|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | 地质样品Sr同位素激光原位等离子体质谱(LA-MC-ICP-MS)测定显示文摘Sr同位素在研究岩浆演化及其源区具有重要的示踪作用。MC-ICP-MS的出现为具有高Sr含量地质样品的激光原位Sr同位素测定变成了现实。本文利用Netpune MC-ICP-MS和193nm准分子激光联机,通过滨珊瑚、斜长石、磷灰石和钙钛矿等系列实验,建立了激光原位Sr同位素测定方法。实验结果表明,激光Sr同位素测定中Kr、Rb和稀土元素二价离子的干扰能够有效扣除,而钙聚合物的干扰在Neptune型MC-ICP-MS并不显著。不同激光参数的实验表明,大激光束斑产生更高信号强度,因而Sr同位素精度更高,同一激光束斑大小,激光脉冲频率对Sr同位素精度无明显影响。 | 杨岳衡 吴福元 谢烈文 杨进辉 张艳斌 | 2009 | 岩石学报2009，25，12： | 16 |
| 2 | 硒化枸杞多糖的制备及其抗氧化性研究显示文摘以亚硒酸钠和枸杞多糖为原料合成硒化枸杞多糖,电感耦合等离子体质谱法(ICP-MS)测定其中硒含量为64.42 mg/g。利用紫外-可见光谱、红外光谱两种表征手段,证实了硒化枸杞多糖的合成。采用邻二氮菲-Fe2+氧化法和邻苯三酚自氧化法测定硒化枸杞多糖的抗氧化能力,结果表明,在实验设置的浓度范围内,硒化枸杞多糖的抗氧化能力随着浓度的增加而增加,且高于枸杞多糖。2.0 mg/mL的枸杞多糖和硒化枸杞多糖对超氧阴离子自由基的清除率分别为51.48%和59.34%,对羟自由基的清除率分别为50.23%和56.16%。本实验为进一步研究硒化枸杞多糖作为抗氧化能力较强的食品和药品的可能性奠定了基础。 | 郝苗 金黎明 刘李娜 许永斌 马堃 范圣第 | 2014 | 食品研究与开发2014，35，6： | 8 |
| 3 | A Study of the Rhenium-Osmium Geochronometry of Molybdenites显示文摘This study deals with the first application of the isotope dilution - inductively coupled plasma mass spectrometry in the rhenium-osmium geochronometry in China. The chemical separation procedure included decomposition of samples by means of alkali fusion, extraction of rhenium by acetone and extraction of osmium by distillation. The recovery of both elements in the entire process was more than 90% . The blanks of analyses were 0.07 ng for rhenium and 0.01 ng for 187Os. The mineralization ages of molybdenites from four molybdenum deposits in China were determined by using this method, with a precision (2σ)of about ±3% . These results agree satisfactorily with their geological backgrounds. The Re-Os method can directly determine ages of metal deposits and reflect the true ages more reliably than other dating methods that only determine the ages of country rocks from which mineralization ages are inferred. As many hydrothermal sulphide deposits usually contain molybdenites, this method has bright | Du Andao, He Hongliao, Yin Ningwan, Zou Xiaoqiu,Sun Yali, Sun Dezhong, Chen Shaozhen and Qu Wenjun Institute of Rock and Mineral Analysis, Chinese Academy of Geological Sciences, Beijing Fei Zhenbi | 1995 | Acta Geologica Sinica(English Edition)1995，69，2： | 7 |
| 4 | Influence of the electroplating pretreatment on corrosion mechanism of NdFeB magnets显示文摘The electroplating pretreatment of Nd Fe B magnets was simulated in this study, and the effect of the pickling process on element, matrix morphology and texture was discussed. The results showed that in the ordinary circumstance the acid solution concentration should be below 4 mol/L and the pickling time was within 120 s. However the concentration was lower than 1 mol/L and the time was about 30 s in the ultrasonic environment. The precoating technology sequentially was studied. The results revealed that there were two main reactions of the corrosion and displacement in the precoating process, and these two reactions were more obvious in the grain boundary. The electrochemical analysis illustrated that the corrosion and displacement reactions were affected obviously by the current density and the precoating solution temperature, usually the current density was controlled about 0.3 A/dm2, and the temperature was about 318 K in the precoating process. | 周巧英 李刚 刘壮 郭帅 闫阿儒 李东 李建忠 | 2016 | Journal of Rare Earths2016，34，2： | 6 |
| 5 | 封闭酸溶-ICP-MS分析超细地质样品的条件优化显示文摘Using ultra-fine sample for determination 42 elements by pressurized acid digestion -ICP-MS, the mass of test portion can be reduced to 2 mg yet maintain the representation. And acid used for digestion could be reduced to less than 0.5 mL, reaction time also largely reduced. | 何红蓼 孙德忠 | 2005 | 质谱学报2005，26，z1： | 6 |
| 6 | Advances in Tropical Soil Characterization via Portable X-Ray Fluorescence Spectrometry显示文摘Portable X-ray fluorescence(pXRF) spectrometers can be used to determine the elemental composition easily, rapidly, and without using chemical reagents, which is very important for tropical regions due to the lack of detailed soil characterization data. Moreover,pXRF data can be used to predict the results of more expensive, time-consuming, and conventional laboratory analyses. This study sought to determine the elemental composition of various soil profiles using pXRF. Two operational modes(Trace Mode and General Mode) and two scanning time(30 and 60 s) were assessed to determine their effects on the correlation of pXRF dataset with respect to conventional inductively coupled plasma(ICP)-optical emission spectrometry analysis. This relationship has been reported in previous studies, however, few studies were performed on tropical soils, which are unique. Furthermore, such relationships establish the viability of developing prediction models directly from pXRF data. Linear regression was applied to develop calibration models for the prediction of ICP analysis results and exchangeable and available elemental contents based on pXRF data. High coefficients of determination(R^2) were obtained for Ca(0.87), Cu(0.90), Fe(0.95), Mn(0.85), Cr(0.95), V(0.72), and Ni(0.90), with adequate validation. Statistically significant results were not found for Al, K, Zn, Ti, and Zr. The models predicting the exchangeable Ca based on the total Ca from p XRF reached an R^2 of up to 0.85. Operational modes influenced the pXRF results. Our results illustrate that pXRF holds great promise for tropical soil characterization and the development of prediction models, justifying the need for larger-scale studies in tropical countries worldwide. | Elen A. SILVA David C. WEINDORF Sergio H. G. SILVA Bruno T. RIBEIRO Giovana C. POGGERE Teotonio S. CARVALHO Mariana G. M. GONQALVES Luiz R. G. GUILHERME Nilton CURI | 2019 | Pedosphere2019，29，4： | 5 |
| 7 | 微波消解-电感耦合等离子体质谱法测定怀牛膝中重金属元素含量(英文)显示文摘[Objective] The inductively coupled plasma mass spectrometry(ICP-MS)was constructed to determine the contents of lead,cadmium,mercury and arsenic in Archyranthes bidentata Blume.[Method]Under the optimum operation condition of ICP-MS,the samples were digested by microwave.The element 114In was taken as an internal standard element to compensate body effect and ICP-MS method was used to determine the contents of lead,cadmium,mercury and arsenic.[Result]For the determined elements,the correlation coefficient(r)of standard curve was over 0.9995 and recovery rate was from 96.7% to 106.4% while RSD was less than 11.2%.The result of determination showed that the heavy metal content in Archyranthes bidentata Blume.beyond standard was serious.[Conclusion]The constructed ICP-MS method with simple operation,rapid response,accuracy and high sensitivity in this experiment could be used for quality control of Chinese medicinal materials by detecting heavy metal contents in different Chinese medicinal materials from original places. | 李宇伟 王新民 连瑞丽 魏志华 介晓磊 陈士林 | 2008 | Agricultural Science & Technology2008，9，5： | 4 |
| 8 | ICP-MS法分析过氧化氢、硝酸、硫酸中的金属杂质显示文摘Inductively coupled plasma mass spectrometry (ICP-MS) was used to detect trace metal impurities in reagents such as H2O2, HNO3and H2SO4. The limit of detection to metal elements can be down to 2-20 ng/L in H2O2 and HNO3 and 0.1-1.0 ng/L in H2SO4. | 黄曜 黄郁芳 | 2005 | 质谱学报2005，26，z1： | 3 |
| 9 | Frequency dependence of plasma characteristics at different pressures in cylindrical inductively coupled plasma source显示文摘The effects of driving frequency on plasma parameters and electron heating efficiency are studied in cylindrical inductively coupled plasma(ICP) source. Measurements are made in an Ar discharge for driving frequency at 13.56/2 MHz, and pressures of 0.4-1.2 Pa. In 13.56 MHz discharge, higher electron density(n_e) and higher electron temperature(T_e) are observed in comparison with 2 MHz discharge at 0.6-1.2 Pa. However, slightly higher n_e and T_e are observed in 2 MHz discharge at 0.4 Pa. This observation is explained by enhanced electron heating efficiency due to the resonance between the oscillation of 2 MHz electromagnetic field and electron-neutral collision process at 0.4 Pa. It is also found that the variation of T_edistribution is different in 13.56 and 2 MHz discharge.For ICP at 13.56 MHz, T_eshows an edge-high profile at 0.4-1.2 Pa. For 2 MHz discharge, T_e remains an edge-high distribution at 0.4-0.8 Pa. However, the distribution pattern involves into a center-high profile at 0.9-1.2 Pa. The spatial profiles of n_e remain a center-high shape in both 13.56 and 2 MHz discharges, which indicates the nonlocal kinetics at low pressures. Better uniformity could be achieved by using 2 MHz discharge. The effects of gas pressure on plasma parameters are also examined. An increase in gas pressure necessitates the rise of n_e in both 13.56 and 2 MHz discharges. Meanwhile, T_e drops when gas pressure increases and shows a flatter distribution at higher pressure. | 郝泽宇 宋健 滑跃 张改玲 白晓东 任春生 | 2019 | Plasma Science and Technology2019，21，7： | 2 |
| 10 | Interaction of silver nanoparticles with mediterranean agricultural soils: Lab-controlled adsorption and desorption studies显示文摘The production of silver nanoparticles(AgNPs) has increased tremendously during recent years due to their antibacterial and physicochemical properties. As a consequence, these particles are released inevitably into the environment, with soil being the main sink of disposal. Soil interactions have an effect on AgNP mobility, transport and bioavailability. To understand AgNP adsorption processes, lab-controlled kinetic studies were performed.Batch tests performed with five different Mediterranean agricultural soils showed that cation exchange capacity and electrical conductivity are the main parameters controlling the adsorption processes. The adsorption kinetics of different sized(40, 75, 100 and 200 nm)and coated(citrate, polyvinylpyrrolidone and polyethyleneglycol(PEG)) AgNPs indicated that these nanoparticle properties have also an effect on the adsorption processes.To assess the mobility and bioavailability of AgNPs and to determine if their form is maintained during adsorption/desorption processes, loaded soils were submitted to leaching tests three weeks after batch adsorption studies. The DIN 38414-S4 extraction method indicated that AgNPs were strongly retained on soils, and single-particle inductively coupled plasma mass spectrometry confirmed that silver particles maintained their nanoform, except for 100 nm PEG-AgNPs and 40 nm citrate-coated AgNPs. The DTPA(diethylenetriaminepentaacetic acid) leaching test was more effective in extracting silver,but there was no presence of AgNPs in almost all of these leachates. | Laura Torrent Eva Margui Ignasi Queralt Manuela Hidalgo Monica Iglesias | 2019 | Journal of Environmental Sciences2019，31，9： | 2 |
| 11 | Three-dimensional discharge simulation of inductively coupled plasma (ICP) etching reactor显示文摘More and more importance has been attached to inductively coupled plasma (ICP) in semiconductor manufacture. For a deep understanding of the plasma discharge process in the etching reactor, this study made a three-dimensional simulation on the Ar plasma discharge process with the commercial software CFD-ACE, which is according to the real experiment conditions and data supplied by North Microelec-tronic Corporation. The error of the simulation results is in the range of ±20% with credibility. The numerical results show that the three-dimentional spatial distribu-tion of electron density is reduced from the chamber center to the wall. The distri-bution of electron density, electron temperature and power deposition is related to the shape and placement of the coil. | AN YiRan LU YiJia LI DongSan CHEN YaoSong | 2008 | Science China(Technological Sciences)2008，51，6： | 2 |
| 12 | 电感耦合等离子体原子发射光谱法(ICP-AES)测定磷生铁中的Mn、P、Si显示文摘建立了电感耦合等离子体原子发射光谱(ICP-AES)法测定磷生铁中3种元素Mn、P、Si的定量分析方法.通过试验选择257.610nm、185.942nm、212.412nm分别作为Mn、P、Si的分析谱线,无需进行光谱干扰校正.实验结果表明,各元素分析谱线线性相关系数大于0.9990.方法用于高磷铸铁标准物质分析,测定值与认定值相符,测定结果的相对标准偏差在0.21% (Mn) ~1.8% (P)范围. | 申娟娟 | 2014 | 四川环境2014，33，2： | 2 |
| 13 | 样品粒度对封闭酸溶-ICP-MS分析性能的影响显示文摘To improve precision of analytical results of pressurized acid digestion-ICP-MS, the first step is to improve the homogeneity by reducing the particle size of sample. Using of ultra-fine sample (-500 mesh) can reduce the mass of the sample and the acid. The satisfactory precision is achieved at 2 mg sampling mass. | 孙德忠 何红蓼 | 2005 | 质谱学报2005，26，z1： | 2 |
| 14 | Studies on diffusion and profiles of elements in deep-sea manganese nodules显示文摘Elemental compositions are measured in manganese nodules collected from the Northern Mid-Pacific floor by inductively-coupled plasma atomic emission spectrometry (1CP-AES) and their growth rates are determined by radiometric methods. The result shows that depth distributions of elements in nodules vary with depth as follows; (i) increase, (ii) decrease and (iii) fluctuation. These internodule variations in elemental compositions are considered to be caused by diffusion and migration of elements in nodules and heterogeneities in textures of nodules. In the present paper, a diffusive model is used to elucidate the inward-increase profile of some elements in nodules. The effective diffusive coefficients are estimated to be of the order of 10-9 cm2/a for Ni, V and Zn in the nodules, which is less than the value reported for radionuclides. | Luo Shangde , Wang Lei and Huang Yipu Department of Oceanography, Xiamen University, Xiamen, China | 1989 | Acta Oceanologica Sinica1989，8，3： | 1 |
| 15 | 多接收电感耦合等离子体质谱法测量痕量钚同位素显示文摘The isotopic analysis of 232Pu plutonium in 5×10-12 g/g samples using a multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) is described. IRMM-290b and uranium (UTB750) were used to correct the metrical data, and the analytical precision is about 0.5%. | 张继龙 王同兴 李力力 常志远 赵永刚 刘俊岭 | 2005 | 质谱学报2005，26，z1： | 1 |
| 16 | Preliminary Study on Destruction of Freon 12 by Inductively Coupled Plasma——Development of ICP Technology for Waste Destruction显示文摘PreliminaryStudyonDestructionofFreon12byInductivelyCoupledPlasma——DevelopmentofICPTechnologyforWasteDestructionCHENDeng-yunan... | CHEN Deng yun and WANG Xiao ru ** (Department of Chemistry, the Research Lab. of SEDC of Analytical Science for Material and Life Chemistry, Xiamen University, Xiamen, 361005) Frank S. C. LEE (Department of Chemistry, Hong Kong Baptist Univ | 1997 | Chemical Research in Chinese Universities1997，13，2： | 1 |
| 17 | Droplet creator based on electrowetting-on-dielectric for lab on a chip显示文摘Electrowetting-on-dielectric (EWOD) is to directly control the wettability of liquids on the solid surface by applying the electric potential to the microelectrode array under the dielectric layer. The prototype of the EWOD droplet creator with the sandwiched structure is used: the droplet is sandwiched between the top and bottom plates; the bot- tom plate consists of silicon used as the substrate of the microelectrode array, nitride sili- con film deposited by low pressure chemical vapor deposition as the dielectric layer and the fluorocarbon polymer film deposited by inductively coupled plasma chemical vapor deposition as the hydrophobic layer; and the top plate is the transparent electrode covered with the hydrophobic layer. To obtain the required minimum voltage, the process and the criterion of creating droplets are analyzed. At the voltage of 35 V the deionized water droplet surrounded in silicone oil is successfully created. | ZENG Xuefeng1, YUE Ruifeng1, WU Jiangang1, HU Huan1, DONG Liang1, WANG Zheyao1, HE Feng2 & LIU Litian1 1. Institute of Microelectronics, Tsinghua University, Beijing 100084, China 2. Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China | 2006 | Science China(Technological Sciences)2006，49，2： | 1 |
| 18 | 烟用接装纸质控样品的制备与应用显示文摘采用深珠光印字烟用接装纸作为质控样品,用微波消解处理质控样品,以电感耦合等离子体质谱法(ICP–MS)对样品的铬、砷、铅含量进行定值,并进行不确定度评定。利用方差分析评价均匀性,ADF检验评价稳定性。经F检验表明在95%的置信区间,制备的烟用接装纸质控样品均匀性良好;经ADF检验表明,各元素在1%的显著水平下稳定可靠,样品稳定性良好。将烟用接装纸质控样品用于质控,并绘制Levy–Jennings质控图,质控效果良好。 | 斯文 黄华 王雨凝 朱书秀 陆明华 | 2014 | 化学分析计量2014，23，3： | 1 |
| 19 | Laser Induced Breakdown Spectroscopy for Comparative Quantitative Analysis of Betel Leaves from Pakistan显示文摘Laser induced breakdown Spectroscopy(LIBS)was applied for the elemental analysis and exposure of the heavy metals in betel leaves in air.Pulsed Nd∶YAG(1064 nm)in conjunction with a suitable detector(LIBS 2000+,Ocean Optics,Inc)having the optical resolution of 0.06 nm was used to record the emission spectra from 220 to 720 nm.Elements like Al,Ba,Ca,Cr,Cu,P,Fe,K,Mg,Mn,Na,P,S,Sr,and Zn were found to present in the samples.The relative abundances of the observed elements were calculated through standard calibration curve method,integrated intensity ratio method,and weight percentage LIBS approach.LIBS findings were validated by comparing its results with the results obtained using a typical analytical technique of Inductively Coupled plasma-optical emission spectroscopy(ICP-OES).Limit of detection(LOD)of the LIBS system was also estimated for heavy metals.The experience gain through this work implies that LIBS could be highly applicable for testing the quality and purity of food products. | I Rehan K Rehan S Sultana R Muhammad | 2018 | 光谱学与光谱分析2018，38，10： | 1 |
| 20 | Determination of Inorganic Elements in Paris daliensis H.Li et V.G.Souku and Paris dulongensis H.Li et S.Kuritap by ICP-OES显示文摘[Objectives] To determine 29 kinds of inorganic elements in samples of Paris daliensis H.Li et V.G.Souku and P. dulongensis H.Li et S.Kuritap produced in different regions, and to measure the content of 10 key inorganic elements: chromium(Cr), manganese(Mn), iron(Fe), copper(Cu), mercury(Hg), zinc(Zn), arsenic(As), antimony(Sr), cadmium(Cd) and lead(Pb). [Methods] The wet digestion and technique of inductively coupled plasma optical emission spectrometry(ICP-OES) were employed. [Results] Under the experimental conditions, elements were not related to each other, and many kinds of elements could be measured at the same time; toxic and heavy metals in samples of P. daliensis H.Li et V.G.Souku and P. dulongensis H.Li et S.Kuritap did not exceed the limit; Hg was not detected in all samples. [Conclusions] This method is simple, easy to operate and reproducible. It can be used for the detection of inorganic elements in P. daliensis H.Li et V.G.Souku and P. dulongensis H.Li et S.Kuritap; the heavy metals and Hg of the rhizome meet the requirements of the limit of medicinal materials. | Jixiu SHEN Zhongjie HUANG Risha WEIZE Xuexue LI Yunzhang XU Yuan LIU | 2019 | Medicinal Plant2019，10，1： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员