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| 1 | Facile synthesis of graphene-supported Ni-CeOx nano-composites as highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane显示文摘 | Qilu Yao Zhang-Hui Lu Yuwen Yang Yuzhen Chen Xiangshu Chen Hai-Long Jiang | 2018 | Nano Research2018，11，8： | 11 |
| 2 | Nanocatalysts for hydrogen generation from ammonia borane and hydra- zine borane 显示文摘 | Lu Zhanghui Yao Qilu Zhang Zhujun | 2014 | J Nanomaterials2014，2014，72： | 1 |
| 3 | In situ facile synthesis of Rh nanoparticles supported on carbon nano- tubes as highly active catalysts for H2 generation from NH3BH3 hydrolysis 显示文摘 | Yao Qilu Lu Zhanghui Jia Yushuai | 2015 | Int J Hydrogen Energy2015，40，5： | 1 |
| 4 | Uhrafine Ru nan- oparticles embedded in SiO2 nanospheres:Highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane 显示文摘 | Yao Qilu Shi Weimei Feng Gang | 2014 | J Power Sources2014，257，： | 1 |
| 5 | Methanolysis of ammonia borane by shape-controlled mesoporous copper nanostructures for hydrogen generation 显示文摘 | Yao Qilu Huang Ming Lu Zhanghui | 2015 | Dalton Trans2015，44，3： | 1 |
| 6 | One-pot syn- thesis of core-shell Ca@ SiO2 nanospheres and their catal- ysis for hydrolytic dehydrogenation of ammonia borane and hydrazine borane 显示文摘 | Yao Qilu Lu Zhanghui Zhang Zhujun | 2014 | Sci Rep2014，4，： | 1 |
| 7 | A step‐growth strategy to grow vertical porous aromatic framework nanosheets on graphene oxide:Hybrid material‐confined Co for ammonia borane methanolysis显示文摘The rational synthesis of a two-dimensional(2D)porous aromatic framework(PAF)with a controllable growth direction remains a challenge to overcome the limitation of traditional stacked 2D materials.Herein,a step-growth strategy is developed to fabricate a vertically oriented nitrogen-rich porous aromatic framework on graphene oxide(V-PAF-GO)using monolayer benzidine-functionalized GO(BZ-GO)as a molecular pillar.Then,the confined Co nanoparticle(NP)catalysts are synthesized by encapsulating ultra-small Co into the slit pores of V-PAF-GO.Due to the high nitrogen content,large specific surface area,and adequate slit pores,the optimized vertical nanocomposites V-PAF-GO provide abundant anchoring sites for metal NPs,leading to ultrafine Co NPs(1.4 nm).The resultant Co/V-PAF-GO catalyst shows an extraordinary catalytic activity for ammonia borane(AB)methanolysis,yielding a turnover frequency value of 47.6 min−1 at 25°C,comparable to the most effective non-noble-metal catalysts ever reported for AB methanolysis.Experimental and density functional theory studies demonstrate that the electron-donating effect of N species of PAF positively corresponds to the low barrier in methanol molecule activation,and the cleavage of the O–H bond in CH3OH has been proven to be the rate-determining step for AB methanolysis.This work presents a versatile step-growth strategy to prepare a vertically oriented PAF on GO to solve the stacking problem of 2D materials,which will be used to fabricate other novel 2D or 2D–2D materials with controllable orientation for various applications. | Xiugang Li Qilu Yao Rongwei Shi Minsong Huang Zhang‐Hui Lu | 2023 | Carbon Energy2023，5，10： | 0 |
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