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| 1 | Optically tunable fluorescent carbon nanoparticles and their application in fluorometric sensing of copper ions显示文摘A series of carb on nano particles(CNPs)with emissi on wavele ngth ranging from 483 to 525 nm were prepared by hydrothermal treatme nt of poly-3-thiopheneacetic acid(PTA)and NaOH.The emission wavelength and surface oxidation degree of CNPs were shown to be controllable by simply adjusti ng NaOH concentration.These CNPs prese nted obvious fluoresce nee spectral response toward copper ions(Cu^2+)through static quenching caused synergistically by electron transfer and inner filter effect.The O-and S-containing groups on the surface of CNPs were dem on strated to be resp on sible for their outsta nding sensing performa nee.Based on that,a CN Ps-based ratiometric fluoresce nt probe for Cu^2+with a high fluoresce nee quenching rate constant of 1.4×10^5 L/mol and a short resp onse time(10 s)was developed.Their practical applications in detecting Cu^2+in pond water and living cells were also dem on strated. | Minhuan Lan Shaojing Zhao Shuilin Wu Xiaofang Wei Yanzhao Fu Juanjuan Wu Pengfei Wang Wenjun Zhang | 2019 | Nano Research2019，12，10： | 2 |
| 2 | Insights into the rheological modeling of semi-solid metals:Theoretical and simulation study显示文摘The power law model is the most widely used model for the rheological behavior of semi-solid metals(SSMs)in the numerical simulation of semi-solid processing.However,it is still not known why the anomalous negative flow exponent exists in the power law model for SSMs and its influence on the simulation.In this research,the rheological behavior of semi-solid Al-7Si-0.3Mg aluminum alloy is experimentally studied followed by modeling.The power law model fitting results show flow curves deviate from the experimental data and negative flow exponents,which are physically nonsensical and inapplicable to the simulation of SSMs flow proved by hydrodynamic analysis.This drawback of the power law model stems from neglecting the yield stress of SSMs.By contrast,the model referring Herschel-Bulkley(HB)theory which takes yield stress into consideration has reasonable flow exponent and yields good agreement between the fitting and experimental results.Furthermore,the simulation of die filling process is conducted,suggesting that the power law model over-optimistically predicts the tendency of blistering and misrun defects at low temperature and high filling velocity during semi-solid processing. | Zhen Ma Huarui Zhang Hanwei Fu Yanzhao Yang Jianji Wang Ming Du Hu Zhang | 2022 | Journal of Materials Science & Technology2022，，5： | 0 |
| 3 | The construction of high precision geostrophic currents based on new gravity models of GOCE and satellite altimetry data显示文摘The new gravity field models of gravity field and steady-state ocean circulation explorer(GOCE),TIM_R6 and DIR_R6,were released by the European Space Agency(ESA)in June 2019.The sixth generation of gravity models have the highest possible signal and lowest error levels compared with other GOCE-only gravity models,and the accuracy is significantly improved.This is an opportunity to build high precision geostrophic currents.The mean dynamic topography and geostrophic currents have been calculated by the 5th(TIM_R5 and DIR_R5),6th(TIM_R6 and DIR_R6)release of GOCE gravity field models and ITSG-Grace2018 of GRACE gravity field model in this study.By comparison with the drifter results,the optimal filtering lengths of them have been obtained(for DIR_R5,DIR_R6,TIM_R5 and TIM_R6 models are 1°and for ITSG-Grace2018 model is 1.1°).The filtered results show that the geostrophic currents obtained by the GOCE gravity field models can better reflect detailed characteristics of ocean currents.The total geostrophic speed based on the TIM_R6 model is similar to the result of the DIR_R6 model with standard deviation(STD)of 0.320 m/s and 0.321 m/s,respectively.The STD of the total velocities are 0.333 m/s and 0.325 m/s for DIR_R5 and TIM_R5.When compared with ITSG-Grace2018 results,the STD(0.344 m/s)of total geostrophic speeds is larger than GOCE results,and the accuracy of geostrophic currents obtained by ITSG-Grace2018 is lower.And the absolute errors are mainly distributed in the areas with faster speeds,such as the Antarctic circumpolar circulation,equatorial region,Kuroshio and Gulf Stream areas.After the remove-restore technique was applied to TIM_R6 MDT,the STD of total geostrophic speeds dropped to 0.162 m/s. | Wenyan Sui Junru Guo Jun Song Zhiliang Liu Meng Wang Xibin Li Yanzhao Fu Yongquan Li Yu Cai Linhui Wang Lingli Li Xiaofang Guo Wenting Zuo | 2021 | Acta Oceanologica Sinica2021，40，3： | 0 |
| 4 | Tuning the crystalline and electronic structure of ZrO_(2)via oxygen vacancies and nano-structuring for polysulfides conversion in lithium-sulfur batteries显示文摘The recent emergence of tetragonal phases zirconium dioxide(ZrO_(2))with vacancies has generated significant interest as a highly efficient and stable electrocatalyst with potential applications in trapping polysulfides and facilitating rapid conversion in lithium-sulfur batteries(LSBs).However,the reduction of ZrO_(2)is challenging,even under strong reducing atmospheres at high temperatures and pressures.Consequently,the limited presence of oxygen vacancies results in insufficient active sites and reaction interfaces,thereby hindering practical implementation.Herein,we successfully introduced abundant oxygen vacancies into ZrO_(2)at the nanoscale with the help of carbon nanotubes(CNTs-OH)through hydrogen-etching at lower temperatures and pressures.The introduced oxygen vacancies on ZrO_(2-x)/CNTs-OH can effectively rearrange charge distribution,enhance sulfiphilicity and increase active sites,contributing to high ionic and electronic transfer kinetics,strong binding energy and low redox barriers between polysulfides and ZrO_(2-x).These findings have been experimentally validated and supported by theory calculations.As a result,LSBs assembled with the ZrO_(2-x)/CNTs-OH modified separators demonstrate excellent rate performance,superior cycling stability,and ultra-high sulfur utilization.Especially,at high sulfur loading of 6 mg cm^(-2),the area capacity is still up to 6.3 mA h cm^(-2).This work provides valuable insights into the structural and functional optimization of electrocatalysts for batteries. | Shengnan Fu Chaowei Hu Jing Li Hongtao Cui Yuanyuan Liu Kaihua Liu Yanzhao Yang Meiri Wang | 2024 | Journal of Energy Chemistry2024，88，1： | 0 |
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