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Investigation of the thermal stability of Mn ferrite particles synthesized by a modified co-precipitation method

查看全文 作  者:DONG [1]ChunHui;WANG [1]GaoXue;SHI [1]Lei;GUO [1]DangWei;JIANG [1]ChangJun;XUE [1]DeSheng 高影响力作者 机构地区:[1]Key Lab for Magnetism and Magnetic Materials of the Ministry of Education,Lanzhou University高影响力机构 出  处:《Science China Chemistry》索引2013年第56卷第3期,共5页高影响力期刊 基  金:supported by the National Basic Research Program of China (Grant No. 2012CB933101);the National Science Fund for Distinguished Young Scholars (Grant No. 50925103);the Key Grant Project of Chinese Ministry of Education (Grant No. 309027);the National Natural Science Foundation of China (Grant Nos. 11034004 and 50902064);the Fundamental Research Funds for Central Universities (Grant No.lzujbky-2010-74) 摘  要:Manganese ferrite particles with spinel structure were synthesized by a modified co-precipitation method,and then the thermal stability on their structural and magnetic properties was investigated by thermal annealing at different gas ambients.Experimental results showed that decomposition of metal oxides occurred when Mn ferrite particles with spinel structure were annealed under air ambient,while samples annealed in vacuum or argon remained in the spinel structural form.The highest saturation magnetization value of 58 emu/g was obtained when the sample was annealed at 400℃ in argon.The result showed that the thermal stability of MnFe2O4 was better under Ar ambient conditions or in vacuum. 关 键 词:MnFe2O4 热稳定性 共沉淀法 铁氧体 颗粒 合成 改性 尖晶石结构
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