| 1 | Preparation of novel magnetic nanoparticles as draw solutes in forward osmosis desalination显示文摘Novel magnetic nanoparticles(MNPs),Fe_(3)O_(4)@SiO_(2) and Fe_(3)O_(4)@SiO_(2)@PEG-(COOH)_(2),were prepared by loading different amounts of SiO_(2) or/and PEG-(COOH)_(2) onto Fe_(3)O_(4) nanoparticles,and their feasibility to be used as forward osmosis(FO)draw solutes was investigated.The characterization of the materials showed that,compared to normal Fe_(3)O_(4) nanoparticles,the modified MNPs exhibited enhanced dispersity and high osmotic pressure in aqueous solution.The FO experiment indicated that the synthesized draw solutes could obtain a water flux as high as 10 L·m^(-2)·h^(-1) with an aquaporin FO membrane.The optimal concentration of the added tetraethyl orthosilicate was 30%during the synthesis.The novel MNPs could be easily recovered from draw solutions by magnetic field,and the recovery rate of Fe_(3)O_(4)@SiO_(2) and Fe_(3)O_(4)@SiO_(2)@PEG-(COOH)_(2) was 83.95%and 63.37%,respectively.Moreover,after 5 recycles of reuse,the water flux of Fe_(3)O_(4)@SiO_(2) and Fe_(3)O_(4)@SiO_(2)@PEG-(COOH)_(2) as draw solutes still remained 64.36%and 85.26%,respectively.The experimental results demonstrated that the synthesized core–shell magnetic nanoparticles are promising draw solutes,and the Fe_(3)O_(4)@SiO_(2)@PEG-(COOH)_(2) was more suitable to be used as draw solute in FO process. | Dongze Ma Ye Tian Tiefei He Xiaobiao Zhu | 2022 | Chinese Journal of Chemical Engineering2022，35，6： | 0 |
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