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| 1 | Mesoporous vanadium pentoxide nanofibers with significantly enhanced Li- ion storage properties by eleetrospinning显示文摘 | Yu Danmei Chen Changguo Xie Shuhong | 2011 | Energy Environ Sci2011，4，3： | 1 |
| 2 | The preparation and performance of high activity Ni-Cr binary catalysts for direct borohydride fuel cells显示文摘Ni-Cr binary anode catalysts used in direct borohydride fuel cells (DBFCs) were prepared using a constant potential electrodepo- sition method. Compared with pure metal Ni catalysts, the electro-oxidation currents of borohydride ions (BH-4) more than doubled when using Ni-Cr binary catalysts under the same conditions. The enhanced activity of the Ni-Cr binary catalysts could be attributed to the change in distribution of BH-4ions on the surface of the Ni electrode. This is due to Cr electrodeposits, which allows a greater number of hydrogen atoms to catalyze from each tetrahedron BH-4 ion. The performance of Ni-Cr binary catalysts could also be improved by optimizing the electrodeposition conditions. The results show that Ni-Cr binary catalysts are optimally prepared using an electrodeposition method of 1s with a Cr3+ concentration of 0.2 mol L-1 and a potential of -0.100 V. | YU DanMei SHEN Yan YE Zhen WEN JiaZhi WANG Jie CHEN ChangGuo | 2013 | Chinese Science Bulletin2013，58，20： | 1 |
| 3 | 显示文摘 | Yu Danmei Zhou Shangqi Chen Changguo | 2004 | J Chongqing Univ Eng Ed2004，3，1： | 1 |
| 4 | Bismuth clusters pinned on TiO_(2) porous nanowires boosting charge transfer for CO_(2) photoreduction to CH_(4)显示文摘Artificial photosynthesis in carbon dioxide(CO_(2))conversion into value-added chemicals attracts considerable attention but suffers from the low activity induced by sluggish separation of photogenerated carriers and the kinetic bottleneck-induced unsatisfied selectivity.Herein,we prepare a new-style Bi/TiO_(2) catalyst formed by pinning bismuth clusters on TiO_(2) nanowires through being confined by pores,which exhibits high activity and selectivity towards photocatalytic production of CH_(4) from CO_(2).Boosted charge transfer from TiO_(2) through Bi to the reactants is revealed via in situ X-ray photon spectroscopy and time-resolved photoluminescence(PL).Further,in situ Fourier transform infrared results confirm that Bi/TiO_(2) not only overcomes the multi-electron kinetics challenge of CO_(2) to CH_(4) via boosting charge transfer,but also facilitates proton production and transfer as well as the intermediates*CHO and*CH_(3)O generation,ultimately achieving the tandem catalysis towards methanation.Theoretical calculation also underlies that the more favorable reaction step from*CO to*CHO on Bi/TiO_(2) results in CH_(4) production with higher selectivity.Our work brings new insights into rational design of photocatalysts with high performance and the formation mechanism of CO_(2) to CH_(4) for solar energy storage in future. | Jiazhi Meng Kaiwen Wang Yang Wang Jiangping Ma Chaogang Ban Yajie Feng Bin Zhang Kai Zhou Liyong Gan Guang Han Danmei Yu Xiaoyuan Zhou | 2024 | Nano Research2024，17，3： | 0 |
| 5 | Study on the electronic structure of nickel hydroxide by quantum chemical DV-Xα calculation显示文摘The electronic structures of atom clusters Ni7O12H122+ and Ni7O12H9-of β-Ni(OH)2 were calculated by quantum chemical DV-Xα method. By analyzing the state densities, orbital populations, net charges and electric charge density differences of the selected clusters, it was indicated that β-Ni(OH)2 was not typical ionic crystal, and the bonds between Ni and O atoms had obvious covalent characteristics. The bonds between H atom and other atoms in the crystal structure were weaker, which ensured that H atoms can easily deintercalate and intercalate into β-Ni(OH)2. The structure of β-Ni(OH)2 was not changed by moderate de-intercalation of H atoms. However, with the excessive de-intercalation of H atoms, the structure of β-Ni(OH)2 changed and the electrochemical active properties were reduced. | YU DanMei CHEN ChangGuo SI YuJun ZHOU ShangQi WANG Li | 2008 | Chinese Science Bulletin2008，53，1： | 0 |
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