| 1 | Design of phase interface and defect in niobium-nickel oxide for ultrafast Li-ion storage显示文摘Niobium pentoxide(Nb2O5)has attracted much attention in lithium batteries due to its advantages of high operating voltage,large theoretical capacity,environmental friendliness and cost-effectiveness.However,the intrinsic poor electrical conductivity,sluggish kinetics,and large volume changes hinder its electrochemical performance at high power density,making it away from the requirements for practical applications.In this research work,we regulate the electron transport of niobium-nickel oxide(NiNbO)anode material with enhanced structural stability at high power density by constructing the two-phase boundaries between niobium pentoxide(Nb2O5)and nickel niobate(NiNb2O6)through simple solid phase reaction.In addition,the presence of lattice defects in NiNbO-F further speeds up the transport of Li+and promotes the electrochemical reaction kinetics more effectively.The two-phase boundaries and defect modulated anode material displays high Li+diffusion coefficient of 1.63×10^(−10) cm^(2) s^(−1),pretty high initial discharge capacity of 222.8 mAh g^(−1) at 1 C,extraordinary high rate performance(66.7 mAh g^(−1))at an ultrahigh rate(100 C)and ultra-long cycling stability under high rate of 25 C(83.4 mAh g^(−1) after 2000 cycles)with only 0.016%attenuation per cycle.These results demonstrate an effective approach for developing electrode materials that greatly improve rate performance and durability. | Haiting Chen Haoyan Cheng Hangchen Liu Yibo Hu Tongtong Yuan Shuge Dai Meilin Liu Hao Hu | 2023 | Journal of Materials Science & Technology2023，，16： | 0 |
| 2 | In Situ Electrochemical Transmission Electron Microscopy for Sodium-Ion Batteries显示文摘Sodium-ion batteries(SIBs)possess promising application prospects for large-scale energy storage systems due to the abundance of sodium ions as a resource and their low cost.Development of advanced SIBs requires a clear understanding of the structures and kinetic/dynamic processes occurring in the cells during the charging/discharging process.In situ transmission electron microscopy(TEM)is a powerful tool for direct visualization of the phase transitions as well as morphological and structural evolutions of the electrodes during the electrochemical reaction process.Herein,we summarize the state-of-the-art in situ TEM studies on SIBs with a specific focus on real-time observations of the electrochemical behavior of battery materials.This review emphasizes the necessity of in situ TEM to elucidate fundamental issues regarding the reaction mechanism,phase transformation,structural evolution,and performance degradation of SIBs.Finally,critical challenges and emerging opportunities for in situ TEM research about SIBs are discussed. | Shuge Dai Jingwen Zhang Jiaqi Qu Xing Li Shaobo Cheng Chongxin Shan | 2023 | Renewables2023，1，1： | 0 |
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