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您的检索式：作者名="Baker Rhimi"
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| 1 | Oxygen-doping of ZnIn_(2)S_(4) nanosheets towards boosted photocatalytic CO_(2) reduction显示文摘Engineering the electronic properties of semiconductor-based photocatalysts using elemental doping is an effective approach to improve their catalytic activity.Nevertheless,there still remain contradictions regarding the role of the dopants played in photocatalysis.Herein,ultrathin ZnIn_(2)S_(4)(ZIS) nanosheets with oxygen doping were synthesized by a one-pot solvothermal method.XRD,XPS and Raman spectral measurements support the presence of lattice oxygen in the oxygen-doped ZIS(O-ZIS) sample.With optimum doping of oxygen,the ultrathin O-ZIS nanosheets show enhanced CO_(2)-to-CO conversion activity with a CO_(2)-evolving rate of 1680 μmol h^(-1) g^(-1) under visible light irradiation,which is about 7 times higher than that of the pristine ZIS.First-principle calculations support that doping of oxygen in the lattice of ZnIn_(2)S_(4) nanosheets plays a key role in tuning its electronic properties.The remarkable photocatalytic performance of O-ZIS can be assigned to a synergistic consequence of a unique ultrathin-layered structure and an upward shift of the conduction band minimum(CBM) caused by the oxygen doping into ZIS and the quantum confinement effect(QCE) induced by the decreased particle size after doping as well as to the improved charge separation efficiency.The present work offers a simple elemental doping method to promote charge separation at atomic level and illustrates the roles played by oxygen doping in photocatalysis,giving new insights into highly efficient artificial photosynthesis. | Bao Pan Yu Wu Baker Rhimi Jiani Qin Ying Huang Mingzhe Yuan Chuanyi Wang | 2021 | Journal of Energy Chemistry2021，30，6： | 3 |
| 2 | Cu-Based Materials for Enhanced C_(2+) Product Selectivity in Photo-/Electro-Catalytic CO_(2) Reduction: Challenges and Prospects显示文摘Carbon dioxide conversion into valuable products using photocatalysis and electrocatalysis is an effective approach to mitigate global environmental issues and the energy shortages. Among the materials utilized for catalytic reduction of CO_(2), Cu-based materials are highly advantageous owing to their widespread availability, cost-effectiveness, and environmental sustainability. Furthermore, Cu-based materials demonstrate interesting abilities in the adsorption and activation of carbon dioxide, allowing the formation of C_(2+) compounds through C–C coupling process. Herein, the basic principles of photocatalytic CO_(2) reduction reactions(PCO_(2)RR) and electrocatalytic CO_(2) reduction reaction(ECO_(2)RR) and the pathways for the generation C_(2+) products are introduced. This review categorizes Cu-based materials into different groups including Cu metal, Cu oxides, Cu alloys, and Cu SACs, Cu heterojunctions based on their catalytic applications. The relationship between the Cu surfaces and their efficiency in both PCO_(2)RR and ECO_(2)RR is emphasized. Through a review of recent studies on PCO_(2)RR and ECO_(2)RR using Cu-based catalysts, the focus is on understanding the underlying reasons for the enhanced selectivity toward C_(2+) products. Finally, the opportunities and challenges associated with Cu-based materials in the CO_(2) catalytic reduction applications are presented, along with research directions that can guide for the design of highly active and selective Cu-based materials for CO_(2) reduction processes in the future. | Baker Rhimi Min Zhou Zaoxue Yan Xiaoyan Cai Zhifeng Jiang | 2024 | Nano-Micro Letters2024，16，4： | 0 |
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