| 1 | Post-Synthetic and In Situ Vacancy Repairing of Iron Hexacyanoferrate Toward Highly Stable Cathodes for Sodium-Ion Batteries显示文摘Iron hexacyanoferrate(FeHCF)is a promising cathode material for sodium-ion batteries.However,FeHCF always suffers from a poor cycling stability,which is closely related to the abundant vacancy defects in its framework.Herein,post-synthetic and in-situ vacancy repairing strategies are proposed for the synthesis of highquality FeHCF in a highly concentrated Na_(4)Fe(CN)_(6) solution.Both the post-synthetic and in-situ vacancy repaired FeHCF products(FeHCF-P and FeHCF-I)show the significant decrease in the number of vacancy defects and the reinforced structure,which can suppress the side reactions and activate the capacity from low-spin Fe in FeHCF.In particular,FeHCF-P delivers a reversible discharge capacity of 131 mAh g^(−1) at 1 C and remains 109 mAh g^(−1) after 500 cycles,with a capacity retention of 83%.FeHCF-I can deliver a high discharge capacity of 158.5 mAh g^(−1) at 1 C.Even at 10 C,the FeHCF-I electrode still maintains a discharge specific capacity of 103 mAh g^(−1) and retains 75% after 800 cycles.This work provides a new vacancy repairing strategy for the solution synthesis of high-quality FeHCF. | Min Wan Rui Zeng Jingtao Meng Zexiao Cheng Weilun Chen Jiayu Peng Wuxing Zhang Yunhui Huang | 2022 | Nano-Micro Letters2022，14，1： | 3 |
| 2 | Facile synthesis of Li2S@C composites as cathode for Li–S batteries显示文摘Lithium sulfide (Li2S) provides a promising route for lithium storage due to high theoretical specific capacity (1166 mAh g-1). The electrochemical performance of Li2S can be significantly enhanced by forming Li2S-carbon composites with the introduction of carbon. However, the complex synthesis method of Li2S-carbon composites restrains the large-scale productivity. Herein, we propose a facile route to prepare carbon coated Li2S-carbon nanotube composites (Li2S@C-CNT) via spray drying and heat treatment, which is a low-cost and large-scale method for facile synthesis of Li2S-carbon composites. For the Li2S@C-CNT composites, Li2S nanoparticles are contacted with surrounding particles due to the 3D CNTs framework. The novel construction not only suppresses the diffusion of polysulfides during cycling, but also remarkably accelerates the transport of electron and ion, resulting in a high specific capacity (1100 mAh g^-1) and good cycling performance. The rational designed architecture and good electrochemical performance of Li2S@C-CNT will pave the avenue for realizing high energy density of Li2S-based batteries. | Xin Chen Linfeng Peng Lixia Yuan Rui Zeng Jingwei Xiang Weilun Chen Kai Yuan Jie Chen Yunhui Huang Jia Xie | 2019 | Journal of Energy Chemistry2019，28，10： | 1 |
| 3 | Experimental investigation of a novel micro gas turbine with flexible switching function for distributed power system显示文摘Micro gas turbine(MGT)is widely used in small-scale distributed power systems because of its low emissions and fuel flexibility.However,the under-utilization of its exhaust heat and the low electric efficiency are the main bottlenecks that restrict its application.Additionally,the flexible switching between the power generated by the MGT and the power grid is also a key factor for keeping the secure operation of a distributed power station.Therefore,this paper conducted some experimental investigations of a 30 kW MGT to provide reference solutions for the above issues.This MGT is located at Shanghai Jiao Tong University(SJTU),which is designed by the Gas Turbine Research Institute of SJTU,and is manufactured by a turbo machinery factory in Chongqing,China.The demonstration prototype is mainly composed of a single stage centrifugal compressor,a radial turbine,a combustor,a high-speed pennanent magnet generator,and a control system.The results show that the MGT can achieve steady operation at a low rotational speed from 10000 r/min to 34000 r/min in the case of using oil lubricated bearings,which can greatly reduce the economic cost compared with the use of air bearings.At the same time,the ignition success rate of combustion chamber(CC)reaches 98%at a low rotational speed,and a wide range of stable combustion area can be obtained,because of the novel design method of combustor by referencing the way applied in an axial flow aero-engine.The MGT generating set can achieve functions,such as starting up,ignition,stable operation,loaded operation,grid-connection and stopping.This system also can realize flexibly switching from the start motor mode to the generator mode,and from grid-connected mode to off^grid mode,because the innovative multi-state switching control system is adopted.The above research work can make our state master independent intellectual property rights of micro gas turbine,rather than continue to be subject to the technological monopoly of the developed states,which can provide theoretical and experimental support for the industrialization of MGT in China. | Xiaojing LV Weilun ZENG Xiaoyi DING Yiwu WENG Shilie WENG | 2020 | Frontiers in Energy2020，14，4： | 1 |
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