Direct access to β-seleno sulfones at room temperature through selenosulfonylation of alkenes

查看全文 作　　者：Kai [1,2]Sun;Yunhe [1]Lv;Zuodong [1]Shi;Fangfang [1]Fu;Chong [1]Zhang;Zhiguo [3]Zhang

机构地区：[1]College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, China;[2]Henan Province Key Laboratory of New Opto-Electronic Functional Materials, Anyang 455000, China;[3]School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

出　　处：《Science China Chemistry》索引2017年第60卷第6期,共4页

基　　金：supported by the National Natural Science Foundation of China (U1504210);the China Postdoctoral Science Foundation (2015M572110);Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis (130028651) 摘　　要：A new protocol has been developed for the formation of C.Se and C.S bonds by the direct selenosulfonylation of alkenes.This protocol is operationally simplistic, has a wide substrate scope, uses readily available seleno and sulfonyl sources, and is amenable to gram-scale synthesis. This reaction represents a significant addition to the limited number of reactions available for the intermolecular selenide difunctionalization of alkenes and would be useful for the synthesis of sulfur-and selenium-containing molecules. 关键词：直接访问烯烃硒室温烃分子砜磺酰基协议

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Direct access to β-seleno sulfones at room temperature through selenosulfonylation of alkenes

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