Application of named reactions in polymer synthesis

查看全文 作　　者：Xue [1,2]Jiang;Chun [1,2]Feng;Guolin [1,2,3,4]Lu;Xiaoyu [1,2]Huang 机构地区：[1]Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Chinese Academy of Sciences;[2]Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences;[3]State Key Laboratory of Molecular Engineering of Polymers;[4]Department of Macromolecular Science, Fudan University 出　　处：《Science China Chemistry》索引2015年第58卷第11期,共15页 基　　金：supported by the National Natural Science Foundation of China(21174158,21274162,21474127);Shanghai Scientific and Technological Innovation Project(12JC1410500,13ZR1464800,14QA1404500,14520720100);the State Key Laboratory of Molecular Engineering of Polymers(K2015-02) 摘　　要：In recent years, with the rapid development of polymer science, the application of classical named reactions has transferred from small-molecule compounds to polymers. The versatility of named reactions in terms of monomer selection, solvent environment, reaction temperature, and post-modification permits the synthesis of sophisticated macromolecular structures under conditions where other reaction processes will not operate. In this review, we divided the named reactions employed in polymer-chain synthesis into three types: transition metal-catalyzed cross-coupling reactions, metal-free cross-coupling reactions, and multi-components reactions. Thus, we focused our discussion on the progress in the utilization of these named reactions in polymer synthesis. 关 键 词：高分子合成 反应温度 应用 交叉偶联反应 过渡金属催化 小分子化合物 聚合物链 高分子科学