Challenges and perspectives for manganese-based oxides for advanced aqueous zinc-ion batteries

查看全文 作　　者：Yinlei [1,2]Zhao;Yunhai [1,3]Zhu;Xinbo [1,2]Zhang

机构地区：[1]State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,China;[2]University of Science and Technology of China(USTC),Hefei,China;[3]Key Laboratory of Automobile Materials(Jilin University),Ministry of Education,Department of Materials Science and Engineering,Jilin University,Changchun,China

出　　处：《InfoMat》索引2020年第2卷第2期,共24页

基　　金：This work was financially supported by This work was financially supported by the National Natural Science Foundation of China(21725103 and 51631004);National Key R&D Program of China(2016YFB0100103,2017YFA0206704);People's Government of Jilin Province Science and Technology Development Plan Funding Project(20180101203JC);Changchun Science and Technology Development Plan Funding Project(18DY012,19SS010);the Program for the JLU Science and Technology Innovative Research Team(2017TD-09). 摘　　要：Li-ion batteries(LIBs)with excellent cycling stability and high-energy densities have already occupied the commercial rechargeable battery market.Unfortunately,the high cost and intrinsic insecurity induced by organic electrolyte severely hinder their applications in large-scale energy storage.In contrast,aqueous Zn-ion batteries(ZIBs)are being developed as an ideal candidate because of their cheapness and high security.Benefiting from high operating voltage and acceptable specific capacity,recently,manganese-based oxides with different various crystal structures have been extensively studied as cathode materials for aqueous ZIBs.This review presents research progress of manganese-based cathodes in aqueous ZIBs,including various manganese-based oxides and their zinc storage mechanisms.In addition,we also discuss some optimization strategies that aim at improving the electrochemical performance of manganese-based cathodes,and the design of flexible aqueous ZIBs based on manganese-based cathodes(MZIBs).Finally,this review summarizes some valuable research directions,which will promote the further development of aqueous MZIBs. 关键词：flexible ZIBs manganese dioxide manganese-based oxides STRATEGIES ZIBs

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Challenges and perspectives for manganese-based oxides for advanced aqueous zinc-ion batteries

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