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1Study of borohydride ionic liquids as hydrogen storage materials显示文摘Stability of borohydrides is determined by the localization of the negative charge on the boron atom.Ionic liquids(ILs) allow to modify the stability of the borohydrides and promote new dehydrogenation pathways with a lower activation energy. The combination of borohydride and IL is very easy to realize and no expensive rare earth metals are required. The composite of the ILs with complex hydrides decreases the enthalpy and activation energy for the hydrogen desorption. The Coulomb interaction between borohydride and IL leads to a destabilization of the materials with a significantly lower enthalpy for hydrogen desorption. Here, we report a simple ion exchange reaction using various ILs, such as vinylbenzyltrimethylammonium chloride([VBTMA][Cl]), 1-butyl-3-methylimidazolium chloride([bmim][Cl]), and 1-ethyl-1-methylpyrrolidinium bromide([EMPY][Br]) with NaBH4 to decrease the hydrogen desorption temperature. Dehydrogenation of 1-butyl-3-methylimidazolium borohydride([bmim][BH4]) starts below 100℃. The quantity of desorbed hydrogen ranges between 2.4 wt% and 2.9 wt%, which is close to the theoretical content of hydrogen. The improvement in dehydrogenation is due to the strong amine cation that destabilizes borohydride by charge transfer.Loris Lombardo Heena Yang Andreas Züttel 2019Journal of Energy Chemistry2019,28,6:2
2The influence of cobalt on the electrochemical cycling stability of LaNi5-based hydride forming alloys 显示文摘Daniel Chartouni Felix Meli Andreas Zü ttel 1996J Alloys Comp1996,241,:2
3The heat shock protein 70 family: Highly homologous proteins with overlapping and distinct functions显示文摘DAUGAARD M ROHDE M J))TTEL)M 2007FEBS Lett2007,581,19:1
4The different modes for absorbing knowledge: an analytic lens on absorptive capacity from a process perspective 显示文摘FILIPPINI R G1]TTEL W H NEIROTTI P NOSELLA A 2012Interna- tional Journal of Knowledge Management Studies2012,5,1:1
5The influence of cobalt on the electrochemical cycling stability of LaNi5-based hydride forming alloys显示文摘Chartouni D Meli F Züttel 1996J Alloys and Comp1996,,241:1
6BLR:beacon-less routing algorithm for mobile ad-hoc networks显示文摘Heissenbüttel M Braun T Bernoulli T W(a)lchli M 2004Elsevier Computer Communication2004,27,11:1
7Organizational antecedents ofpay-for-performance systems in nonprofit organizations显示文摘Brandl J Güttel W H 2007Voluntas: International Journal of Voluntary andNonprofit Organizations2007,18,2:1
8Hydrogen storage in carbon nanostructures显示文摘Züttel A Sudan P Mauron P 2002Int J Hydrogen Energy2002,27,:1
9The dynamic capability view in strategic management:A bibliometric review显示文摘Vogel R G ttel W H 0,,:1
10Immediate loading of two unsplinted mandibular implants in edentulous patients with an implant-retained overdenture: an observational study over two years显示文摘Büttel AE Gratwohl DA Sendi P 2012Schweiz Monatsschr Zahnmed2012,122,5:1
11Mechanically milled Mg composites for hydrogen storage the transition to a steady state composition显示文摘 SPATZ P Z(U)TTEL A 1996J Alloys and Compounds1996,240,12:1
12LiBH4 a new hydrogen storage material显示文摘Z(U)TTEL A WENGER P RENTSCH S 2003J Power Sources2003,118,:1
13Acquired antiestrogen resistance in MCF-7 human breast cancer sublines is not accomplished by altered expression of receptors in the ErbB-family显示文摘S?ren S. Larsen Mikala Egeblad Marja J??ttel? Anne E. Lykkesfeldt 1999Breast Cancer Research and Treatment1999,,1:1
14Materials for Hydrogen Storage显示文摘ZTTEL A 2003Mater Today2003,6,:1
15显示文摘Züttel A Meli F Schlapbach L 1994J Alloys Comp1994,209,:1
16Hydrogen-storage Materials for Mobile Applications显示文摘SCHLAPBACH L ZTTEL A 2001Nature2001,414,:1
17Materials for hydrogen storage显示文摘ZüTTEL A 2003Materials Today2003,6,9:1
18Hydrogen-storage materials for mobile application显示文摘Schlapbach L Züttel A 2001Nature2001,414,:1
19Hydrogen-storage materials for mobile applications显示文摘SCHLAPBACH L ZI]TTEL A 2001Nature2001,414,6861:1
20Hydrogen storage methods显示文摘Züttel A 2004Nature2004,91,:1
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