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| 1 | Effect of Magnetic Field on Tribological Properties of Lubricating Oils with and without Tricresyl Phosphate显示文摘Tribological properties of neat 150 SN mineral base oil and the oils doped with different contents of tricresyl phosphate(TCP) under magnetic field or non-magnetic field were evaluated on a four-ball tribotester, on which an external magnetic field was applied. Furthermore, the morphology and the tribochemical characteristics of the worn surfaces were examined with a scanning electron microscope(SEM) and an X-ray photoelectron spectrograph(XPS). The tribological test results showed that the magnetic field improved anti-wear properties but impaired the friction-reducing properties of neat base oil and the TCP-doped oils. The worn surfaces tested in magnetic field were characterized by a slighter wear than those tested in normal condition, especially for the surfaces lubricated with the TCP-doped oils. Furthermore, the results of XPS analysis indicated that tribochemical films on the surfaces tested with TCP-doped oils were mainly composed of ferriccontaining compounds such as Fe_2O_3, Fe_3O_4 and FePO_4. Under the influence of a magnetic field, the atomic concentrations of oxygen and phosphorous in the frictional sub-surfaces were higher than those without magnetic impact. Thus it can be inferred that the improved anti-wear properties and impaired friction-reducing capabilities of lubricating oils with TCP under a magnetic field were related to the diffusion of phosphorus and oxygen into the substrate induced by magnetism. | Jiang Zeqi Fang Jianhua Chen Boshui Zheng Zhe Li Hao Xu Lai | 2016 | China Petroleum Processing & Petrochemical Technology2016,18,3: | 12 |
| 2 | Improvement of Magnetic Field on Tribological Properties of Lubricating Oils with Zinc Butyloctyldithiophosphate显示文摘Tribological properties of 150 SN mineral oil and the oils doped with different contents of zinc butyloctyldithiophosphate(T202) under magnetic field or non-magnetic field were evaluated on a four-ball tribotester by applying an external magnetic field around the friction region. Moreover, the morphology and the tribochemical characteristics of worn surfaces were examined by a scanning electron microscope(SEM) and an X-ray photoelectron spectrometer(XPS). Then the lubrication mechanisms were discussed. The tribological test results indicated that the wear scar diameters(WSDs) of steel balls lubricated by the T202-containing lubricating oils and the friction coefficients of the corresponding oil under magnetic field were smaller than those without magnetic affection. The worn surface lubricated with the T202-formulated oils in a magnetic field was smoother than that obtained under the normal condition. Furthermore, the results of XPS analysis indicated that tribochemical films on the surfaces lubricated with T202-doped oils were mainly composed of compounds such as FeSO_4, FeS and ZnS. The atomic concentrations of oxygen, sulfur, iron, zinc and phosphorus species identified in T202 under magnetic field were higher than those without magnetic impact. It can be inferred that the improved anti-wear and friction-reducing ability of T202-doped oils was attributed to the promoted tribochemical reactions and the modification of the worn surfaces induced by magnetic field. | Jiang Zeqi Fang Jianhua Chen Boshui Wu Jiang Wang Jiu Zheng Zhe | 2016 | China Petroleum Processing & Petrochemical Technology2016,18,4: | 11 |
| 3 | Effect of Biodiesel on Oxidation Stability, Detergency and Antiwear Ability of Diesel Oil显示文摘Different contents of biodiesel and petrodiesel were incorporated into diesel engine oils. The oxidative stability, detergency and antiwear performance of the formulated diesel oils were evaluated. The results indicated that, compared with petrodiesel, biodiesel was more liable to promote oxidation degradation of diesel oils, leading to worse oxidative stability, detergency and antiwear ability of the oils. | Wu Jiang Chen Boshui Fang Jianhua Wang Jiu (Department of Petrochemistry, Logistical Engineering University, Chongqing 401311) | 2011 | China Petroleum Processing & Petrochemical Technology2011,13,4: | 9 |
| 4 | Tribological Performances of Fatty Acyl Amino Acids Used as Green Additives in Lubricating Oil显示文摘磨擦并且穿 lauroyl 夫酸安, lauroyl glycine 和 lauroyl 丙氨酸的特征,在 HVI 350 矿物质润滑的使用的同样绿的添加剂上油,在四球的 tribotester.The 上被评估形态学和穿的表面的化学种类被扫描电子显微镜( SEM )和X光检查光电子分光镜( XPS )分析, respectively.The 测试结果显示三丰满的酰氨基酸能有效地改进反穿和 HVI350 | Chen Boshui Wang Jiu Fang Jianhua Huang Weijiu Sun Xia Yu Ying | 2010 | China Petroleum Processing & Petrochemical Technology2010,12,3: | 9 |
| 5 | Lubricant Biodegradation Enhancers: Designed Chemistry and Engineered Technology显示文摘In recent decades, a growing worldwide trend of developing the biodegradable lubricants has been prevailing to form a specific field of green chemistry and green engineering. Enhancement of biodegradability of unreadily biodegradable petroleum-based lubricants has as such become an urgent must. For over a decade the authors have been focusing on the improvement of biodegradability of unreadily biodegradable lubricants such as petroleum-based lubricating oils and greases. A new idea of lubricant biodegradation enhancer was put forward by the authors with the aim to stimulate the biodegradation of unreadily biodegradable lubricants by incorporating the enhancer into the lubricants in order to turn the lubricants into greener biodegradable ones and to help in situ bioremediation of lubricant-contaminated environment. This manuscript summarizes our recent efforts relating to the chemistry and technology of biodegradation enhancers for lubricants. Firstly, the chemistry of lubricant biodegradation enhancers was designed based on the principles of bioremediation for the treatment of hydrocarbon contaminated environment. Secondly, the ability of the designed biodegradation enhancers for increasing the biodegradability of unreadily biodegradable industrial lubricants was investigated through biodegradability evaluation tests, microbial population analysis, and biodegradation kinetics modeling. Finally, the impact of biodegradation enhancers on some crucial performance characteristics of lubricants such as lubricity and oxidation stability was tested via tribological evaluation and oxidation determinations. Our results have shown that the designed chemistry of nitrogenous and/or phosphorous compounds such as lauroyl glutamine, oleoyl glycine, oleic diethanolamide phosphate and lauric diethanolamide borate was outstanding in boosting biodegradation of petroleum-based lubricants which was ascribed to increase the microbial population and decrease the oil-water interfacial tension during the biodegradation process. Lubricants doped with the biodegradation enhancers exhibited much better biodegradability and higher biodegradation rate in the surrounding soils which could be well modeled by the exponential biodegradation kinetics. Furthermore, as lubricant dopants, the biodegradation enhancers also provided excellent capability in reducing friction and wear and in retarding oxidation of lubricants. In the nature of things, lubricant biodegradation enhancers, which are multi-functional not only in the improvement of biodegradability, but also in the fortification of lubricity and in the inhibition of oxidation of lubricants, are expected to be promising as a new category of lubricant additives. | Chen Boshui Gao Lingyue Fang Jianhua Zhang Nan Wu Jiang Wang Jiu | 2015 | China Petroleum Processing & Petrochemical Technology2015,17,3: | 8 |
| 6 | Friction and Wear Performance of Magnesium Alloy against Steel under Lubrication of Rapeseed Oil with BN-containing Additive显示文摘A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of the AZ91D magnesium alloy against the GCr15 bearing steel under lubrication of rapeseed oil containing BNR were evaluated on a SRV tribotester.The topography and chemical species of the worn surfaces of magnesium alloy were analyzed by a scanning electron microscope (SEM) and an X-ray photoelectron spectroscope (XPS),respectively.The test results indicated that the friction and wear of the magnesium alloy-steel tribomates could be effectively reduced by incorporating BNR into the rapeseed oil lubricant.The friction coefficients and the wear scars of magnesium alloy decreased with an increasing content of BNR.The surface lubricated with the BNR-doped rapeseed oil demonstrated less wear as compared with that lubricated with neat rapeseed oil.The enhanced anti-wear and friction-reducing abilities of rapeseed oil provided by BNR in the lubrication of magnesium alloy against steel were ascribed to the formation of a composite boundary lubrication film due to the strong adsorption of BNR and rapeseed oil onto the lubricated surfaces and their tribochemical reactions with magnesium alloy. | Fang Jianhua Chen Boshui Dong Ling Wu Jiang Wang Jiu | 2011 | China Petroleum Processing & Petrochemical Technology2011,13,1: | 6 |
| 7 | Spectroscopic Analysis of Structural Transformation in Biodiesel Oxidation显示文摘The oxidation behavior of three biodiesels of different origins,viz.rapeseed oil derived biodiesel,soybean oil derived biodiesel and waste oil based biodiesel,were tested on an oxidation tester.The chemical compositions of the biodiesels were characterized by gas chromatography.Thereafter,the structural transformation of fatty acid methyl ester(FAME)of the biodiesels was analyzed by an infrared spectrometer and an ultraviolet absorption spectrometer.The results demonstrated that the oxidation behavior of biodiesels of different origins was closely related to the composition and distribution of FAMEs.Higher concentration of unsaturated FAME with multi-double bonds exhibited poorer oxidation resistance.Furthermore,cis-trans isomerization transformation occurred in the unsaturated FAME molecules and conjugated double-bond produced during the oxidation process of biodiesel.Greater cis-trans variations corresponded to deeper oxidation degree.The higher the content of unsaturated FAME with multi-double bonds in a biodiesel,the more the conjugated double bonds was formed. | Wu Jiang Chen Boshui Fang Jianhua Wang Jiu | 2013 | China Petroleum Processing & Petrochemical Technology2013,15,3: | 4 |
| 8 | Tribological Performance of Two Potential Environmentally Friendly Ashless Vegetable Oil Additives显示文摘二潜在的新奇环境地友好的无灰的蔬菜油添加剂, 2-mercaptobenzothiazole 衍生物,di-n-dodecyl-[2-( 2-benzothiazolyl ) thio ] ethylborane ( LBN )和di-n-dodecylthio-[2-( 2-benzothiazolyl ) thio ] ethylborane ( LBNS ),被综合,他们在油菜籽的添加剂上油的 tribological 表演( RSO )被评估用一四球穿测试者。他们的防腐蚀的性质和热稳定性也被检验。钢球的穿的表面借助于扫描电子显微镜学(SEM ) 和 X 光检查光电子光谱学(XPS ) 被分析。结果证明 2-mercaptobenzothiazole 衍生物展出了优秀防腐蚀的性质和高热的稳定性。而且,他们有的好带负担的能力和减少磨擦的性质。样品的 PB 价值在下列顺序减少了:LBNS > LBN > RSO。说明的 XPS 检查的结果准备混合物的优秀 tribological 行为在 RSO 用作添加剂,这在穿的表面上被归因于一部保护的润滑油电影的形成,它由吸附层和包含 Fe3O4 的反应层组成了, FeS , Fe2 ( SO4 ) 3 ,2月,和器官的包含氮的混合物。 | You Jianwei Li Fenfang Chen Boshui | 2010 | China Petroleum Processing & Petrochemical Technology2010,12,1: | 3 |
| 9 | Biodegradation of Petroleum Hydrocarbon by Pseudomonas Aeruginosa显示文摘A bacterial strain of the genus Pseudomonas aeruginosa was inoculated into a hydrocarbon culture medium and incubated for a definite period of time. The ability of the bacterial strain to biodegrade a hydrocarbon, viz. n-hexadecane, was evaluated through determining the hexadecane concentration in the inoculated culture medium on a gas chromatograph (GC). The effect of pH value on the degrading ability of the bacterial isolate and the impact of temperature on microbial growth were also explored. Test results showed that Pseudomonas aeruginosa was markedly effective in biodegrading n-hexadecane. Furthermore, the ability of Pseudomonas aeruginosa to biodegrade n-hexadecane was different at various pH values. Pseudomonas aeruginosa provided excellent degrading ability at a pH value of 7.0. The microbial cells of Pseudomonas aeruginosa increased with an increasing incubation duration at temperatures ranging from 28 ℃ to 35 ℃, and an exponential phase of microbial growth was observed. | Chen Boshui Zhang Nan Wu Jiang Wang Jiu Fang Jianhua | 2012 | China Petroleum Processing & Petrochemical Technology2012,14,2: | 3 |
| 10 | Pyrolysis Characteristics and Kinetics of Methyl Oleate Based on TG-FTIR Method显示文摘The thermal decomposition characteristics of methyl oleate were preliminarily investigated under nitrogen atmosphere by a thermogravimetric analyzer when the ester was heated at a heating rate of 10 ℃/min from room temperature to 600 ℃. Furthermore, the pyrolytic and kinetic characteristics of methyl oleate were intensively studied at different heating rates. The gaseous species obtained during thermal decomposition were also identified by the TG-FTIR coupling analysis. The results showed that the pyrolysis of methyl oleate proceeded in three stages, viz. the drying stage, the main pyrolysis stage and the residual pyrolysis stage. The initial decomposition temperature, the maximum weight loss temperature, the peak decomposition temperature and the rate of maximum weight loss of methyl oleate increased with the increasing heating rates. Gaseous CO, CO2 and H2 O were the typical decomposition products from pyrolysis of methyl oleate. In addition, a kinetic model for thermal decomposition of methyl oleate was built up based on the experimental results using the CoatsRedfern integral method and the multiple-linear regression method. The activation energy, the pre-exponential factor, the reaction order and the kinetic equation for thermal decomposition of methyl oleate were obtained. Comparison of the experimental data with the calculated ones and analysis of statistical errors of pyrolysis ratios demonstrated that the kinetic model was reliable for studying the pyrolysis of methyl oleate. Finally, the kinetic compensation effect between the preexponential factors and the activation energy in the pyrolysis of methyl oleate was also confirmed. | Wang Xuechun Fang Jianhua Chen Boshui Wang Jiu Wu Jiang | 2015 | China Petroleum Processing & Petrochemical Technology2015,17,2: | 2 |
| 11 | Boosted Biodegradability and Tribological Properties of Mineral Base Oil by Methyl Diethanolamine Fatty Acid Esters显示文摘Methyl diethanolamine fatty acid esters, viz. methyl diethanolamine octanoate and methyl diethanolamine oleate,were prepared. Their impacts on the biodegradability and tribological properties of mineral base oil 400 SN were evaluated by a tester for fast evaluating the biodegradability of lubricants and by a four-ball tester, respectively. The results showed that methyl diethanolamine octanoate and methyl diethanolamine oleate both could markedly promote the biodegradation of the oil and improved its tribological properties. The improvement of biodegradability was attributed to the enhanced growth and quantity of microbes by methyl diethanolamine fatty acid esters. The worn surfaces were analyzed by a scanning electron microscope(SEM) equipped with an energy dispersive spectrometer(EDS) and an X-ray photoelectron spectroscope(XPS). The results indicated that the enhancement of friction-reducing and anti-wear properties of the mineral oil was attributed to the formation of complicated boundary lubrication films composed of species such as Fe_2O_3, Fe_3O_4 and organic nitrogen-containing compounds with a structure of –C-N-or R-NH_2. | Ding Jianhua Fang Jianhua Chen Boshui Zhang Nan Fan Xingyu Zheng Zhe | 2018 | China Petroleum Processing & Petrochemical Technology2018,20,4: | 2 |
| 12 | Biodegradability and Tribological Properties of Mineral Base Oil Enhanced by Caprylic Methyl Diethanolamine Phosphate Ester显示文摘The influence of synthetic caprylic methyl diethanolamine phosphate ester (abbreviated as MDEACP) on biodegradability and tribological properties of 400SN mineral base oil was studied. The biodegradability of the neat base oil and the oil doped with MDEACP was determined on a biodegradation tester. The tribological properties of the neat base oil and the oil doped with MDEACP were evaluated on a four-ball tester. Moreover, the worn surfaces were investigated by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results revealed that MDEACP significantly promoted the biodegradation of the mineral base oil. The improvement in biodegradability was attributed to the enhanced growth and quantity of microbes by MDEACP. Furthermore, MDEACP enhanced the anti-wear properties, the friction-reducing properties, and the extreme pressure properties of the base oil. It was mainly attributed to the formation of the complex boundary lubrication film resulted from the adsorption and tribochemical reactions of MDEACP on the friction surface. | Ding Jianhua Fang Jianhua Chen Boshui Liu Ping Fan Xingyu Chen Ran | 2019 | China Petroleum Processing & Petrochemical Technology2019,21,2: | 1 |
| 13 | Effect of cold flow improvers on flow properties of soybean biodiesel显示文摘 | Chen Boshui Sun Yuqiu Fang Jianhua et a1 | 2010 | Biomass Bioenergy2010,34,9: | 1 |
| 14 | Preparation and Tribological Behavior of Hydrophobic Lanthanum Borate Nanosheets in Rapeseed Oil显示文摘Oleic acid-capped lanthanum borate(abbreviated as OA/La BO_3·H_2O) nanosheets were prepared by the hydrothermal method. The microstructures of as-prepared OA/La BO_3·H_2O were characterized by means of SEM, TEM, EDS, FTIR and XRD, respectively. Moreover, the friction and wear properties of OA/La BO_3·H_2O as a lubricant additive in rapeseed oil were evaluated on a four-ball tribotester. The tribochemical characteristics of worn surfaces were investigated by SEM and XPS. The results showed that the hydrophobic OA/La BO_3·H_2O nanosheets exhibited their morphology with a diameter in the range of 100 nm to 300 nm and a thickness of about 25 nm, and displayed excellent dispersing stability in rapeseed oil. In the meantime, the rapeseed oil doped with OA/La BO_3·H_2O nanosheets markedly decreased the friction and wear of steel balls, and the optimal friction-reducing and antiwear ability of rapeseed oil was obtained at an OA/La BO_3·H_2O content of 1.0%. The outstanding tribological performance of OA/La BO_3·H_2O in rapeseed oil was attributed to the formation of a composite boundary lubrication film mainly composed of lubricious tribochemical species of B_2O_3, La_2O_3 and Fe_2O_3, and deposits of OA/La BO_3·H_2O nanosheets as well as the adsorbates of rapeseed oil on rubbed surfaces. | Gu Kecheng Chen Boshui Xue Ming Wang Jiu Fang Jianhua Wu Jiang | 2016 | China Petroleum Processing & Petrochemical Technology2016,18,2: | 1 |
| 15 | Cold flow prop-erties and crystal morphologies of biodiesel blends显示文摘 | Chen Boshui 1 SunYuqiu Fang Jianhua | 2010 | Chem-istry and Technology of Fuels and 0ils2010,,: | 1 |
| 16 | Cold flow prop-erties and crystal morphologies of biodiesel blends显示文摘 | Chen Boshui 1 SunYuqiu Fang Jianhua | 2010 | Chem-istry and Technology of Fuels and 0ils2010,,: | 1 |
| 17 | The binding of anti-wear additives to iron surfaces: quantum chemical calculations and tribological tests显示文摘 | Weijiu Huang Yuanqiang Tan Boshui Chen | 2003 | Tribology International2003,36,: | 1 |
| 18 | Effect of Oleic Acid Tris-(2-hydroxyethyl) isocyanurate Phosphate Ester on Biodegradability and Tribological Performance of Mineral Lubricating Oil显示文摘The oil solubility of synthetic oleic acid tris-(2-hydroxyethyl) isocyanurate phosphate ester(abbreviated as OHTP hereinafter) and its influence on the biodegradability and tribological performance of 400 SN mineral oil were investigated on a tester and a four-ball tribotester,respectively,for fast evaluating the biodegradability of lubricants.Furthermore,the morphologies and tribochemical species of the worn surfaces lubricated by OHTP-doped oil were studied by scanning electron microscope(SEM) and X-ray photoelectron spectroscope(XPS).The results indicated that OHTP possessed good oil solubility and could improve obviously the biodegradability,the extreme pressure properties,the anti-wear properties and friction-reducing properties of the 400 SN mineral oil.The analytical results of XPS spectra showed that the composite boundary lubrication films were mainly composed of absorbed films and tribochemical species such as FePO-4,Fe_3(PO_4)_2,Fe_2O_3 and Fe_3O_4,which contributed to improving the tribological performances. | Ding Jianhua Fang Jianhua Chen Boshui Zhang Nan Fan Xingyu Zheng Zhe | 2018 | China Petroleum Processing & Petrochemical Technology2018,20,2: | 1 |
| 19 | Enhancedbiodegradability, lubricity and corrosiveness oflubricating oil by oleic acid diethanolamide phosphate显示文摘 | CHEN Boshui WANG Jiu FANG Jianhua | 2012 | Tribology in Industry2012,34,3: | 1 |
| 20 | Enhanced biodegradability and lubricity of minerallubricating oil by fatty acidic diethanolamide borates显示文摘 | CHEN Boshui ZHANG Nan WU Jiang | 2013 | Green Chemistry2013,15,3: | 1 |