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Electrocatalytic and photocatalytic applications of atomically precise gold-based nanoclusters

查看全文 作  者:Yongnan [1]Sun;Xiao [1]Cai;Weigang [1]Hu;Xu [1]Liu;Yan [1]Zhu 高影响力作者 机构地区:[1]School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China高影响力机构 出  处:《Science China Chemistry》索引2021年第64卷第7期,共11页高影响力期刊 基  金:supported by the National Natural Science Foundation of China(21773109,91845104)。 摘  要:With advances in cluster chemistry,atomically precise gold nanoclusters(NCs)with well-defined composition and tunable structure provide an exciting opportunity to uncover the specific roles of the geometrical and electronic structures as well as the capped ligands in overall catalytic performances.The Au NCs possess quantum energy levels and unique optical properties,which have exhibited unexpected photocatalytic and electrocatalytic activities.In this review,we first highlight the electrocatalytic applications of Au NCs,including hydrogen evolution reaction,oxygen reduction reaction,CO_2 reduction and catalytic oxidation reactions,and then present Au NCs-driven photocatalytic applications such as selective organic reactions,decomposition of pollutants and energy conversion reactions.Finally,we conclude this review with a brief perspective on the catalytic field of Au NCs. 关 键 词:NANOCLUSTERS atomic-level structure electronic structure ELECTROCATALYSIS PHOTOCATALYSIS
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