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1Effect of rare earth elements and their oxides on tribo-mechanical performance of laser claddings:A review显示文摘Laser cladding is a promising photon-based surface engineering technique broadly utilized for fabricating harder and wear resistant composite coatings. In spite of excellent properties, the practical applications of laser claddings are relatively restricted when compared with well-established coating techniques because of their inherent defects identified as cracks, pores and inclusions. Substantial evidence suggests that the incorporation of an appropriate amount of rare earth in laser claddings can remarkably prevent these defects. Additionally, the presence of rare earth in laser claddings can notably enhance tribo-mechanical properties such as surface hardness, modulus of elasticity, fracture toughness, friction coefficient and wear rate. In this literature review, the effect of rare earth in reducing dilution and cracks susceptibility of laser claddings in addition to microstructural refinement attained was examined. Mechanical and tribological properties of these claddings along with their underlying mechanism were discussed in detail. Finally, this article summarizes current applications of laser claddings based on rare earth and was concluded with future research directions.M.M.Quazi M.A.Fazal A.S.M.A.Haseeb Farazila Yusof H.H.Masjuki A.Arslan 2016Journal of Rare Earths2016,34,6:48
2太行山南段符山高镁闪长岩的成因——拆沉陆壳物质熔融的熔体与地幔橄榄岩反应的结果显示文摘本文对太行山南段符山高镁闪长岩进行了年代学与地球化学研究,结合其中地幔橄榄岩包体的研究,对符山高镁闪长岩的成因和中生代岩石圈地幔的性质进行了探讨。研究表明,符山闪长岩体是由一套含橄榄石角闪闪长岩-角闪闪长岩-闪长岩构成。含橄榄岩包体的寄主岩——角闪闪长岩中的锆石可划分为两种:一是代表寄主岩浆结晶的锆石:内部结构均匀、呈条带状吸收、自形-半自形晶形,具有较高的Th/U比值(1.10~4.08),其^(206)Pb/^(238)U年龄介于123~128Ma之间,12个点的加权平均值为125±1Ma,这表明岩体的形成时代为早白垩世;二是捕获或继承锆石:具有核边结构、吸收程度不均匀、呈浑圆状和自形-半自形两种,它们的Th/U比值介于0.32~2.03之间,构成了3组^(207)Pb/^(206)Pb加权平均年龄:2503±11Ma、2181±26Ma和1778±36Ma。该类岩石的SiO_2和MgO含量分别介于56.69%~59.21%和3.60%~6.33%之间;且以高Mg~#(0.51~0.64)、富Na(Na_2O/K_2O大于1)、高Cr(93.1×10^(-6)~420×10^(-6))、Ni(35.1×10^(-6)~137×10^(-6))为特征。该类岩石强烈富集轻稀土元素和大离子亲石元素、明显亏损高场强元素,(^(87)Sr/^(86)Sr)_i、ε_(Nd)(t)值和(^(206)Pb/^(204)Pb)_i分别变化于0.70581~0.70641、-8.30~-16.56和17.052~17.512之间。综合上述特征,同时结合地慢橄榄岩包体的特征和古元古代捕获锆石的大量存在,认为符山高镁闪长岩的原始岩浆起源于拆沉陆壳物质的部分熔融,其后经历了与地幔橄榄岩的反应过程。许文良 杨德彬 裴福萍 于洋 2009岩石学报2009,25,8:39
3长白山森林生态系统中的稀有和濒危多孔菌显示文摘In last 10 years,extensive field inventories were carried out to investigate Polypore species, the major wood decaying fungi in the Changbaishan Nature Reserve of Northeastern China. The following 27 species were treated as rare or threathened species: Amylocystis lapponica (Romell) Singer, Anomoporia albolutescens (Romell) Pouzar, Anomoporia bombycina (Fr.) Pouzar, Anomoporia vesiculosa Y.C. Dai & Niemel, Antrodia carbonica (Overh.) Ryvarden & Gilb., Antrodia crassa (P. Karst.) Ryvarden, Antrodiella citrinella Niemel & Ryvarden, Diplomitoporus flavescens (Bres.) Dománski, Donkioporia expansa (Desm.) Kotl. & Pouzar, Gloeophyllum carbonarium (Berk. & M.A. Curtis) Ryvarden, Haploporus odorus (Sommerf.) Bondartsev & Singer, Inonotopsis subiculosa (Peck) Parmasto, Nigroporus ussuriensis (Bondartsev & Ljub.) Y.C. Dai & Niemela, Oxyporus sinensis X.L. Zeng, Parmastomyces taxi (Bondartsev) Y.C. Dai & Niemela, Phellinidium sulphurascens (Pilat) Y.C. Dai, Phellinus vaninii Ljub., Polyporus vassilievae Thorn, Pycnoporellus fulgens (Fr.) Donk, Skeletocutis brevispora Niemela, Skeletocutis ochroalba Niemela, Skeletocutis perennis Ryvarden, Trechispora candidissima (Schwein.) Bondartsev & Singer, Wolfiporia dilatohypha Ryvarden & Gilb., Wolfiporia curvispora Y.C. Dai, Wrightoporia avellanea (Bres.) Pouzar and Wrightoporia lenta (Oveh. & J. Lowe) Pouzar. Polypores are richer in East Asia than in Europe and North America, not only because of destructive galciations and fewer hosts in the latters, but also because of the geography. NE Asia is a link between Europe and North America. Changbaishan Nature Reserve is very rich in polypores, and over 260 species were recorded in the reserve. Some rare species in North America and Europe, for instance, Anomoporia albolutescens, Antrodia crassa, Diplomitoporus flavescens, Inonotopsis subiculosa and Skeletocutis ochroalba etc. were found in Changbaishan Nature Reserve as well, and these species are in fact rare in the earth. Most of the 27 species occurred on fallen trunks or rotten wood in the reserve, but some of them grew on living trees. 18 species occured on substrate of gymnosperms, and 9 species grew on wood of angiosperm.Among the 27 species, 7 species caused a brown rot,and 20 species produced a white rot. The morphology, substrate and ecology of each species were briefly discussed. The most important tool for polypore conservation is the conservation of their habitats, and it is necessary to study the ecology of the rare and threathened species of polypores in the Changbaishan Nature Reserve. Because most of polypores live on the substrate of fallen trunks and rotten wood, it is very important to keep such substrate in the ecosystem.戴玉成 2003应用生态学报2003,14,6:35
4Perspective and Prospects for Rare Earth Permanent Magnets显示文摘Rare earth permanent magnets constitute a mature technology,but the shock of the 2011 rare earth crisis led to the re-evaluation of many ideas from the 1980s and 1990s about possible new hard magnets containing little or no rare earth(or heavy rare earth).Nd-Fe-B magnets have been painstakingly and skillfully optimized for a wide range of applications in which high performance is required at reasonable cost.Sm-Co is the material of choice when high-temperature stability is required,and Sm-Fe-N magnets are making their way into some niche applications.The scope for improvement in these basic materials by substitution has been rather thoroughly explored,and the effects of processing techniques on the microstructure and hysteresis are largely understood.A big idea from a generation ago-which held real potential to raise the record energy product significantly-was the oriented exchange-spring hard/soft nanocomposite magnet;however,it has proved very difficult to realize.Nevertheless,the field has evolved,and innovation has flourished in other areas.For example,electrical personal transport has progressed from millions of electric bicycles to the point where cars and trucks with electrical drives are becoming mainstream,and looks ready to bring the dominance of the internal combustion engine to an end.As the limitations of particular permanent magnets become clearer,ingenuity and imagination are being used to design around them,and to exploit the available mix of rare earth resources most efficiently.Huge new markets in robotics beckon,and the opportunities offered by additive manufacturing are just beginning to be explored.New methods of increasing magnet stability at elevated temperature are being developed,and integrated multifunctionality of hard magnets with other useful properties is now envisaged.These themes are elaborated here,with various examples.J.M.D.Coey 2020Engineering2020,6,2:31
5Recent advances in solid-state LED phosphors with thermally stable luminescence显示文摘Phosphor-converted white light-emitting diode(LED) lighting has gained tremendous achievements since the invention of the InGaN blue LED by Nakamura et al., who won the Nobel Physics Prize in 2014.By far, a significant challenge comes from the thermal quenching(TQ) behavior of the present LED phosphors during the high-power LED operation or the updated laser lighting. But systematic research or review on the luminescence quenching character and/or how to realize thermally stable luminescence are lacking. Since TQ is an inherent property of phosphors, it can be diminished by different approaches.This review proceeds from the mechanism of TQ, summarizes previous researches on improving the thermal stability of LED phosphors and also discusses future research opportunities in this field. The developments of the phosphors with properties of high luminance and thermal stability, as well as the improved strategies involved,will benefit the basic researches and applications in high power lighting or high-luminance laser lighting.Jianwei Qiao Jing Zhao Quanlin Liu Zhiguo Xia 2019Journal of Rare Earths2019,37,6:34
6华北克拉通东北缘岩石圈深部物质组成的不均一性:来自吉林南部中生代火山岩元素及Sr-Nd同位素地球化学的证据显示文摘本文报导了吉林南部果松组和三棵榆树组火山岩的全岩K-Ar和角闪石^(40)Ar/^(39)Ar定年结果和岩石地球化学资料,并讨论了吉林南部早白垩世火山岩岩浆源区性质以及空间变异。定年结果显示,果松组和三棵榆树纽火山岩的形成时代分别为130.2±0.3Ma和118.3±1.9Ma。果松组火山岩主要由玄武岩-玄武质粗面安山岩-粗面安山岩-英安岩组成;它们的SiO_2含量介于46%~64%,Mg~#介于31~50之间,Al_2O_3含量介于14.9%~18.9%之间,全碱含量(Na_2O+K_2O)介于4.61%~9.23%之间,属于亚碱性系列,具钙碱性演化趋势;并以富集大离子亲石元素(LILEs)和轻稀土元素(LREEs),亏损重稀土元素(HREEs)和Nb、Ta、Ti等高场强元素(HFSEs)为特征;(^(87)Sr/^(86)Sr)_i值和ε_(Nd)(t)值分别介于0.7065~0.7077和-2.67~ -19.71之间。果松组火山岩的成分具有较好的空间变异趋势,由东向西,火山岩的基性程度增高,东部果松组火山岩具有较高的(^(87)Sr/^(86)Sr)。值,而西部具有较低的ε_(Nd)(t)值。三棵榆树组火山岩由粗面安山岩和粗面英安岩组成;三棵榆树组火山岩的SiO_2含量介于55.5%~65.8%之间,Mg~#介于42~50,Al_2O_3含量介于15.0%~15.7%,全碱含量偏高(Na_2O+K_2O=6.93%~9.24%),主体属于亚碱性系列,具钙碱性系列的演化趋势;并以较高的Th/U(5.36~5.82)、Ba/Nh(50.2~120.0)、(La/Yh)_N(32.9~47.9)和Sr/Y(50.0~72.4)比值为特征;它们的(^(87)Sr/^(86)Sr)_i值和ε_(Nd)(t)值分别变化于0.7056~0.7057和-8.99~-19.71之间。上述特征揭示,果松组火山岩(130Ma)的形成主要与古太平洋板块的俯冲作用有关,岩浆来源于受流体/熔体交代的地幔楔,东西部受到不同程度陆壳物质的混染。与果松组火山岩相比,三棵榆树组火山岩(118Ma)形成于俯冲背景下的相对引张环境,岩浆来源于受交代的岩石圈地幔,但受到深部陆壳物质的混染。裴福萍 许文良 杨德彬 于洋 孟恩 2009岩石学报2009,25,8:28
7Effects of rare earth on inclusions and corrosion resistance of 10PCuRE weathering steel显示文摘The types, morphologies and distributions of nonmetallic inclusions in Cu-P weathering steels with and without rare earth were analyzed through a quantitative image analyzer, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) attached to SEM. Solid-soluble content of rare earth in the steels was analyzed by non-aqua electroanalysis and ICP. The results showed that rare earth modified the types and the morphologies of inclusions in the weathering steels. The small spherical rare earth oxysulfides and rare earth sulphides replaced the elongated MnS inclusions in the RE weathering steels. The rare earth inclusions dispersedly distributed and most inclusions were smaller than 2 μm in size. The optimum content of RE was 0.0065%-0.016% for 10PCuRE weathering steels containing about 0.002% oxygen and 0.004% sulfur. Solid-soluble content of rare earth in steels was (14-20)×10-6, which can act as a micro-alloying element. The corrosion resistance of 10PCuRE weathering steels and Q235 were studied by dry-wet cyclic immersion test. Their corrosion rates were obtained respectively. The polarization curves and pitting corrosion behaviors of weathering steels with and without rare earth were measured by electrochemical methods. The corrosion resistance of Cu-P weathering steels was improved by adding an appropriate amount of rare earth. Less and fewer rare earth inclusions largely decreased pitting susceptibility and rate of pit propagation. The pitting potential and the resistance against pitting corrosion of the RE weathering steel were significantly improved due to the modification of rare earth to inclusions.岳丽杰 王龙妹 韩金生 2010Journal of Rare Earths2010,28,6:25
8Growth and corrosion behavior of rare earth film on hot-dip galvanized steel卢锦堂 吴海江 孔纲 车淳山 许乔瑜 2006Transactions of Nonferrous Metals Society of China2006,7,6:26
9Application of Lanthanum in High Strength and High Conductivity Copper Alloys显示文摘China is quite poor in argent resource. Roughly 80% of this industrial argent is imported every year. In order to improve the situation, we took advantage of rare earth (RE) mineral resource and successfully developed the non-argent Lanthanum-tellurium-copper alloy as a substitute for industry argent-copper. In our research, we were able to successfully apply rare earth lanthanum to copper alloy. The defects as porosity, inclusion, etc. originating from nonvacuum melting processing were controlled. Fine grain was obtained. Meanwhile, the comprehensive properties of the copper alloy, such as strength, conductivity and thermal conductivity were improved. The research results in increasing conductivity and thermal conductivity by 5% and 15%, respectively, while the tensile strength is increased by 6% higher than Ag-Cu alloy. The anti-electric corrosion property is good, and there is no argent-cadmium steam population originating from the electric arc effect. The addition of lanthanum further reduces the content of oxygen and hydrogen.The optimum quantity of the addition of RE lanthanum in the copper alloy is 0.010%~0.020%.周世杰 赵秉钧 赵桢 金鑫 2006Journal of Rare Earths2006,24,z2:22
10REE TRACER METHOD FOR STUDIES ON SOIL EROSION显示文摘REETRACERMETHODFORSTUDIESONSOILEROSIONTIANJunliang;ZHOUPeihuaandLIUPuling(TheEnglishtextiseditedbyMrs.SUUanandDr.DINGLianzhen...TIAN Junliang ZHOU Peihua and LIU Puling( Northwestern Institute of Son and Water Conservancy. Acadernia Sinlca and Ministry of WaterResources. Yangling. Shaanxi 712 100. China) 1994International Journal of Sediment Research1994,9,2:22
11Effects of rare earth elements on inclusions and impact toughness of high-carbon chromium bearing steel显示文摘High-carbon chromium bearing steels with different rare earth (RE) contents were prepared to investigate the effects of RE on inclusions and impact toughness by different techniques. The results showed that RE addition could modify irregular Al2O3 and MnS into regular RE inclusions. With the increase of RE content, the reaction sequence of RE and potential inclusion forming elements should be O, S, As, P and C successively. RE inclusions containing C might precipitate in molten steel and solid state, but the precipitation tem perature was significantly higher than that of carbides in high-carbon chromium bearing steel. For experim ental bearing steels, the volume fraction of inclusions increased steadily with the increase of RE content, but smaller and more dispersed inclusions could be obtained by 0.018% RE content compared with bearing steel without RE, whereas the continuous increase of RE content led to an increasing trend for inclusion size and a gradual deterioration for inclusion distribution. RE addition could improve the transverse impact toughness and isotropy of bearing steel, and for modified highcarbon chrom ium bearing steel by RE alloying, the increase of RE content continuously increased both transverse and longitudinal im pact toughness until excessive RE addition.Chaoyun Yang Yikun Luan Dianzhong Li Yiyi Li 2019Journal of Materials Science & Technology2019,35,7:22
12Application of P507 and isooctanol extraction system in recovery of scandium from simulated red mud leach solution显示文摘The current recovery technique of Sc was complicated and the chemical consumption was high,This was due to the low content of Sc in resources and the difficulty of stripping.In this research,the isooctanol was added into the 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester(P507)extraction system to reduce the extraction and improve the stripping of Sc.The maximum stripping ratio of Sc from loaded organic phase by sulfuric acid can increase from 10%(without isooctanol)to 99%(with 15 vol%isooctanol).In the extraction test of the simulated red mud leaching liquor,the separation factors between Sc and Zr,Sc and Ti are 36 and 350,separately.At the same time,other metals are almost not extracted.The high selectivity and stripping of Sc suggest that the P507 with isooctanol extraction system can be applied in the practical Sc recovery process.Chuanying Liu Li Chen Ji Chen Dan Zou Yuefeng Deng Deqian Li 2019Journal of Rare Earths2019,37,9:22
13Development course of separating rare earths with acid phosphorus extractants: A critical review显示文摘This paper reviews the development course of separating rare earths with acid phosphorus extractants,including extraction chemistry(thermodynamics and kinetics), separation process and industrial application, the loss/degradation of extractants, etc.Deqian Li 2019Journal of Rare Earths2019,37,5:20
14Leaching ion adsorption rare earth by aluminum sulfate for increasing efficiency and lowering the environmental impact显示文摘The leaching efficiency(LE) of ion adsorption rare earth(IARE) by the sulfate and chloride of ammonium,magnesium and aluminum were comparatively determined using column leaching method. It is found that at equal equivalent concentration of cation, the LE of IARE by aluminum sulfate is the highest, and the zeta potential of clay mineral particles in the tailing is near to zero, which means a lower risk of landslide and pollutant emission. Furthermore, the optimum concentration of aluminum sulfate is determined to be0.02 mol/L, which is much lower than that of ammonium sulfate and magnesium sulfate. To reduce the production cost and environmental impact, we proposed a multi-stage leaching process, which was firstly leaching with ammonium sulfate and then with aluminum sulfate, following by water washing and lime neutralizing. With the ratio of ammonium sulfate to aluminum sulfate varying from 1:0 to 0.5:0.5, the residual ammonium in tailing decreases from 11.2% to 0.6%, however, the LE of RE shows an optimum value at 0.8:0.2. By neutralizing the pH of tailing with lime water to over 6, the ion concentration in water rinsing solution can meet the requirement for water discharge. At the same time, the zeta potential of clay particles is found to be around-5 mV, means a relatively lower risk of landslide. These facts indicate that the LE of IARE can be increased and the danger caused by tailings landslides and pollutant emissions can be reduced by replacing ammonium sulfate with aluminum sulfate as leaching reagent.Lifen Yang Cuicui Li Dashan Wang Fengyang Li Yanzhu Liu Xuezhen Zhou Mingbiao Liu Xiufeng Wang Yongxiu Li 2019Journal of Rare Earths2019,37,4:19
15Study on Roasting Decomposition of Mixed Rare Earth Concentrate in CaO-NaCl-CaCl_2显示文摘The decomposed process of bastnaesite, monazite and mixed rare earth concentrate in CaO-CaCl-CaCl2 was studied by means of TG-DTA method. The relationship among decomposition ratio, roasting temperature, and CaO-NaCl addition was studied by the quadratic regression orthogonal analysis, and then the regression equation was obtained. Through analysis, the optimum process conditions of mixed rare earth concentrate decomposed by CaO-CaCl-CaCl2 were obtained as follows: roasting temperature: 700 ℃, CaO addition: 15%, NaCl-CaCl2 addition: 10%, roasting time: 60 min, the decomposition ratio: 91.3%.吴文远 边雪 孙树臣 涂赣峰 2006Journal of Rare Earths2006,24,z2:18
16Effects of the accumulation of the rare earth elements on soil macrofauna community显示文摘The accumulation of rare earth elements (REEs) in soil has occurred due to the pollution caused by the exploitation of rare earth resources and the wide rare earth fertilizers in agriculture. The accumulation of REEs has a toxic effect on the soil macrofauna community. 12 study samples were collected near a mine tailings dam with a large amount of REEs by distance gradient sample method. The total concentration of REEs was analyzed and the results were compared with that of the sample from a control site. The effects of the amount of REEs in the soil on the soil macrofauna community were also analyzed. The results showed that the accumulation of REEs in soil was significant in the study area and its concentration was strongly correlated with the distance from the pollution source. One-way ANOVA analysis indicated the significant differences in soil macrofauna communities among the different sites. The ordination obtained through the redundancy analysis demonstrated that the concentration of REEs and the total nitrogen, total potassium and pH, had affected the soil macrofauna community. A small amount of REEs in the soil can promote the diversity of soil macrofauna, but a large amount of REEs can reduce its diversity. The insect groups of Carabidae and Dermaptera were comparatively sensitive to the concentration of REEs in soil, and could be used as an indicator of soil pollution of REEs. However, the Formicidae and Stibaropus formosanus exhibited a high tolerance to REEs in soil. We believe that it is very important for the soil environment protection to strictly control the application of the rare earth fertilizers in agriculture in China.李金霞 红梅 殷秀琴 刘继亮 2010Journal of Rare Earths2010,28,6:18
17Geochemical changes across the Ordovician-Silurian transition on the Yangtze Platform,South China显示文摘The trace element and rare earth element(REE) variations across the Ordovician-Silurian succession are presented from two outcrop sections on the Yangtze Platform:the Nanbazi section,Guizhou Province,deposited in a shallow platform interior setting,and the Wangjiawan section,Hubei Province,deposited in a deeper basinal environment.Geochemical analysis of closely spaced samples through three intervals,the Wufeng,Guanyinqiao and Longmaxi,revealed vast palaeoceanographic changes.Some geochemical proxies,including Th/U,Ni/Co,V/Cr,and V/(V+Ni) ratios,together with sedimentary facies and biotic data,indicate that an anoxic condition on the most of the Yangtze Platform during the Wufeng and Longmaxi intervals,but an oxic condition during the Guanyinqiao time.The shift of the anoxic to the oxic environment during the Guanyinqiao time coincided with a global sea-level lowstand,in parallel with the global glaciation.The Longmaxian anoxic environment was a result of a global sea-level rise,which may be synchronized with a mainly catastrophic event in the latest Ordovician.Although the two sections generally show similar variation patterns of trace and REE concentrations and some element ratios,a minor difference occurs between the Wangjiawan and Nanbazi sections,likely reflecting a difference in depositional setting during the accumulation.Such an oceanic oxygen-level variation may add a useful constraint to the current arguments on the cause and consequence of the latest Ordovician mass extinction.YAN DeTian CHEN DaiZhao WANG QingChen WANG JianGuo 2009Science China Earth Sciences2009,52,1:17
18Thiolactone copolymer donor gifts organic solar cells a 16.72% efficiency显示文摘Since 1995,bulk-heterojunction organic solar cells consisting of one or two organic donors and one or two organic acceptors have been fighting for high power conversion efficiencies(PCEs)and good stability[1].Until recent years,this next-generation photovoltaic technology starts to offer decent PCEs,shedding the light on commercialization,and attracting great attention again[2-14].Compared w让h the continuously emerging highperformance nonfullerene acceptors,high-performance donors are rare.Ji Xiong Ke Jin Yufan Jiang Jianqiang Qin Tan Wang Jinfeng Liu Qishi Liu Haili Peng Xiongfeng Li Anxin Sun Xianyi Meng Lixiu Zhang Ling Liu Wenting Li Zhimin Fang Xue Jia Zuo Xiao Yaqing Feng Xiaotao Zhang Kuan Sun Shangfeng Yang Shengwei Shi Liming Ding 2019Science Bulletin2019,64,21:17
19CuZnAl Shape Memory Alloy Refined with Composite Rare Earths La+Ce显示文摘The effects of composite rare earths La+Ce on properties of CuZnAl shape memory alloys were studied bymetallograph examination, tensile and bending tests, electric resistivity measurements, EDS and SEM. The test resultsshow that the grain size of CuZnAl shape memory alloys could be diminished effectively and the mechanical propertiesimproved obviously by the addition of composite rare earths La+Ce (La: Ce=1: 1). Meanwhile, the excellent shapememory properties remained unchanged. The results of microanalyses indicate that the composite rare earths were segregated at grain boundaries and impeded the grain growth, leading to the improvement of the mechanical properties ofCuZnAl alloys. If the amount of composite rare earths La+Ce was greater than 0. 10%, the shape memorial propertiesbecame poor.司乃潮 1999Journal of Rare Earths1999,17,4:16
20Synthesis,Characterization and Antibacterial Properties of Rare Earth (Ce^(3+) ,Pr^(3+) ,Nd^(3+) ,Sm^(3+) ,Er^(3+) ) Complexes with L-Aspartic Acid and o-Phenanthroline显示文摘Five novel ternary complexes of rare earth ions with L-Aspartic acid (Asp) and o-phenanthroline (Phen) were synthesized in ethanol aqueous solution. Their compositions were characterized by elemental analysis, molar conductance, FT-IR, Raman, UV-VIS and TG-DTA. The compositions of the complexes were confirmed to be: RE(Asp)3PhenCl3·3H2O (RE: Ce3+, Pr3+, Nd3+, Sm3+, Er3+). The antibacterial activity test shows that all these complexes exhibit excellent antibacterial ability against Escherichia coli, Staphylococcus aureus and Candida albicans. The antimicrobial spectrum of the complexes are broad.郁慧 何其庄 杨静 郑文捷 2006Journal of Rare Earths2006,24,z2:15
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