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| 1 | One-pot synthesis of thermally stable gold@mesoporous silica core-shell nanospheres with catalytic activity显示文摘一个灵巧的一个壶方法被开发了综合一致 gold@mesoporous 硅石 nanospheres (Au@MSNs ) ,它作为壳与订的 mesoporous 硅石有明确的核心壳结构。产生 Au@MSNs 为 mesoporous 硅石壳有一个高表面区域(521 m2/g ) 和一致毛孔尺寸(2.5 nm ) 。金核心的直径能被调整 HAuCl4 的数量调整。Au@MSNs 的催化表演作为模型反应用 4-nitrophenol 的减小被调查。硅石壳的 mesopores 提供直接存取让反应物分子与金核心扩散并且随后交往。另外, Au@MSNs 显示到 950 | Junchen Chen Renyuan Zhang Lu Han Bo Tu Dongyuan Zhao | 2013 | Nano Research2013，6，12： | 13 |
| 2 | Monodisperse core-shell structured magnetic mesoporous aluminosilicate nanospheres with large dendritic mesochannels显示文摘合理设计和有一个定制的活跃核心和大、树枝状的、修改 mesoporous 的多功能的混合 nanostructures 的精确合成组织了壳能支持催化作用,精力存储,和生物应用。这里,油水双相层化涂层策略被开发了准备 monodisperse 磁性的树枝状的 mesoporous 硅石核心壳结构化的 nanospheres。这些复杂 Fe 3 O 4@SiO2@dendritic-mSiO2 nanospheres 特征大树枝状的开的毛孔(2.7 和 10.3 nm ) 。显著地,硅石壳能与未改变的孔, 14 的 Si/Al 臼齿的比率,和显著地强壮的酸的地点被变换成树枝状的 mesoporous 铝矽酸盐框架,通过一条合成以后的途径。另外,结果的磁性的树枝状的 mesoporous 铝矽酸盐 nanospheres 展览在从废水的磷酸盐移动的突出的性质和有希望的申请。 | Jianping Yang Dengke Shen Yong Wei Wei Li Fan Zhang Biao Kong Shaohua Zhang Wei Teng Jianwei Fan Weixian Zhang Shixue Dou Dongyuan Zhao | 2015 | Nano Research2015，8，8： | 11 |
| 3 | A single Au nanoparticle anchored inside the porous shell of periodic mesoporous organosilica hollow spheres显示文摘理想的金属催化剂对沥滤或粒子凝块与反应试剂,很多暴露的活跃地点,和高稳定性要求容易的接触。抛锚尽管几乎没报导,在多孔的壳内的一个金属核心可以由于常规支持的金属安排的集成把这些优点合为 core@void@shell 体系结构。然而,完成这由于弱 coreshell 亲密关系是极其困难的。此处,第一次,我们报导一条途径由增加核心壳相互作用克服这挑战。在这方面,我们综合了一个单个 Au 核心是的新奇 Au@void@periodic mesoporous organosilica (PMO ) 在体系结构坚定地在空 PMO 范围的多孔的壳内抛锚了。在之间的非共有原子价相互作用(vinylpyrrolidone )(PVP ) poly,一些 functionalized Au 和 PMO 的乙烷一半向多孔的壳便于 Au 核心的运动在期间 Au@SiO2@PMO 的选择碱的蚀刻。抛锚壳的 Au 核心以与活跃地点的试剂和暴露的接触比在常规 Au@void@PMO 的推迟的核心优异,并且因此为 4-nitrophenol 减小显示出更高催化的效率。这里表明的方法论提供新卓见因为有核心的万用的多功能的 nanostructures 的制造在空壳内抛锚了。 | Ying Yang Wen Zhang Ying Zhang Anmin Zheng Hui Sun Xinsong Li Suyan Liu Pengfang Zhang Xin Zhang | 2015 | Nano Research2015，8，10： | 3 |
| 4 | Inorganic shell nanostructures to enhance performance and stability of metal nanoparticles in catalytic applications显示文摘In this article,we review the recent progress and our research activity on the synthesis of inorganic shell nanostructures to enhance the catalytic performance and stability of metal nanoparticles in catalytic applications.First,we introduce general synthetic strategies for the fabrication of inorganic nanoscale shell layers,including template-assisted sol-gel coating,hydrothermal(or solvothermal)synthesis and the self-templating process.We also discuss recent examples of metal nanoparticles(NPs)with nanoscale shell layers,namely core-shell,yolk-shell and multiple NPs-embedded nanoscale shell.We then discuss the performance and stability of metal particles in practical catalytic applications.Finally,we conclude with a summary and perspective on the further progress of inorganic nanostructure with nanoscale shell layers for catalytic applications. | Inhee Choi Hyeon Kyeong Lee Gyoung Woo Lee Jiyull Kim Ji Bong Joo | 2020 | Rare Metals2020，39，7： | 2 |
| 5 | Novel Combination Therapy for Triple-Negative Breast Cancer based on an Intelligent Hollow Carbon Sphere显示文摘Triple-negative breast cancer(TNBC)is a subtype of breast cancer with high mortality,and the efficacy of monotherapy for TNBC is still disappointing.Here,we developed a novel combination therapy for TNBC based on a multifunctional nanohollow carbon sphere.This intelligent material contains a superadsorbed silicon dioxide sphere,sufficient loading space,a nanoscale hole on its surface,a robust shell,and an outer bilayer,and it could load both programmed cell death protein 1/programmed cell death ligand 1(PD-1/PD-L1)small-molecule immune checkpoints and small-molecule photosensitizers with excellent loading contents,protect these small molecules during the systemic circulation,and achieve accumulation of them in tumor sites after systemic administration followed by the application of laser irradiation,thereby realizing dual attack of photodynamic therapy and immunotherapy on tumors.Importantly,we integrated the fasting-mimicking diet condition that can further enhance the cellular uptake efficiency of nanoparticles in tumor cells and amplify the immune responses,further enhancing the therapeutic effect.Thus,a novel combination therapy“PD-1/PD-L1 immune checkpoint blockade+photodynamic therapy+fasting-mimicking diet”was developed with the aid of our materials,which eventually achieved a marked therapeutic effect in 4T1-tumor-bearing mice.The concept can also be applied to the clinical treatment of human TNBC with guiding significance in the future. | Yue Yin Yaping Yan Biao Fan Wenping Huang Jie Zhang Hai-Yan Hu Xiaoqiong Li Dongbin Xiong Shu-Lei Chou Yao Xiao Hai Wang | 2023 | Research2023，，4： | 1 |
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