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1篇 您的检索式:作者名="Yuandui Bi"
    题名 作者 年代 出处 被引量
1Improved method for analyzing the degradation of estrogens in water by solid-phase extraction coupled with ultra performance liquid chromatography-ultraviolet detection显示文摘We established an improved method for the determination of four estrogens including estriol (E3), 17β-estradiol (E2), 17α-ethynyl-estrodiol (EE2) and estrone (E1) in water. The method consisted of solid-phase extraction (0.5 L water) and subsequent analysis of analytes by ultra-performance liquid chromatography (UPLC) with an ultraviolet detector (UVD). Base-line separation was achieved for all studied estrogens using a column (50 mm × 2.1 mm) packed with 1.7 μm particle size stationary phase. Recovery was higher than 88% and detection limits ranged between 12.5-23.7 ng/L for the four estrogens, with the RSD ranging from 7% to 11%. The method was successfully applied to determine E2 and EE2 in simulated natural water, which found that about 70% of E2 was degraded (with a half-life of about 30 hr) within 48 hr and about 55% of EE2 was degraded (with a half-life of about 36 hr). Low levels of E1 were found, however E3 was undetectable during the process.Minggang Zheng Ling Wang Yuandui Bi Feng Liu 2011Journal of Environmental Sciences2011,23,4:2
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