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| 1 | Effect of calcination temperature on structure and performance of Ni/TiO_2-SiO_2 catalyst for CO_2 reforming of methane显示文摘为在气压下面甲烷改过到合成气体的公司 2 ,结构和 Ni/TiO 2-SiO2 催化剂的催化行为上的锻烧温度的影响被调查。当催化剂在低的有的 550 和 850 ° C 和不稳定的活动锻烧时,结果证明在 700 ° C 锻烧的 Ni/TiO 2-SiO2 催化剂举办了高、稳定的活动。取决于锻烧温度,一,二,或三下列包含 Ni 种, NiO, Ni 2.44 Ti 0.72 Si 0.07 O 4, 和 NiTiO 3 被联合温度识别规划减小(TPR ) 和 X 光检查衍射(XRD ) 结果。他们的 reducibility 在顺序减少了:NiO >
Ni 2.44 Ti 0.72 Si 0.07 O 4>
NiTiO 3 。它建议高、稳定的活动在在 700 点锻烧的 Ni/TiO 2-SiO2 催化剂上观察到° C 被 Ni 2.44 Ti 0.72 Si 0.07 O 4 和更小的 NiO 种类雏晶缩放。 | Sanbing Zhang Jiankang Wang Xiaolai Wang | 2008 | Journal of Natural Gas Chemistry2008，17，2： | 5 |
| 2 | Effect of the operation parameters on the Fischer-Tropsch synthesis in fluidized bed reactors显示文摘For the Fischer-Tropsch synthesis(FTS), this paper presents a numerical investigation in a 3 D fluidized bed reactor. The effect of the operation parameters such as bed temperature, superficial gas velocities, particle size and bed heights is discussed. A 3 D-CFD model coupled with FTS chemical kinetics was set up. The computational results are compared with experimental data in terms of the components production rates, etc. The analysis shows that the bed heights, the bed temperature, the superficial gas velocities and particle sizes affect the C_(5+) selectivity and the reaction rates. Product yields are dependent on the operating conditions especially the temperature. | Xiaolai Zhang Weixin Qian Haitao Zhang Qiwen Sun Weiyong Ying | 2018 | Chinese Journal of Chemical Engineering2018，26，2： | 3 |
| 3 | Numerical simulation of effect of gas distributor on Fischer-Tropsch synthesis in fluidized-bed reactor显示文摘Circular and branched pipe distributors were designed for Fischer-Tropsch synthesis in a fluidized-bed reactor. A numerical investigation of the effects of these distributors on product selectivity and production rate was performed. Under the same conditions, the circular distributor gave higher production rates for small diameter particles. For superficial gas velocities ranging from 5 to 15 times the minimum fluidization velocity, the production rates of methane and C5+(the sum of C10H22 and C22H46)were 18%, which was 2% higher than those using the branched pipe distributor, while the C5+ selectivity was 1% lower. For deeper beds, the circular distributor led to higher production rates and the selectivity for C5+ was 5% lower than that using the branched pipe distributor. | Xiaolai Zhang Guangwei Zhai Weixin Qian Haitao Zhang Qiwen Sun Weiyong Ying | 2019 | Particuology2019，17，4： | 2 |
| 4 | Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products显示文摘By exchanging the conventional role of functional monomer and template molecules,we develop a new molecu-larly imprinted nanospheres with grape grain structures based on multi-hydrogen bonding interactions between melamine and 6-aminouracil.Molecular imprinting-electrochemical sensor was established with the assistance of graphene and ionic liquids.The content of melamine in dairy products was detected by the molecular imprinting-electrochemical sensor.The detection limit was determined to be as low as 1.57×10^(−3) mg kg^(-1). | Peini Zhao Xiaolai Zhang Jingcheng Hao | 2022 | ChemPhysMater2022，1，3： | 0 |
| 5 | Online measurement of solids motion in fluidized bed reactor with different distributor for Fischer–Tropsch synthesis显示文摘In this paper, the distributions of particle velocity in a gas–solid fluidized bed with branched pipe distributor or circle distributor were measured by using a laser Doppler velocimetry. Our results show that, within a certain range of superficial gas velocity, when using circle distributor, the particle velocity is large and the distribution of the particle velocity is even more compared with the branched pipe distributor. On the basis of the amplitude of tangential movement statistics, the amplitude of tangential movement statistics(AVATMS) decreases with increasing the axial height under the appropriate superficial gas velocity. | Xiaolai Zhang Weixin Qian Haitao Zhang Qiwen Sun Weiyong Ying | 2018 | Chinese Journal of Chemical Engineering2018，26，10： | 0 |
| 6 | Effects of dietary Clostridium butyricum and rumen protected fat on meat quality,oxidative stability,and chemical composition of finishing goats显示文摘Background Clostridium butyricum(CB)is a probiotic that can regulate intestinal microbial composition and improve meat quality.Rumen protected fat(RPF)has been shown to increase the dietary energy density and provide essential fatty acids.However,it is still unknown whether dietary supplementation with CB and RPF exerts beneficial effects on growth performance and nutritional value of goat meat.This study aimed to investigate the effects of dietary CB and RPF supplementation on growth performance,meat quality,oxidative stability,and meat nutritional value of finishing goats.Thirty-two goats(initial body weight,20.5±0.82 kg)were used in a completely randomized block design with a 2 RPF supplementation(0 vs.30 g/d)×2 CB supplementation(0 vs.1.0 g/d)factorial treatment arrangement.The experiment included a 14-d adaptation and 70-d data and sample collection period.The goats were fed a diet consisted of 400 g/kg peanut seedling and 600 g/kg corn-based concentrate(dry matter basis).Result Interaction between CB and RPF was rarely observed on the variables measured,except that shear force was reduced(P<0.05)by adding CB or RPF alone or their combination;the increased intramuscular fat(IMF)content with adding RPF was more pronounced(P<0.05)with CB than without CB addition.The pH24h(P=0.009),a*values(P=0.007),total antioxidant capacity(P=0.050),glutathione peroxidase activities(P=0.006),concentrations of 18:3(P<0.001),20:5(P=0.003)and total polyunsaturated fatty acids(P=0.048)were increased,whereas the L*values(P<0.001),shear force(P=0.050)and malondialdehyde content(P=0.044)were decreased by adding CB.Furthermore,CB supplementation increased essential amino acid(P=0.027),flavor amino acid(P=0.010)and total amino acid contents(P=0.024)as well as upregulated the expression of lipoprotein lipase(P=0.034)and peroxisome proliferator-activated receptorγ(PPARγ)(P=0.012),and downregulated the expression of stearoyl-CoA desaturase(SCD)(P=0.034).The RPF supplementation increased dry matter intake(P=0.005),averaged daily gain(trend,P=0.058),hot carcass weight(P=0.046),backfat thickness(P=0.006),concentrations of 16:0(P<0.001)and c9-18:1(P=0.002),and decreased the shear force(P<0.001),isoleucine(P=0.049)and lysine content(P=0.003)of meat.In addition,the expressions of acetyl-CoA carboxylase(P=0.003),fatty acid synthase(P=0.038),SCD(P<0.001)and PPARγ(P=0.022)were upregulated due to RPF supplementation,resulting in higher(P<0.001)content of IMF.Conclusions CB and RPF could be fed to goats for improving the growth performance,carcass traits and meat quality,and promote fat deposition by upregulating the expression of lipogenic genes of Longissimus thoracis muscle. | Meimei Zhang Zhiyue Zhang Xinlong Zhang Changming Lu Wenzhu Yang Xiaolai Xie Hangshu Xin Xiaotan Lu Mingbo Ni Xinyue Yang Xiaoyang Lv Peixin Jiao | 2024 | Journal of Animal Science and Biotechnology2024，15，2： | 0 |
| 7 | Synthesis and Performance of an Associative Anti-shear Drag Reducer Based on Hydrogen Bond Association of Dodecyl Methacrylate显示文摘Using K2S2O8-Na2SO3 as the redox initiation system,a hydrogen-bond-association-based dodecyl methacrylate system associative anti-shear drag reducer was synthesised by standard emulsion polymerisation.The reaction process was simple and gentle as well as safe and stable.Molecular design was carried out using molecular dynamics simulation methods.The results of infrared spectroscopy,thermogravimetric analysis,differential scanning calorimetry,gel chromatography,and laser light scattering showed that the reaction polymerisation was relatively complete,the product was uniform,the molecular weight distribution was controllable,and the synthesised polymer had good flexibility.The donor lauryl methacrylate-styrene-methacrylic acid(LMA-St-MAA)and acceptor lauryl methacrylate-styrene-dimethylaminoethyl methacrylate(LMA-St-DMA)polymers had an associative intermolecular interaction force,which increased the molecular cluster size of the associative system complex.The complex had good shear resistance,and the test results of the tube pump shear test showed that the synthesised associative oil-soluble polymer drag reduction system exhibited better drag reduction rate performance than poly-α-olefins over repeated cycles.The research results provide a reference plan for minimising the number of station-to-station inputs,thereby ensuring the stability of oil pipelines and reducing transportation costs. | Lu Yong Li Chenhao Li Hao Chen Yue Xu Dan Wang Yiran Meng Yeqiao Zhang Xiaolai | 2023 | China Petroleum Processing & Petrochemical Technology2023，25，1： | 0 |
| 8 | Preparation of Poly-α-Olefin Microcapsule Particles Coated with Polyurethane as a Drag Reducer Based on Interface Polymerization显示文摘The molecular behavior of polyurethane(PU)coating materials during the surface adsorption of poly-α-olefin as a drag reducing polymer was explored by a molecular dynamics simulation.Three different PU capsule wall materials were synthesized using two reaction monomers,and a poly-α-olefin/PU drag reducer microcapsule was prepared based on interface polymerization.The structure,morphology,thermal stability,compressive strength,and drag reduction performance of the microcapsules were characterized and compared.The results showed that a non-bonding interaction induced the adsorption of the PU coating material,poly-α-olefin and PU then fused at the interface,and the PU coating material was embedded into the inner grooves of poly-α-olefin in the form of a local mosaic,thereby forming a stable core–shell structure.The morphological characterization indicated that PU and poly-α-olefin could form microcapsule structures.The thermal decomposition temperature of the microcapsule was dependent on the type of capsule wall material.The microcapsule structure had a slight effect on poly-α-olefin drag reduction.The system enabled poly-α-olefin to exist in powdered particles through microcapsulation,and had a good dispersion effect that facilitated storage and transport processes.The method effectively inhibited the accumulation and bonding of poly-α-olefin at room temperature. | Li Chenhao Lu Yong Li Hao Chen Yue Meng Yeqiao Zhou Pengfei Xu Dan Wang Yiran Zhang Xiaolai | 2023 | China Petroleum Processing & Petrochemical Technology2023，25，2： | 0 |
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