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1N_2-Ar-He systematics and source of ore-forming fluid in Changkeng Au-Ag deposit, central Guangdong, China显示文摘Changkeng Au-Ag deposit is a newly-discovered new type precious metal deposit. N2-Ar-He systematics studies and 3He/4He and δD-δ18O composition analyses show that the ore-forming fluid of the deposit is composed mainly of formation water (sedimentary brine) but not of meteoric water, which was thought to be source of the ore-forming fluid by most previous researchers. The content of mantle-derived magmatic water in the ore-forming fluid is quite low, usually lower than 10%. According to the source of the ore-forming fluid, the Changkeng Au-Ag deposit should belong to sedimentary brine transformed deposits. From the Late Jurassic to the Early Cretaceous Period, with deposition and accumulation of thick sediments in Sanzhou Basin, the formation water in the sedimentary layers was expelled from the basin because of overburden pressure and increasing temperature. The expelled fluid moved laterally along sedimentary layers to the margin of the basin, and finally moved upward along a gently-dipping孙晓明 孙凯 陈炳辉 陈敬德 David I.Norman 1999Science China Earth Sciences1999,42,5:12
2Organic Gases in Fluid Inclusions of Ore Minerals and Their Constraints on Ore Genesis:A Case Study of the Changkeng Au-Ag Deposit,Guangdong,China显示文摘The newly discovered Changkeng Au-Ag deposit is a new type of sediment-hosted precious metal deposit. Most of the previous researchers believed that the deposit was formed by meteoric water convection. By using a high vacuum quadrupole gas mass spectrometric system, nine light hydrocarbons have been recognized in the fluid inclusions in ore minerals collected from the Changkeng deposit. The hydrocarbons are composed mainly of saturated alkanes C1-4 and unsaturated alkenes C2-4 and aromatic hydrocarbons, in which the alkanes are predominant, while the contents of alkenes and aromatic hydrocarbons are very low. The Σalka/Σalke ratio of most samples is higher than 100, suggesting that those hydrocarbons are mainly generated by pyrolysis of kerogens in sedimentary rocks caused by water-rock interactions at medium-low temperatures, and the metallogenic processes might have not been affected by magmatic activity. A thermodynamic calculation shows that the light hydrocarbons have reached chemical equilibrium at temperatures higher than 200?C, and they may have been generated in the deep part of sedimentary basins (e.g., the Sanzhou basin) and then be transported by ore-forming fluids to a shallow position of the basin via a long distance. Most of the organic gases are generated by pyrolysis of the type II kerogens (kukersite) in sedimentary host rocks, only a few by microorganism activity. The compositions and various parameters of light hydrocarbons in gold ores are quite similar to those in silver ores, suggesting that the gold and silver ores may have similar metallogenic processes. Based on the compositions of organic gases in fluid inclusions, the authors infer that the Changkeng deposit may be of a tectonic setting of continental rift. The results of this study support from one aspect the authors' opinion that the Changkeng deposit is not formed by meteoric water convection, and that its genesis has a close relationship with the evolution of the Sanzhou basin, so it belongs to the sedimentary hot brine transformed deposit.DavidI.NORMAN 2003Acta Geologica Sinica(English Edition)2003,77,1:5
3Light hydrocarbon in ore-forming fluids and its constraints on ore genesis——A case study on Changkeng large-scale Au-Ag deposit, central Guangdong, China显示文摘ORGANIC matters in the ore-forming fluids are composed mainly of light hydrocarbons. Because of the small amount of hydrocarbons in fluid inclusions, it is quite difficult to study their behavior in mineralizing processes, excepting methane (CH4). In this work, we used a high vacuum quadrupole gas massspectrometer system to determine the content and composition of light hydrocarbons (C1-7) in fluid inclusions in minerals collected from Changkeng Au-Ag deposit. The geological significance of the new data forgenesis of the deposit has been discussed briefly.D. l. Norman 1999Chinese Science Bulletin1999,44,S2:0
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