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3篇 您的检索式:作者名="Tang Guangshi"
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1Synthesis of N-acetamide C_(60) nitride and its performance of optical limiting显示文摘N-acetamide C60 nitride (N-acetamide-1,2-dihydro-1,2-aza-fullerene[60]) has been synthesized by the reaction of C60 and azidoacetamide and initially characterized. Its mechanism was that the objective product is formed through intermediate triazoline. The computational study shows that N-nitride structure is thermodynamically more stable by using the semi-empirical AM1 SCF-MO method. The properties of optical limiting were tested by using double frequency Nd: YAG pulse laser system and showed that the optical limiting mechanism is reverse saturation absorption. At wavelength of 532 nm, compared with optical limiting for ns pulse, this new material has good optical limiting character for ps pulse. At wavelength of 707 nm. the capacity of optical limiting of the derivative is prior to C60-TANG Guangshi, ZHU Hesun & SONG Yinglin Research Center of Materials Science, Beijing Institute of Technology, Beijing 100081, China Department of Applied Physics, Harbin Institute of Technology. Harbin 150001. China Department of Applied Chemiscy Beiji 2000Chinese Science Bulletin2000,45,2:4
2An integrated strategy towards the facile synthesis of core-shell SiC-derived carbon@N-doped carbon for high-performance supercapacitors显示文摘Porous active core-shell carbon material with excellent synergistic effect has been regarded as a prospective material for supercapacitors.Herein,we report an integrated method for the facile synthesis of carbide-derived carbon(CDC)encapsulated with porous N-doped carbon(CDC@NC)towards highperformance supercapacitors.Polydopamine(PDA)as nitrogen and carbon sources was simply coated on SiC nanospheres to form SiC@PDA,which was then directly transformed into CDC@NC via a onestep molten salt electro-etching/in-situ doping process.The synthesized CDC@NC with hierarchically porous structure has a high specific surface area of 1191 m^(2) g^(-1).The CDC core and NC shell are typical amorphous carbon and more ordered N-doped carbon,respectively.Benefitting from its unique dual porous structures,the CDC@NC demonstrates high specific capacitances of 255 and 193 F g^(-1) at 0.5 and20 A g^(-1),respectively.The reaction mechanism of the electro-etching/in-situ doping process has also been investigated through experimental characterizations and theoretical density functional theory calculations.It is suggested that the molten salt electro-etching/in-situ doping strategy is promising for the synthesis of active core-shell porous carbon materials with synergistic properties for supercapacitors without the need for additional doping/activation processes.Zhongya Pang Guangshi Li Xingli Zou Chenteng Sun Conghui Hu Wei Tang Li Ji Hsien-Yi Hsu Qian Xu Xionggang Lu 2021Journal of Energy Chemistry2021,30,5:2
3Synthesis, characterization and intramolecular diels-alder reaction tandem dehydroaromatization of a diene-diyne 显示文摘Liu Shuzhi Tang Guangshi Wang Jing 2005Chemistry Letters2005,34,7:1
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