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1篇 您的检索式:作者名="William P.Gillin"
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1Enhanced 1.54-μm photo-and electroluminescence based on a perfluorinated Er(Ⅲ) complex utilizing an iridium(Ⅲ) complex as a sensitizer显示文摘Advanced 1.5-μm emitting materials that can be used to fabricate electrically driven light-emitting devices have the potential for developing cost-effective light sources for integrated silicon photonics.Sensitized erbium(Er^(3+))in organic materials can give bright 1.5-μm luminescence and provide a route for realizing 1.5-μm organic light emitting diodes(OLEDs).However,the Er3+electroluminescence(EL)intensity needs to be further improved for device applications.Herein,an efficient 1.5-μm OLED made from a sensitized organic Er3+co-doped system is realized,where a“traditional”organic phosphorescent molecule with minimal triplet–triplet annihilation is used as a chromophore sensitizer.The chromophore provides efficient sensitization to a co-doped organic Er^(3+) complex with a perfluorinatedligand shell.The large volume can protect the Er^(3+) 1.5-μm luminescence from vibrational quenching.The average lifetime of the sensitized Er^(3+) 1.5-μm luminescence reaches ~0.86 ms,with a lifetime component of 2.65 ms,which is by far the longest Er^(3+) lifetime in a hydrogen-abundant organic environment and can even compete with that obtained in the fully fluorinated organic Er^(3+) system.The optimal sensitization enhances the Er^(3+) luminescence by a factor of 1600 even with a high concentration of the phosphorescent molecule,and bright 1.5-μm OLEDs are obtained.Hong-Fei Li Xiao-Qi Liu Chen Lyu Jelena Gorbaciova Li-Li Wen Guo-Gang Shan Peter B.Wyatt Huan-Qing Ye William P.Gillin 2020Light(Science & Applications)2020,9,1:1
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