PtCo alloy nanoparticles supported on graphene nanosheets with high performance for methanol oxidation

查看全文 作　　者：HUANG HuaJie SUN DongPing WANG [1]Xin

机构地区：[1]Key Laboratory of Soft Chemistry and Functional Materials of the Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China

出　　处：《Chinese Science Bulletin》索引2012年第57卷第23期,共9页

基　　金：supported by the National Natural Science Foundation of China(50902070);the National High Technology Research and Development Program of China(2010AA0500293002);a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions and Nanjing University of Science and Technology Research Funding(2011PYXM03) 摘　　要：PtCo alloy nanoparticles are deposited onto graphene sheets through a facile and reproducible hydrothermal method.During the hydrothermal reaction,the reduction of graphene oxide and PtCo alloy nanoparticles loading can be achieved.X-ray diffraction (XRD) analyses reveal a good crystallinity of the supported Pt nanoparticles in the composites and the formation of PtCo alloy.X-ray photoelectron spectra (XPS) results depict that Pt mainly exists in the metallic form,while much of the cobalt is oxidized.Transmission electron microscope (TEM) observations show that the PtCo alloy nanoparticles are uniformly dispersed on graphene nanosheets compared with multiwalled carbon nanotubes (MWNTs).This PtCo-graphene composite exhibits excellent electrocatalytic activity and high poison tolerance toward poisoning species for methanol oxidation reaction,far outperforming the Pt-graphene or PtCo-MWNTs composites with the same feeding ratio of Pt/carbon. 关键词：GRAPHENE PtCo alloy nanoparticles ELECTROCATALYST METHANOL OXIDATION FUEL cells

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PtCo alloy nanoparticles supported on graphene nanosheets with high performance for methanol oxidation

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