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1篇 您的检索式:作者名="Borgea G.M.Ekoya"
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1Molecular interactions induced collapse of charge density wave quantum states in 2H tantalum disulfide nanosheets显示文摘2H-tantalum disulfide(2H-TaS_(2))is a layered metallic transition metal dichalcogenide(TMD)that has recently been studied from the perspective of new physics phenomena,including simultaneous lattice distortion and charge density modulation known as the charge density wave(CDW)phase.Here we explored the collapse of CDW states in few-layer 2H-TaS_(2)induced by molecular interactions using Raman spectroscopy.Our results indicate that the CDW states disappear in few-layer 2H-TaS_(2)with rhodamine 6G(R6G)adsorbed due to the charge transfer,which is reflected by the change of behaviors of lattice vibrational modes in 2HTaS_(2).We observed the 2-phonon mode that signifies the CDW formation in 2H-TaS_(2),becomes a phonon-hardened mode when R6G molecules are absorbed on its surface.R6G adsorption further induces the breakdown of the Raman polarization selection rule in 2H-TaS_(2),which results in the alteration of the A_(1g)phonon mode polarization state of 2H-TaS_(2).This study can shed light not only on the underlying mechanisms of CDW states but also on controlling the CDW states under a variety of environmental conditions.Borgea G.M.Ekoya Jinkun Han Junqiang Zhu Yabing Shan Ran Liu Laigui Hu Zhi-Jun Qiu Chunxiao Cong 2023Nano Research2023,16,5:0
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