs.The iPTr,iPTr1,and iPTr2 ratios and 2-iPT concentrations can be used to distinguish the organic matter origin of crude oils,especially for light oils and condensates with low concentrations of biomarkers. | Bingkun Meng Daofu Song Yuan Chen Shengbao Shi Shixin Zhou | 2022 | Journal of Earth Science2022，33，1： | 0 |
| 6 | Petrology and geochemistry of the Carboniferous cutinite-rich coals from the Hequ area of Shanxi Province, China显示文摘Coal samples taken from the Taiyuan Formation in the Hequ area, China, for this study are typical cutinite-rich coals.The petrology and geochemistry of the samples were analyzed using microscopic examination, proximate and ultimate analysis,rock pyrolysis, and gas chromatography-mass spectrometry(GC-MS). The cutinites in Haochuan(HC) coals are predominantly of the thin-walled type, whereas those in the Jingzigou(JZG) coals are predominantly thick-walled. The variable thickness of cutinites in different coals is related to the environment in which the coal-forming plants grew. Compared with typical Ⅲ kerogens, HC and JZG bituminous coals are characterized by high volatile matter yields and hydrogen contents due to the elevated hydrogen-rich cutinite content. Pyrolysis data indicate that these cutinite-rich coals can be expected to generate commercial liquid and gaseous hydrocarbons. Pristane(Pr) and phytane(Ph) are both abundant in the samples, with the Pr/Ph ratios for both the HC and JZG coals being >3.0, indicating moderate maturity and oxic peat depositional conditions. The C>>C>Cnormalized relative abundance of regular steranes is consistent with a dominant contribution from higher plants.Abundant hopanes in the coals also suggest a substantial organic matter input from bacteria, which are common inhabitants of peat and coal. Palynology studies indicate that pteridophytes are likely to be the most common coal-forming plants. A gymnosperm contribution is also indicated by the presence of tetracyclic diterpenes. Massive accumulations of cuticles as cutinite in coal are rare and account for only a small proportion of coals worldwide. However, cutinite-rich coals are found in the northern margin of the North China Craton, in the Taiyuan Formation. The accumulation of cutinite in this area is the result of distinctive peat deposition conditions. Frequent marine transgression was an important contributing factor. | Daofu SONG Tieguan WANG Ping LI Jiadong YAN Xiangji ZHENG | 2022 | Science China Earth Sciences2022，65，10： | 0 |
| 7 | Detrital Zircon U-Pb Ages of the Zhaojiazhuang Formation, Middle–South Section, Taihang Mountains, China and their Geological Significance显示文摘The sedimentary Zhaojiazhuang Formation overlies the ancient Paleo-proterozoic crystalline basement in the middle-south sections of the Taihang Mountains,China.It is a complete stratigraphic sequence with clear boundaries.The formation has an angular unconformity with the underlying Paleo-proterozoic Tongyu Formation and a parallel unconformity with the overlying Changzhougou Formation from the Changcheng System,which is widely distributed throughout the W utai-Zhongtiao-T aihang Mountains.Qiu Zhen et al.(2007)and Wang Qingchun et al. | LYU Qiqi LUO Shunshe WANG Tongshan SONG Daofu TAN Cong ZHANG Yan GUAN Yulong | 2019 | Acta Geologica Sinica(English Edition)2019，93，3： | 0 |
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