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| 1 | Efficient Modeling of an Axial Compressor with Swirl Distortion显示文摘This paper presents a satisfactory numerical strategy to reliably evaluate the three-dimensional large-scale flow feature of multistage axial compressors in response to complex swirl distortion with acceptable computational cost. Under the theoretical framework of the body force method, the guide vanes of a swirl distortion generator and the multiple blade rows of a two-stage low-speed axial compressor are described by distributed source terms instead of a complex body-fitted grid approach. The key flow structure of the paired swirl generated by the swirl generator and the main distributions of flow angle at the rotor outlet of the first stage captured by the model agree well with experimental results, demonstrating the effectiveness of the numerical strategy. Additionally, the interaction process between the steady-state paired swirl and the compressor is clearly revealed by the study. The intensity of the swirl distortion can be greatly reduced after passing through the axial compressor. However, the swirl has a significant impact on the local blade loading of the first stage, which induces the mass flux nonuniformity as well as total pressure and total temperature distortion. The combined total pressure and total temperature distortion is significantly attenuated near tip and slightly enhanced near hub as it moves through the second stage. | GUO Jin HU Jun WANG Xuegao TU Baofeng | 2021 | Journal of Thermal Science2021,30,4: | 1 |
| 2 | K-doped BaCo_(0.4)Fe_(0.4)Zr_(0.2)O_(3−δ) as a promising cathode material for protonic ceramic fuel cells显示文摘Slow oxygen reduction reaction(ORR)involving proton transport remains the limiting factor for electrochemical performance of proton-conducting cathodes.To further reduce the operating temperature of protonic ceramic fuel cells(PCFCs),developing triple-conducting cathodes with excellent electrochemical performance is required.In this study,K-doped BaCo_(0.4)Fe_(0.4)Zr_(0.2)O_(3−δ)(BCFZ442)series were developed and used as the cathodes of the PCFCs,and their crystal structure,conductivity,hydration capability,and electrochemical performance were characterized in detail.Among them,Ba_(0.9)K_(0.1)Co_(0.4)Fe_(0.4)Zr_(0.2)O_(3−δ)(K10)cathode has the best electrochemical performance,which can be attributed to its high electron(e^(−))/oxygen ion(O^(2−))/H^(+)conductivity and proton uptake capacity.At 750℃,the polarization resistance of the K10 cathode is only 0.009Ω·cm^(2),the peak power density(PPD)of the single cell with the K10 cathode is close to 1 W·cm^(−2),and there is no significant degradation within 150 h.Excellent electrochemical performance and durability make K10 a promising cathode material for the PCFCs.This work can provide a guidance for further improving the proton transport capability of the triple-conducting oxides,which is of great significance for developing the PCFC cathodes with excellent electrochemical performance. | Peng QIU Bo LIU Lei WU Huiying QI Baofeng TU Jian LI Lichao JIA | 2022 | Journal of Advanced Ceramics2022,11,12: | 1 |
| 3 | A comparison on effects of CO 2 on La 0.8 Sr 0.2 MnO 3+ δ and La 0.6 Sr 0.4 CoO 3? δ cathodes显示文摘 | Zhe Zhao Li Liu Xiaomin Zhang Weiming Wu Baofeng Tu Dingrong Ou Mojie Cheng | 2013 | Journal of Power Sources2013,,: | 1 |
| 4 | LSM-YSZ nano-composite cathode with YSZ interlayer for solid oxide fuel cells显示文摘Low temperature prepared(La_(0.8)Sr_(0.2))_(0.9)MnO_3-δ-Y_(0.15)Zr_(0.85)O_(1.93)(LSM-YSZ) nano-composite cathode has high three-phase boundary(TPB) density and shows higher oxygen reduction reaction(ORR) activity than traditional LSM-YSZ cathode at reduced temperatures. But the weak connection between cathode and electrolyte due to low sintering temperature restrains the performance of LSM-YSZ nano-composite cathode. A YSZ interlayer, consisted of nanoparticles smaller than 10 nm, is introduced by spinning coating hydrolyzed YSZ sol solution on electrolyte and sintering at 800 °C. The thickness of the interlayer is about 150 nm. The YSZ interlayer intimately adheres to the electrolyte and shows obvious agglomeration with LSM-YSZ nano-composite cathode. The power densities of the cell with interlayer are 0.83, 0.46 and 0.21 W/cm^2 under 0.7 V at 800, 700 and 600 °C, respectively, which are 36%, 48% and 50% improved than that of original cell. The interlayer introduction slightly increases the ohmic resistance but significantly decreases the polarization resistance. The depressed high frequency arcs of impedance spectra suggest that the oxygen incorporation kinetics are enhanced at the boundary of YSZ interlayer and LSM-YSZ nanocomposite cathode, contributing to improved electrochemical performance of the cell with interlayer. | Zhongbo Liu Zhe Zhao Lei Shang Dingrong Ou Daan Cui Baofeng Tu Mojie Cheng | 2017 | Journal of Energy Chemistry2017,26,3: | 0 |
| 5 | Enhancing cathode performance for CO2 electrolysis with Ce0.9M0.1O2-δ(M=Fe, Co, Ni) catalysts in solid oxide electrolysis cell显示文摘Electrochemical conversion with solid oxide electrolysis cells is a promising technology for CO2 utilization and simultaneously store renewable energy.In this work,Ce0.9M0.1O2-δ(CeM,M=Fe,Co,Ni)catalysts are infiltrated into La0.6Sr0.4Cr0.5Fe0.5O3-δ-Gd0.2Ce0.8O2-δ(LSCr Fe-GDC)cathode to enhance the electrochemical performance for CO2 electrolysis.CeCo-LSCrFe-GDC cell obtains the best performance with a current density of 0.652 A cm^-2,followed by CeFe-LSCrFe-GDC and CeNi-LSCrFe-GDC cells with the value of 0.603 and 0.535 A cm^-2,respectively,about 2.44,2.26 and 2.01 times higher than that of the LSCrFe-GDC cell at1.5 V and 800℃.Electrochemical impedance spectra combined with distributions of relaxed times analysis shows that both CO2 adsorption process and the dissociation of CO2 at triple phase boundaries are accelerated by Ce M catalysts,while the latter is the key rate-determining step. | Zhidong Huang Zhe Zhao Huiying Qi Xiuling Wang Baofeng Tu Mojie Cheng | 2020 | Journal of Energy Chemistry2020,29,1: | 0 |