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2篇 您的检索式:作者名="Yaohang Cheng"
    题名 作者 年代 出处 被引量
1Visible-light-enabled ruthenium-catalyzed para-C-H difluoroalkylation of anilides显示文摘Visible-light-mediated para-C-H difluoroalkylation of anilides via combination of steric effects and Lewis acid activation strategies has been developed. The addition of(C_6H_5O)_(2)P(O)OH and Ag_(2)CO_(3) properly tune the redox potential of ruthenium catalyst and leads to mild reaction conditions. The protocol exhibits broad functional group tolerance and allows the late-stage functionalization of complex bioactive molecules.Yaohang Cheng Xian Zhang Guanghui An Guangming Li Zhenyu Yang 2023Chinese Chemical Letters2023,34,3:1
2Ruthenium(Ⅱ)-catalyzed para-selective C—H difluoroalkylation of aromatic aldehydes and ketones using transient directing groups显示文摘A Ru(Ⅱ)-catalyzed para-difluoroalkylation of aro matic alde hydes and ketones with a tra nsient directing group has been developed.It utilizes less expensive ruthenium catalysts and allows facile access to challenging difluoroalkylated aldehydes.The mechanism studies suggest that the distinct coordination mode of ruthenium complex with imine moieties is responsible for para-selectivity.Yaohang Cheng Yuhang He Jie Zheng Hui Yang Jun Liu Guanghui An Guangming Li 2021Chinese Chemical Letters2021,32,4:1
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