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| 1 | 三氟甲基化试剂的研究进展显示文摘近年来,三氟甲基化成为有机氟化学的研究热点,其主要驱动力是含有三氟甲基基团的有机分子常常表现出独特的物理和化学性质,具有广泛的应用。三氟甲基试剂是向目标分子中引入三氟甲基基团的重要方法之一。综述了三氟甲基化试剂的类型、特点、适用范围等,并对三氟甲基试剂的应用前景作出了展望。 | 牛腾 杨天宇 邓周斌 姜立萍 魏惠荣 刘琦敏 张慧芳 郭昊岩 | 2022 | 化学试剂2022，44，12： | 0 |
| 2 | Neutral Five-Coordinate Arylated Copper(Ⅲ) Complex: Key Intermediate in Copper-Mediated Arene Trifluoromethylation显示文摘Five-coordinate neutral Cu(Ⅲ)complexes have long been considered as the key intermediates in copper-mediated/catalyzed arene trifluoromethylative reactions,but the identity of these complexes remains elusive.Herein,we reported,for the first time,the preparation and characterization of these putative complexes[(bpy)Cu(CF_(3))_(2)(C_(6)F_(4)R)]and investigation of their C(sp^(2))-CF_(3) bond-forming reductive elimination.Our mechanistic studies including kinetic studies,the effect of temperature and solvents,the effect of the para-substitution of the ligand as well as DFT calculations suggest that C(sp^(2))-CF_(3) reductive elimination process proceeds via synchronous bond-breaking/bond-forming process. | Guangyu Wang Man Li Xuebing Leng Xiaosong Xue Qilong Shen | 2022 | Chinese Journal of Chemistry2022，40，16： | 0 |
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