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1篇 您的检索式:作者名="Xiongfei Deng"
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1Quinoxaline-specific enantioselective sulfa-michael reaction catalyzed by chiral phosphoric acid显示文摘Highly enantioselective sulfa-Michael additions(SMA)between 2-alkenyl quinoxalines and aromatic thiols are accomplished using a low loading of chiral phosphoric acid catalyst(1 mol%).It was confirmed by an investigation of a lot of azaarenes that the two C-N units of quinoxalines are indispensable for controlling the reaction enantioselectivities.A series of non-terminal 2-alkenes substituted with aryls or alkyls,even other electro-withdrawing groups such as ketones,esters,or amides,selectively reacted and afforded the desired SMA products(48 examples)in good regioselectivities with high yields(up to 99%)and good ee values(up to 97%).Xiongfei Deng Shiqi Zhang Hesen Huang Xin Cui Zhuo Tang Guangxun Li 2023Chinese Chemical Letters2023,34,12:0
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