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| 1 | Study on the viscoelastic behavior of SEEPS block copolymer based on a modified BSW model显示文摘Studies on the viscoelastic behavior of styrene- [ethylene-(ethylene-propylene)]-styrene block copolymer (SEEPS) were carried out, and some characteristic viscoelas-tic parameters were calculated. The longest relaxation time τmax was obtained through simulating the relaxation spec-trum on the basis of a modified Baumgaertel-Schausberger- Winter (mBSW) model. The results revealed that there exists a “second plateau” in the low frequency region of the master curves. The reason for this phenomenon is attributed to the entanglement of macromolecular chains. It is suggested that the hard blocks, polystyrene, act as entanglement points, resulting in a topology restraint to the movement of macro-molecular chains. Meanwhile, it is found that the horizontal shift factors (aT) vs temperature in the master curve could be fitted to the Williams-Landel-Ferry (WLF) equation and Ar-rhenius equation respectively and the flow activation energy (Ea) is 127.88 kJ/mol. In addition, the plateau modulus (GN0) and entanglement molecule weight (Me) were calculated. | WANG Wanjie ZHENG Qiang YU Qiuming | 2005 | Chinese Science Bulletin2005，50，19： | 2 |
| 2 | Optical elements with subwavelength stmctured surfaces显示文摘 | Toyota H Yu Wanji | 2004 | Proceedings of SPIE2004，5515，： | 1 |
| 3 | Synthesis of polarization-selective optical components with multi-layer subwavelength structures显示文摘 | Kikuta H Konishi T | 2003 | Proceedings of SHE2003，5183，： | 1 |
| 4 | Performances of an all-optical subtracted joint transform correlator that uses a photorefractive crystal显示文摘 | Takumi Minemoto | 2000 | Optical and Quantum Electronics2000，32，： | 1 |
| 5 | Fast Bulky Anion Conduction Enabled by Free Shuttling Phosphonium Cations显示文摘Highly conductive anion-exchange membranes(AEMs)are desirable for applications in various energy storage and conversion technologies.However,conventional AEMs with bulky HCO3-or Br-as counterion generally exhibit low conductivity because the covalent bonding restrains the tethered cationic group’s mobility and rotation.Here,we report an alternative polyrotaxane AEM with nontethered and free-shuttling phosphonium cation.As proved by temperature-dependent NMR,solid-state NMR,and molecular dynamics simulation,the phosphonium cation possesses a thermally trigged shuttling behavior,broader extension range,and greater mobility,thus accelerating the diffusion conduction of bulky anions.Owing to this striking feature,high HCO_(3)-conductivity of 105 mS cm^(-1) at 90℃ was obtained at a relatively lower ion-exchange capacity of 1.17 mmol g^(-1).This study provides a new concept for developing highly conductive anion-exchange membranes and will catalyze the exploration of new applications for polyrotaxanes in ion conduction processes. | Xiaolin Ge Yubin He Kaiyu Zhang Xian Liang Chengpeng Wei Muhammad A.Shehzad Wanjie Song Zijuan Ge Geng Li Weisheng Yu Liang Wu Tongwen Xu | 2022 | Research2022，，1： | 0 |
| 6 | Fast Bulky Anion Conduction Enabled by Free Shuttling Phosphonium Cations显示文摘Highly conductive anion-exchange membranes(AEMs)are desirable for applications in various energy storage and conversion technologies.However,conventional AEMs with bulky HCO_(3)^(-)or Br-as counterion generally exhibit low conductivity because the covalent bonding restrains the tethered cationic group’s mobility and rotation.Here,we report an alternative polyrotaxane AEM with nontethered and free-shuttling phosphonium cation.As proved by temperature-dependent NMR,solid-state NMR,and molecular dynamics simulation,the phosphonium cation possesses a thermally trigged shuttling behavior,broader extension range,and greater mobility,thus accelerating the diffusion conduction of bulky anions.Owing to this striking feature,high HCO_(3)^(-)conductivity of 105 mS cm^(-1)at 90℃ was obtained at a relatively lower ion-exchange capacity of 1.17 mmol g^(-1).This study provides a new concept for developing highly conductive anion-exchange membranes and will catalyze the exploration of new applications for polyrotaxanes in ion conduction processes. | Xiaolin Ge Yubin He Kaiyu Zhang Xian Liang Chengpeng Wei Muhammad A.Shehzad Wanjie Song Zijuan Ge Geng Li Weisheng Yu Liang Wu Tongwen Xu | 2021 | Research2021，，1： | 0 |
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