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2篇 您的检索式:作者名="C.Armellini"
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1Er^(3+)-activated silica inverse opals synthesized by the solgel method显示文摘We present the details of the sol-gel processing used to realize inverse silica opal,where the silica was activated with 0.3 mol% of Er3+ ions. The template(direct opal) was obtained assembling polystyrene spheres of the dimensions of 260 nm by means of a vertical deposition technique. The Er3+-activated silica inverse opal was obtained infiltrating,into the void of the template,the silica sol doped with Er3+ ions and subsequently removing the polystyrene spheres by means of calcinations. Scanning electron microscope showed that the inverse opals possess a fcc structure with a air hollows of about 210 nm and a photonic band gap,in the visible range,was observed from reflectance measurements. Spectroscopic properties of Er3+-activated silica inverse opal were investigated by luminescence spectroscopy,where,upon excitation at 514.5 nm,an emission of 4I13/2 → 4I15/2 of Er3+ ions transition with a 21 nm bandwidth was observed. Moreover the 4I13/2 level decay curve presents a single-exponential profile,with a measured lifetime of 18 ms,corresponding a high quantum efficiency of the system.A. Chiappini C.Armellini A. Chiasera Y. Jestin M. Ferrari M. Mattarelli M. Montagna E. Moser C. Tosello L. Zampedri G. Nunzi Conti S. Pelli R. M. Almeida G. C. Righini 2007Optoelectronics Letters2007,3,3:2
2Effect of Yb^(3+) concentration on Er^(3+) luminescence properties of sol-gelderived silica-alumina xerogels显示文摘Er3+/Yb3+ co-doped silica-alumina monolithic xerogels were prepared with the same concentration on 2 000 Er/Si ppm and 6 000 Al/Si ppm.The Yb/Si content was varied from 0 to 4 000 ppm.Densification of the samples was achieved by thermal treatment in air at 950 ℃ for 120 hours with a heating rate 0.1 ℃/min.Photoluminescence spectroscopy was used to obtain information about the effective excitation efficiency of Er3+ ions by co-doping with Yb 3+ ions.The infrared-to-visible up-conversion luminescence has been investigated upon continuous wave excitation at 980 nm.The samples exhibit red,green and blue up-conversion emission.It is found that the intensity of up-conversion luminescence increases with increasing Yb3+ doping concentration.An opposite behavior is observed for the 4I13/2 luminescence of the Er3+ ions.K.Tran Ngoc H.Pham Thanh C.Nguyen Duc C.Armellini A.Chiasera M.Ferrari Y.Jestin M.Montagna E.Moser S.Pelli G.C.Righini 2006Optoelectronics Letters2006,2,5:0
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