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| 1 | A chlorinated copolymer donor demonstrates a 18.13% power conversion efficiency显示文摘The rapid development of low-bandgap(LBG)nonfullerene acceptors and wide-bandgap(WBG)copolymer donors in recent years has boosted the power conversion efficiency(PCE)of organic solar cells(OSCs)to the 18%level[1−21].The commercialization of OSCs is highly expected.However,critical issues like the cost and the stability also determine whether OSCs can enter the market or not[22]. | Jianqiang Qin Lixiu Zhang Chuantian Zuo Zuo Xiao Yongbo Yuan Shangfeng Yang Feng Hao Ming Cheng Kuan Sun Qinye Bao Zhengyang Bin Zhiwen Jin and Liming Ding | 2021 | Journal of Semiconductors2021,42,1: | 19 |
| 2 | Thiolactone copolymer donor gifts organic solar cells a 16.72% efficiency显示文摘Since 1995,bulk-heterojunction organic solar cells consisting of one or two organic donors and one or two organic acceptors have been fighting for high power conversion efficiencies(PCEs)and good stability[1].Until recent years,this next-generation photovoltaic technology starts to offer decent PCEs,shedding the light on commercialization,and attracting great attention again[2-14].Compared w让h the continuously emerging highperformance nonfullerene acceptors,high-performance donors are rare. | Ji Xiong Ke Jin Yufan Jiang Jianqiang Qin Tan Wang Jinfeng Liu Qishi Liu Haili Peng Xiongfeng Li Anxin Sun Xianyi Meng Lixiu Zhang Ling Liu Wenting Li Zhimin Fang Xue Jia Zuo Xiao Yaqing Feng Xiaotao Zhang Kuan Sun Shangfeng Yang Shengwei Shi Liming Ding | 2019 | Science Bulletin2019,64,21: | 17 |
| 3 | Progress of the key materials for organic solar cells显示文摘Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight,flexibility and roll-to-roll fabrication.Nowadays,18%power conversion efficiency has been achieved in the state-of-the-art organic solar cells.The recent rapid progress in organic solar cells relies on the continuously emerging new materials and device fabrication technologies,and the deep understanding on film morphology,molecular packing and device physics.Donor and acceptor materials are the key materials for organic solar cells since they determine the device performance.The past 25 years have witnessed an odyssey in developing high-performance donors and acceptors.In this review,we focus on those star materials and milestone work,and introduce the molecular structure evolution of key materials.These key materials include homopolymer donors,D-A copolymer donors,A-D-A small molecular donors,fullerene acceptors and nonfullerene acceptors.At last,we outlook the challenges and very important directions in key materials development. | Yang Tong Zuo Xiao Xiaoyan Du Chuantian Zuo Yuelong Li Menglan Lv Yongbo Yuan Chenyi Yi Feng Hao Yong Hua Ting Lei Qianqian Lin Kuan Sun Dewei Zhao Chunhui Duan Xiangfeng Shao Wei Li Hin-Lap Yip Zhengguo Xiaol Bin Zhang Qingzhen Bian Yuanhang Cheng Shengjian Liu Ming Cheng Zhiwen Jin Shangfeng Yang Liming Ding | 2020 | Science China Chemistry2020,63,6: | 15 |
| 4 | Discovery of carbonaceous compressions and their multicellular tissues from the Changzhougou Formation (1 800 Ma) in the Yanshan range, North China显示文摘In 1997 and 1998, hundreds of specimens of megascopic carbonaceous compressions or algal fossils were found from - 1800-million-year old Changzhougou Formation, which is the lowermost unit of the latest Palaeoproterozoic Changcheng Group (~1 600-1 800 Ma) in the Xinglong-Kuancheng areas at the middle Yanshan Range, North China. They are discoid, ellipsoid and sausage-like, namely shaped like Chuaria Shouhsiennia (Ellipsophyta) and Tawuia. By adopting HF acid-resistant maceration coupled with scanning electron microscope and petrologic section, the authors made a preliminary research on the histology for some circular and ellipsoid carbonaceous compressions, namely Chuaria- and Shouhsienia-llke forms, in addition to their morphology. The following three types of multicellular tissues have been found in the fragments of them: colony-like, pseudoparenchyma-like and parenchyma-like. All of the new data about multicelluar tissues not only supply a very important basis in histology to determine the | ZHU Shixing SUN Shufen HUANG Xueguang HE Yuzhen ZHU Gengxin SUN Lixin ZHANG Kuan | 2000 | Chinese Science Bulletin2000,45,9: | 10 |
| 5 | Toughening Poly(lactic acid) with Imidazolium-based Elastomeric Ionomers显示文摘Imidazolium-based elastomeric ionomers(i-BIIR) were facilely synthesized by ionically modified brominated poly(isobutylene-co-isoprene)(BIIR) with different alkyl chain imidazole and thoroughly explored as novel toughening agents for poly(lactic acid)(PLA). The miscibility, thermal behavior, phase morphology and mechanical property of ionomers and blends were investigated through dynamic mechanical analyses(DMA), differential scanning calorimetry(DSC), scanning electron microscopy(SEM), tensile and impact testing. DMA and SEM results showed that better compatibility between the PLA and i-BIIR was achieved compared to the PLA/unmodified BIIR elastomer. A remarkable improvement in ductility with an optimum elongation at break up to235% was achieved for the PLA/i-BIIR blends with 1-dodecylimidazole alkyl chain(i-BIIR-12), more than 10 times higher than that of pure PLA. The impact strengths of PLA were enhanced from 1.9 kJ/m^2 to 4.1 kJ/m^2 for the PLA/10 wt% i-BIIR-12 blend. Toughening mechanism had been established by systematical analysis of the compatibility, intermolecular interaction and phase structures of the blends. Interfacial cavitations initiated massive shear yielding of the PLA matrix owing to a suitable interfacial adhesion which played a key role in the enormous toughening effect in these blends. We believed that introducing imidazolium group into the BIIR elastomer was vital for the formation of a suitable interfacial adhesion. | Lu Chen Kuan Hu Si-Ting Sun Hai Jiang Dong Huang Kun-Yu Zhang Li Pan Yue-Sheng Li | 2018 | Chinese Journal of Polymer Science2018,36,12: | 7 |
| 6 | Effects of Bacterial-Feeding Nematode Grazing and Tea Saponin Addition on the Enhanced Bioremediation of Pyrene-Contaminated Soil Using Polycyclic Aromatic Hydrocarbon-Degrading Bacterial Strain显示文摘As one of the most widely distributed bacterial predators in the soil, the role of bacterivorous nematodes on the enhanced bioremediation of polycyclic aromatic hydrocarbon-contaminated soils is crucial, but remains to be investigated.A microcosm-level study was conducted to examine the effects of bacterial-feeding nematode grazing and tea saponin(TS) addition on bioremediation of a pyrene-contaminated soil enhanced by the polycyclic aromatic hydrocarbon(PAH)-degrading bacterial strain Sphingobium sp.PHE9.After 180 d of incubation, the highest pyrene dissipation(71.3%) was achieved through a combination of Sphingobium sp.PHE9 inoculation with nematode and TS addition.Meanwhile, high counts of culturable PAH-degrading bacteria, soil enzyme activity, and biodiversity indices were observed under the combined treatment, implying that the microbiological function of the contaminated soil was significantly restored.Additionally, the results of Tenax~ extraction with the first-order three-compartment model indicated that rate-limiting factors varied among treatments.The lack of degrading microorganisms was the main rate-limiting factor for the treatments involving TS/nematode addition, and inadequate bioaccessible pyrene was the vital rate-limiting factor in the treatments involving Sphingobium sp.PHE9 inoculation.The proposed combined clean-up strategy proved to be a promising bioremediation technology for aged pyrene-contaminated soils. | SUN Mingming LIU Kuan ZHAO Yuanchao TIAN Da YE Mao LIU Manqiang JIAO Jiaguo JIANG Xin | 2017 | Pedosphere2017,27,6: | 7 |
| 7 | Flexible control strategy for HVDC transmission system adapted to intermittent new energy delivery显示文摘Intermittent new energy delivery requires increasing the flexibility of ultra-high voltage direct current(DC)power adjustment.Based on a converter steady-state model and a DC power model,the control angle constraints of a converter valve are relaxed for power regulation.In this paper,a flexible DC power control method based on a fixed tap changer position is proposed.The initial ratio of the converter transformer is optimized.The effects of the fixed-tap changer position control on the control angle,reactive power compensation,and commutation failure are analyzed.The new control method allows a DC system to operate at a large angle and increase the additional reactive power loss while improving the commutation security margin.Steady-state and electromagnetic transient simulations in the CIGRE test system verify the validity of the method proposed in this paper and the correctness of the analysis conclusions. | Chenhao Li Kuan Li Changhui Ma Pengfei Zhang Qi Tao Yingtao Sun Xin Wang | 2021 | Global Energy Interconnection2021,4,4: | 6 |
| 8 | Feasibility of Tea Saponin-Enhanced Soil Washing in a Soybean Oil-Water Solvent System to Extract PAHs/Cd/Ni Efficiently from a Coking Plant Site显示文摘Mixed contaminated brownfield sites have brought serious risks to human health and environmental safety. With the purpose of removing polycyclic aromatic hydrocarbons(PAHs) and heavy metals from a coking plant site, an innovative technology for ex-situ washing was developed in the present work. The combination of 15.0 mL L^(-1) soybean oil and 7.5 g L^(-1) tea saponin proved an effective method to extract co-pollutants from soil. After two consecutive washing cycles, the efficiency rates of removal for 3-, 4-,5(+6)-ring, and total PAHs, Cd, and Ni were approximately 98.2%, 96.4%, 92.3%, 96.3%, 94.1%, and 89.4%, respectively. Meanwhile,as evaluated by Tenax extraction method and metal stability indices, the residual PAHs and heavy metals after consecutive washing mainly existed in the form with extremely low bioaccessibility in the soil. Thus, in the soil after two washing cycles, there appeared limited environmental transfer risk of co-pollutants. Moreover, a subsequent precipitation method with alkaline solution and PAHdegrading strain Sphingobium sp. PHE9 inoculation effectively removed 84.6%–100% of Cd, 82.5%–91.7% of Ni, and 92.6%–98.4% of PAHs from the first and second washing solvents. The recovered solvents also exhibited a high recycling effectiveness. Therefore, the combined cleanup strategy proposed in this study proved environmentally friendly, which also played a major role in risk assessment and management in mixed polluted sites. | YE Mao SUN Mingming XIE Shanni LIU Kuan FENG Yanfang ZHAO Yu WAN Jinzhong HU Feng LI Huixin ZONG Lianggang JIANG Xin | 2017 | Pedosphere2017,27,3: | 5 |
| 9 | m6A promotes R-loop formation to facilitate transcription termination显示文摘R-loops are three-stranded nucleic acid structures consisting of a DNA:RNA heteroduplex and a displaced single DNA strand.They constitute a prevalent genomic feature with important functions in all kingdoms of eukaryotes.1,2,3 For example,R-loops have been found over unmethylated CpG island promoters,G-rich terminators,and many other regulatory chromosomal loci.2,3 Moreover,they are essential for diverse cellular processes,such as immunoglobulin class switching,mitotic chromosome segregation,4 DNA replication and repair,genome stability regulation,5 as well as in multiple steps during transcription.6,7 R-loops can be formed both in cis and in trans;cis R-loops are formed between a nascent RNA and its DNA template following transcribing RNA polymerases and exert co-transcriptional regulatory effects.3,8 Therefore,it is important to control their formation and resolution,and many external factors have already been identified for this process.7 However,it is still unknown whether the intrinsic properties of the RNA itself,such as various modifications,can modulate the formation of DNA:RNA hybrids. | Xin Yang Qian-Lan Liu Wei Xu Yi-Chang Zhang Ying Yang Lin-Fang Ju Jing Chen Yu-Sheng Chen Kuan Li Jie Ren Qianwen Sun Yun-Gui Yang | 2019 | Cell Research2019,29,12: | 5 |
| 10 | Tunable luminescent CsPb_2Br_5 nanoplatelets:applications in light-emitting diodes and photodetectors显示文摘Unlike organic–inorganic hybrid perovskites, all-inorganic cesium lead halide perovskites hold great promise for developing high-performance optoelectronic devices, owing to their improved stability. Herein, we investigate the perovskite-related CsPb_2 Br_5 nanoplatelets(NPLs) with tunable emission wavelengths via changing the reaction temperatures to 100°C, 120°C, and 140°C. Reaction temperature plays a key role in determining the shapes and thicknesses of the resulting CsPb_2 Br_5 NPLs. A higher temperature is in favor of the formation of smaller and thicker NPLs. To develop their potential applications in optoelectronic devices, green light emitting diodes(LEDs) and photodetectors based on CsPb_2 Br_5 NPLs are fabricated. The green LEDs based on CsPb_2 Br_5 NPLs synthesized at 140°C exhibit an excellent pure green emission(full width at half-maximum of <20 nm) and display a luminous efficiency of 34.49 lm∕W under an operation current of 10 m A. Moreover, the photodetector based on CsPb_2 Br_5 NPLs synthesized at 100°C has better performance with a rise time of 0.426 s, a decay time of0.422 s, and a ratio of the current(with and without irradiation) of 364%. | CENG HAN CUNLONG LI ZHIGANG ZANG MING WANG KUAN SUN XIAOSHENG TANG JIHE DU | 2017 | Photonics Research2017,5,5: | 4 |
| 11 | CsPb(I_(x)Br_(1-x))_(3) solar cells显示文摘Owing to its nice performance, low cost, and simple solution-processing, organic-inorganic hybrid perovskite solar cell(PSC) becomes a promising candidate for next-generation high-efficiency solar cells.The power conversion efficiency(PCE) has boosted from 3.8% to 25.2% over the past ten years. Despite the rapid progress in PCE, the device stability is a key issue that impedes the commercialization of PSCs. Recently, all-inorganic cesium lead halide perovskites have attracted much attention due to their better stability compared with their organic-inorganic counterpart. In this progress report, we summarize the properties of CsPb(IxBr1-x)3 and their applications in solar cells. The current challenges and corresponding solutions are discussed. Finally, we share our perspectives on CsPb(IxBr1-x)3 solar cells and outline possible directions to further improve the device performance. | Xue Jia Chuantian Zuo Shuxia Tao Kuan Sun Yixin Zhao Shangfeng Yang Ming Cheng Mingkui Wang Yongbo Yuan Junliang Yang Feng Gao Guichuan Xing Zhanhua Wei Lijun Zhang Hin-Lap Yip Mingzhen Liu Qing Shen Longwei Yin Liyuan Han Shengzhong Liu Lianzhou Wang Jingshan Luo Hairen Tan Zhiwen Jin Liming Ding | 2019 | Science Bulletin2019,64,20: | 2 |
| 12 | The Flavor and Antioxidant Activity Change Pattern of Shrimp Head Paste During Fermentation显示文摘To study the changes of volatile compounds and antioxidant activity of fast fermented shrimp head paste during the fermentation processing,Penaeus vannamei boone head was used as the raw material,and compound starter was added for fermen-tation.During the 14 days of fermentation,the changes of free amino acids,volatile flavor compounds and main components were determined by SPME-GC-MS and electronic nose.The oxidation-resistance changes of water extract at different fermentation stages were evaluated.The results showed that the total free amino acids increased from original 2320 to 5640 mg(100 mL)^(−1).SPME-GC-MS analysis found that aldehydes,pyrazine compounds increased from 10.80%,1.94%to 24.35%,13.63%respectively during the fermentation process.The HO·scavenging ability of shrimp head paste increased from 52%to 86%.Our results showed that the shrimp paste produced from shrimp head fermentation could obtain good flavor and possess certain antioxidant activity of aquatic fermented condiment. | YU Jing LU Kuan SUN Jinyuan XIE Wancui SONG Lin CHE Hongxia | 2022 | Journal of Ocean University of China2022,21,1: | 2 |
| 13 | Hepatic Cyp1a2 Expression Reduction during Inflammation Elicited in a Rat Model of Intermittent Hypoxia显示文摘 | Li-Xia Shi Xing Wang Qi Wu Xin Sun Zhen Wan Li Li Kuan Li Xue Li Yu Li Qiu-Yang Zhang Jun-Ping Wu Huai-Yong Chen | 2017 | Chinese Medical Journal2017,,21: | 2 |
| 14 | Saposin C: neuronal effect and CNS delivery by liposomes 显示文摘 | Chu Z Sun Y Kuan CY | 2005 | Ann NY Acad Sci2005,1053,: | 1 |
| 15 | Gelatin-based composite hydrogels with biomimetic lubrication and sustained drug release显示文摘The occurrence of osteoarthritis is closely related to progressive and irreversible destruction of the articular cartilage,which increases the friction significantly and causes further inflammation of the joint.Thus,a scaffold for articular cartilage defects should be developed via lubrication restoration and drug intervention.In this study,we successfully synthesized gelatin-based composite hydrogels,namely GelMA–PAM–PMPC,with the properties of biomimetic lubrication and sustained drug release by photopolymerization of methacrylic anhydride modified gelatin(GelMA),acrylamide(AM),and 2-methacryloyloxyethyl phosphorylcholine(MPC).Tribological test showed that the composite hydrogels remarkably enhanced lubrication due to the hydration lubrication mechanism,where a tenacious hydration shell was formed around the zwitterionic phosphocholine headgroups.In addition,drug release test indicated that the composite hydrogels efficiently encapsulated an anti-inflammatory drug(diclofenac sodium)and achieved sustained release.Furthermore,the in vitro test revealed that the composite hydrogels were biocompatible,and the mRNA expression of both anabolic and catabolic genes of the articular cartilage was suitably regulated.This indicated that the composite hydrogels could effectively protect chondrocytes from inflammatory cytokine-induced degeneration.In summary,the composite hydrogels that provide biomimetic hydration lubrication and sustained local drug release represent a promising scaffold for cartilage defects in the treatment of osteoarthritis. | Kuan ZHANG Jielai YANG Yulong SUN Yi WANG Jing LIANG Jing LUO Wenguo CUI Lianfu DENG Xiangyang XU Bo WANG Hongyu ZHANG | 2022 | Friction2022,10,2: | 1 |
| 16 | Heat calculation and numerical simulation in steam mining of permafrost gas hydrate显示文摘Steam mining method was injecting hot steam into the borehole to heat the hydrate strata at the same time of depressurization mining,which could promote further decomposition and expand mining areas of gas hydrate. Steam heat calculation would provide the basis for the design of heating device and the choice of the field test parameters. There were piping heat loss in the process of mining. The heat transfer of steam flowing in the pipe was steady,so the heat loss could be obtained easily by formula calculation. The power of stratum heating should be determined by numerical simulation for the process of heating was dynamic and the equations were usually nonlinear. The selected mining conditions were 500-millimeter mining radius,10 centigrade mining temperature and 180 centigrade steam temperature. Heat loss and best heating power,obtained by formula calculation and numerical simulation,were 21. 35 W/m and 20 kW. | LI Bing SUN Youhong GUO Wei LI Kuan | 2012 | Global Geology2012,15,2: | 1 |
| 17 | Mannitol facilitated perfusion staining with 2,3, 5 triphenyltetrazolium chloride (TTC) fordetection of experimental cerebral infarction and biochemical a nalysis显示文摘 | Sun YY Yang D Kuan CY | 2012 | J NeurosciMethods2012,203,1: | 1 |
| 18 | Towards reperfusion-centric preclinical stroke research:outside the box of “reperfusion injury”显示文摘Stroke is a major health issue of increasing significance for any society with an aging population.Globally,stroke is the second-leading cause of death with approximately5.9 million fatal events in 2010,equivalent to 11.1%of all deaths.Yet,despite years of preclinical research on neuroprotection and a multitude of clinical trials,tissue plasminogen activator(tPA)-mediated recanalization | Chia Yi Kuan Yu Yo Sun | 2015 | Neural Regeneration Research2015,10,4: | 1 |
| 19 | A kinetic model of carbon burnout in pulverized coal combustion显示文摘 | ROBERT HURT SUN JIAN KUAN MELISSA LUNDEN | 1998 | Combustion And Flame1998,113,: | 1 |
| 20 | Directional diffusion-controlled development of spinel interlayer between zinc-orthosilicate glaze and alumina显示文摘 | Chao-Hsien Wu Chang-Ning Huang Chao Sun Cheng Kuan Pouyan Shen | 2011 | Ceramics International2011,,6: | 1 |