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| 1 | Pressure-induced robust emission in a zero-dimensional hybrid metal halide (C_(9)NH_(20))_(6)Pb_(3)Br_(12)显示文摘Zero-dimensional(0D)hybrid metal halides are under intensive investigation owing to their unique physical properties,such as the broadband emission from highly localized excitons that is promising for white-emitting lighting.However,fundamental understanding of emission variations and structure–property relationships is still limited.Here,by using pressure processing,we obtain robust exciton emission in 0D(C_(9)NH_(20))_(6)Pb_(3)Br_(12) at room temperature that can survive to 80 GPa,the recorded highest value among all the hybrid metal halides.In situ experimental characterization and first-principles calculations reveal that the pressure-induced emission is mainly caused by the largely suppressed phonon-assisted nonradiative pathway.Lattice compression leads to phonon hardening,which considerably weakens the exciton–phonon interaction and thus enhances the emission.The robust emission is attributed to the unique structure of separated spring-like[Pb_(3)Br_(12)]^(6−)trimers,which leads to the outstanding stability of the optically active inorganic units.Our findings not only reveal abnormally robust emission in a 0D metal halide,but also provide new insight into the design and optimization of local structures of trimers and oligomers in lowdimensional hybrid materials. | Mengting Chen Songhao Guo Kejun Bu Sujin Lee Hui Luo Yiming Wang Bingyan Liu Zhipeng Yan Hongliang Dong Wenge Yang Biwu Ma Xujie Lü | 2021 | Matter and Radiation at Extremes2021，6，5： | 1 |
| 2 | Application of parametric sketching and associability in 3D CAD显示文摘 | Wang SongHao Melendez Steven Tsai Chyi-Shyan | 2008 | Computer-Aided Design and Applications2008，5，6： | 1 |
| 3 | Investigation of the influence of MoS2 filler on the tribological properties of carbon fiber reinforced nylon 1010 composites显示文摘 | Wang Junxiang Gu Mingyuan Bai Songhao | 2003 | Wear2003，255，： | 1 |
| 4 | Study of synthesizing process for nanosized silicon powder by laser显示文摘 | Songhao Liu Yanbiao Mei | 1995 | Applicational Laser1995，，1： | 1 |
| 5 | Regulating off-centering distortion maximizes photoluminescence in halide perovskites显示文摘Metal halide perovskites possess unique atomic and electronic configurations that endow them with high defect tolerance and enable high-performance photovoltaics and optoelectronics.Perovskite light-emitting diodes have achieved an external quantum efficiency of over 20%.Despite tremendous progress,fundamental questions remain,such as how structural distortion affects the optical properties.Addressing their relationships is considerably challenging due to the scarcity of effective diagnostic tools during structural and property tuning as well as the limited tunability achievable by conventional methods.Here,using pressure and chemical methods to regulate the metal off-centering distortion,we demonstrate the giant tunability of photoluminescence(PL)in both the intensity(>20 times)and wavelength(>180 nm/GPa)in the highly distorted halide perovskites[CH_(3)NH_(3)GeI_(3),HC(NH_(2))2GeI_(3),and Cs Ge I_(3)].Using advanced in situ high-pressure probes and first-principles calculations,we quantitatively reveal a universal relationship whereby regulating the level of off-centering distortion towards 0.2 leads to the best PL performance in the halide perovskites.By applying this principle,intense PL can still be induced by substituting CH_(3)NH_(3)^(+)with Cs^(+)to control the distortion in(CH_(3)NH_(3))_(1-x)Cs_(x)GeI_(3),where the chemical substitution plays a similar role as external pressure.The compression of a fully substituted sample of CsGe I_(3)further tunes the distortion to the optimal value at 0.7 GPa,which maximizes the emission with a10-fold enhancement.This work not only demonstrates a quantitative relationship between structural distortion and PL property of the halide perovskites but also illustrates the use of knowledge gained from high-pressure research to achieve the desired properties by ambient methods. | Xujie Lv Constantinos Stoumpos Qingyang Hu Xuedan Ma Dongzhou Zhang Songhao Guo Justin Hoffman Kejun Bu Xiaofeng Guo Yingqi Wang Cheng Ji Haijie Chen Hongwu Xu Quanxi Jia Wenge Yang Mercouri G.Kanatzidis Ho-Kwang Mao | 2021 | National Science Review2021，8，9： | 1 |
| 6 | Ray traces in graded-index optical fibers显示文摘 | Wang An Liu Songhao | 1986 | Acta Optica Sinica1986，6，2： | 1 |
| 7 | A Study on Investment Casting Directly with Plastic Rapid Prototype Patterns显示文摘 | Songhao Wang Chinwang Shih Xinyin He | 2010 | 材料科学与工程(中英文版)2010，4，11： | 0 |
| 8 | Petrogenesis and Geodynamic Implications of Early Cretaceous(~130 Ma)Magmatism in the Baingoin Batholith,Central Tibet:Products of Subducting Slab Rollback显示文摘The Baingoin batholith is one of the largest granitic plutons in the North Lhasa terrane.Its petrogenesis and tectonic setting have been studied for decades,but remain controversial.Here we report data on geochronology,geochemistry and isotopes of Early Cretaceous granitoids within the Baingoin batholith,which provide more evidence to uncover its petrogenesis and regional geodynamic processes.The Early Cretaceous magmatism yields ages of 134.4–132.0 Ma and can be divided into I-type,S-type and highly fractionated granites.The I-and S-type granites exhibit medium SiO2,high K_(2)O/Na_(2)O with negativeεNd(t)andεHf(t)values,whereas,the albite granites have very high SiO_(2)(79.04%–80.40%),very low K_(2)O/N_(2)O,negativeεNd(t)and a large variation inεHf(t).Our new data indicate that these granitoids are derived from unbalanced melting in a heterogeneous source area.The granodiorites involved had a hybrid origin from partial melting of basalt-derived and Al-rich rocks in the crust,the porphyritic monzogranites being derived from partial melting of pelitic rocks.The albite granites crystallized from residual melt separated from K-rich magma within the‘mush’process and underwent fractionation of K-feldspar.We believe that the Early Cretaceous magmatism formed in an extensional setting produced by the initial and continuous rollback of a northward-subducting slab of the NTO. | LI Faqiao TANG Juxing WANG Nan LIU Zhibo SONG Yang ZHANG Jing MA Xudong FU Bin LI Haifeng HAN Songhao | 2022 | Acta Geologica Sinica(English Edition)2022，96，6： | 0 |
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