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| 1 | Zircon U-Pb geochronological framework of Qitianling granite batholith, middle part of Nanling Range, South China显示文摘The Qitianling granite batholith (QGB) is located in the southern Hunan Province, middle part of the Nanling Range, South China. Its total exposure area is about 520 km2. Based on our 25 single grain zircon U-Pb age data and 7 published data as well as the geological, petrological, and space distribution characteristics, we conclude that QGB is an Early Yanshanian (Jurassic) multi-staged composite pluton. Its formation process can be subdivided into three major stages. The first stage, emplaced at 163―160 Ma with a peak at about 161 Ma, is mainly composed of hornblende-biotite monzonitic granites and locally biotite granites, and distributed in the eastern, northern, and western peripheral parts of the pluton. The second stage, emplaced at 157―153 Ma with a peak at 157―156 Ma, is mainly composed of biotite granites and locally containing hornblende, and distributed in the middle and southeastern parts of the pluton. The third stage, emplaced at 150―146 Ma with a peak at about 149 Ma, is mainly composed of fine-grained (locally porphyritic) biotite granites, and distributed in the middle-southern part of the pluton. Each stage can be further disintegrated into several granite bodies. The first two intrusive stages comprise the major phase of QGB, and the third intrusive stage comprises the additional phase. Many second stage fine-grained granite bosses and dykes intruded into the first stage host granites with clear chilling margin-baking phenomena at their intrusive contacts. They were emplaced in the open fracture space of the earlier stage consolidated rocks. Their isotopic ages are mostly 2―6 Ma younger than their hosts. Conceivably, the time interval from magma emplacement, through cooling, crystallization, solidification, up to fracturing of the earlier stage granites cannot exceed 2―6 Ma. During the Middle-Late Jurassic in the Qitianling area and neighboring Nanling Range, the coeval granitic and basic-intermediate magmatic activities were widely developed. It indicates that the Early Yanshanian period was the culmination time of magmatic activities in this region. The Nanling Range was under a post-orogenic, intracontinental geotectonic environment with an obvious lithospheric extension and thinning. The crust-mantle interaction played an important role in formation of granitic rocks in this region. | ZHU JinChu WANG RuCheng ZHANG PeiHua XIE CaiFu ZHANG WenLan ZHAO KuiDong XIE Lei YANG Ce CHE XuDong YU APeng WANG LuBin | 2009 | Science China Earth Sciences2009，52，9： | 27 |
| 2 | Identification of Hercynian shoshonitic intrusive rocks in central Hainan Island and its geotectonic implications显示文摘An identification has been made of some shoshonitic intrusive rocks in central Hainan Island recently. These rocks are K-rich (K2O=2.9%―5.1%, K2O/Na2O=0.95―2.12), distinctly enriched in LILE and LREE, strongly depleted in Nb, Ta, and moder- ately depleted in Sr and Ti, with (87Sr/86Sr)i = 0.70859―0.71425 and ε Nd(t) = (?2.77―?7.49). They were derived from an EMⅡ-type mantle source. The enrichment process is related to metasomatism of depleted mantle caused by a great amount of fluid-melt released from oceanic crust and terri- genous sediments at great depth (eclogite facies) during the subduction of the South China plate under the Indochina-South China Sea plate in the Carbon- iferous–Early Permian. A SHRIMP U-Pb zircon dating yields a crystallization age of 272±7 Ma for the sho- shonitic intrusions, which is coeval with the strongly peraluminous granites found in central Hainan Island. These two kinds of rocks generally possess syn-intrusion ductile deformation structures. Thus they are considered to have been generated during the early stage (syn-thrust phase) of a post-collisional event. The primary magma of shoshonitic rocks was produced at a depth > 80 km by decompression- dehydration melting of previously enriched litho- spheric mantle wedge, phlogopite-bearing garnet peridotite, which was in turn caused by the break-off of a descendent slab and upwelling of a hot as- thenosphere. The rising of melts was accompaniedby crustal contamination and crystallization fractiona- tion (AFC). Combining with other related data, it is proposed that the southwards subduction and amal- gamation of the South China plate with the Indo- China-South China Sea plate took place at ca. 287- 278 Ma, which was a part of the convergence proc- ess of the Pangea supercontinent. The suture zone was probably located along the line of Song Ma-Beibu Gulf-north margin of the Yunkai Moun- tains-Wuyi Mountains. | XIE Caifu ZHU Jinchu DING Shijiang ZHANG Yeming FU Tai'an LI Zhihong | 2006 | Chinese Science Bulletin2006，51，20： | 17 |
| 3 | Hydrocarbon migration and accumulation along the fault intersection zone-a case study on the reef-flat systems of the No.1 slope break zone in the Tazhong area, Tarim Basin显示文摘Understanding hydrocarbon migration and accumulation mechanisms is one of the key scientif ic problems that should be solved for effective hydrocarbon exploration in the superimposed basins developed in northwest China. The northwest striking No.1 slope break zone, which is a representative of superimposed basins in the Tarim Basin, can be divided into five parts due to the intersection of the northeast strike-slip faults. Controlled by the tectonic framework, the types and properties of reservoirs and the hydrocarbon compositions can also be divided into five parts from east to west. Anomalies of all the parameters were found on the fault intersection zone and weakened up-dip along the structural ridge away from it. Thus, it can be inferred that the intersection zone is the hydrocarbon charging position. This new conclusion differs greatly from the traditional viewpoint, which believes that the hydrocarbon migrates and accumulates along the whole plane of the No.1 slope break zone. The viewpoint is further supported by the evidence from the theory of main pathway systems, obvious improvement of the reservoir quality (2-3 orders of magnitude at the intersection zone) and the formation mechanisms of the fault intersection zone. Differential hydrocarbon migration and entrapment exists in and around the strike- slip faults. This is controlled by the internal structure of faults. It is concluded that the more complicated the fault structure is, the more significant the effects will be. If there is a deformation band, it will hinder the cross fault migration due to the common feature of two to four orders of magnitude reduction in permeability. Otherwise, hydrocarbons tend to accumulate in the up-dip structure under the control of buoyancy. Further research on the internal fault structure should be emphasized. | Xiang Caifu Pang Xiongqi Yang Wenjing Wang Jianzhong LiQiming Liu Luofu Li Yanqun | 2010 | Petroleum Science2010，7，2： | 14 |
| 4 | Dynamic Field Division of Hydrocarbon Migration,Accumulation and Hydrocarbon Enrichment Rules in Sedimentary Basins显示文摘Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much lower in the deep parts of basins: at a depth of 7000 m, hydrocarbons can accumulate only in rocks with porosity less than 5%. However, in the shallow parts of basins (i.e., depths of around 1000 m), hydrocarbon can accumulate in rocks only when porosity is over 20%. Second, hydrocarbon reservoirs tend to exhibit negative pressures after hydrocarbon accumulation at depth, with a pressure coefficient less than 0.7. However, hydrocarbon reservoirs at shallow depths tend to exhibit high pressure after hydrocarbon accumulation. Third, deep reservoirs tend to exhibit characteristics of oil (-gas)-water inversion, indicating that the oil (gas) accumulated under the water. However, the oil (gas) tends to accumulate over water in shallow reservoirs. Fourth, continuous unconventional tight hydrocarbon reservoirs are distributed widely in deep reservoirs, where the buoyancy force is not the primary dynamic force and the caprock is not involved during the process of hydrocarbon accumulation. Conversely, the majority of hydrocarbons in shallow regions accumulate in traps with complex structures. The results of this study indicate that two dynamic boundary conditions are primarily responsible for the above phenomena: a lower limit to the buoyancy force and the lower limit of hydrocarbon accumulation overall, corresponding to about 10%-12% porosity and irreducible water saturation of 100%, respectively. These two dynamic boundary conditions were used to divide sedimentary basins into three different dynamic fields of hydrocarbon accumulation: the free fluid dynamic field, limit fluid dynamic field, and restrain fluid dynamic field. The free fluid dynamic field is located between the surface and the lower limit of the buoyancy force, such that hydrocarbons in this field migrate and accumulate under the influence of, for example, the buoyancy force, pressure, hydrodynamic force, and capillary force. The hydrocarbon reservoirs formed are characterized as 'four high,' indicating that they accumulate in high structures, are sealed in high locations, migrate into areas of high porosity, and are stored in reservoirs at high pressure. The basic features of distribution and accumulation in this case include hydrocarbon migration as a result of the buoyancy force and formation of a reservoir by a caprock. The limit fluid dynamic field is located between the lower limit of the buoyancy force and the lower limit of hydrocarbon accumulation overall; the hydrocarbon migrates and accumulates as a result of, for example, the molecular expansion force and the capillary force. The hydrocarbon reservoirs formed are characterized as 'four low,' indicating that hydrocarbons accumulate in low structures, migrate into areas of low porosity, and accumulate in reservoirs with low pressure, and that oil(-gas)-water inversion occurs at low locations. Continuous hydrocarbon accumulation over a large area is a basic feature of this field. The restrain fluid dynamic field is located under the bottom of hydrocarbon accumulation, such that the entire pore space is filled with water. Hydrocarbons migrate as a result of the molecular diffusion force only. This field lacks many of the basic conditions required for formation of hydrocarbon reservoirs: there is no effective porosity, movable fluid, or hydrocarbon accumulation, and potential for hydrocarbon exploration is low. Many conventional hydrocarbon resources have been discovered and exploited in the free fluid dynamic field of shallow reservoirs, where exploration potential was previously considered to be low. Continuous unconventional tight hydrocarbon resources have been discovered in the limit fluid dynamic field of deep reservoirs; the exploration potential of this setting is thought to be tremendous, indicating that future exploration should be focused primarily in this direction. | PANG Xiongqi LIU Keyu MA Zhongzhen JIANG Zhenxue XIANG Caifu HUO Zhipeng PANG Hong CHEN Junqing | 2012 | Acta Geologica Sinica(English Edition)2012，86，6： | 13 |
| 5 | Advances and problems in hydrocarbon exploration in the Tazhong area, Tarim Basin显示文摘Located in the middle of the Tarim Basin, Tazhong is a typical area of compound reservoirs rich in oil and gas found in the Carboniferous, Silurian and Ordovician strata. The proved, probable and possible reserves (3P reserves) in the area amount to 5×108 tons, so it is of great significance to study the advances and problems in hydrocarbon exploration in the Tazhong area. On the basis of exploration history and analysis of scientific problems, we outline eight achievements: distribution characteristics of reservoirs, stages of reservoir formation, different sources of oil and gas and their respective contributions, the effective regional caprock and reservoir-caprock combinations dominating the vertical distribution of hydrocarbon reservoirs, the control of the Tazhong Palaeo-uplift on reservoir formation and establishing geologic models, structure balance belts influencing the reconstruction and residual potential of reservoirs after accumulation, the rules and mechanisms of fractures controlling oil and gas, and the types of favorable reservoirs and their characteristics of controlling oil and gas distribution. We further point out the main problems about the oil and gas exploration in the Tazhong area and put forward some relevant proposals. | Zhou Xinyuan Pang Xiongqi Li Qiming Pang Hong Xiang Caifu Jiang Zhenxne Li Sumei Liu Luofu | 2010 | Petroleum Science2010，7，2： | 12 |
| 6 | Genesis of Highly Fractionated I-Type Granites from Fengshun Complex:Implications to Tectonic Evolutions of South China显示文摘The South China Block is characterized by the large-scale emplacement of felsic magmas and giant ore deposits during the Yanshanian. We present zircon Hf isotopic compositions, whole-rock major and trace element compositions of the Fengshun complex, located in eastern Guangdong Province, South China. The Fengshun complex is a multi-stage magmatic intrusion. It is composed of two main units, i.e., the Mantoushan(MTS) syeno-monzogranites, alkali feldspar granites and the Hulutian(HLT) alkali feldspar granites. LA-ICPMS zircon dating shows that the complex emplaced in 166–161 and 139±2 Ma, respectively. Geochemically, the MTS granites show relatively various geochemical compositions with low REE contents(87.76×10^(-6)–249.71×10^(-6)), Rb/Sr ratios(1.19–58.93), pronounced Eu negative anomaly(0.01–0.37) and low Nb/Ta ratios(2.40–6.82). In contrast, the HLT granites exhibit relatively stable geochemical characteristics with high REE contents(147.35×10^(-6)– 282.17×10^(-6)), Rb/Sr ratios(2.05–10.30) and relatively high Nb/Ta ratios(4.45–13.00). The isotopic data of the MTS granites display relatively enriched values, with I_(Sr) varying from 0.708 2 to 0.709 7, εNd(t) from-7.8 to-6.9 and εHf(t) from-7.4 to-3.2, in comparison with those of the HLT which are I_(Sr)=0.703 05–0.704 77, εNd(t)=-5–-3.4 and εHf(t)=-0.7–1.8). The two-stage model ages of the MTS granites(T_(2DM)(Nd)=1.51–1.59 Ga and T_(2DM)(Hf)=1.26–1.48 Ga) are also higher than those of the HLT granites(T_(2DM)(Nd)=1.21–1.34 Ga and T_(2DM)(Hf)=0.96–1.10 Ga). Thus the MTS and HLT granites might originate from different sources. The former is more likely derived from partial melting of Meso-Proterozoic basement triggered by upwelling of asthenosphere and/or underplate of the basaltic magma and then extensive fractional crystallisation, similar to the genesis of Early Yanshanian granitoids of the EW-trending tectono-magmatism belt in the Nanling range. In comparison, the latter might have involved with asthenosphere component, similar to the Early Cretaceous granitoids of NE-NNE-trending granitoid-volcanic belt in coastal region, southeastern China. We propose that the MTS granites were mainly formed in Paleo-Tethyan post-orogenic extensional tectonic setting whereas the HLT granites were formed in the back-arc extensional tectonic setting. The period at 139 Ma represents the initial time of roll-back of the paleo-Pacific Plate in SE-trending. | Zuomin Zhou Changqian Ma Caifu Xie Lianxun Wang Yuanyuan Liu Wei Liu | 2016 | Journal of Earth Science2016，27，3： | 11 |
| 7 | Main progress and problems in research on Ordovician hydrocarbon accumulation in the Tarim Basin显示文摘The Tarim Basin is the largest petroliferous basin in the northwest of China, and is composed of a Paleozoic marine craton basin and a Meso-Cenozoic continental foreland basin. It is of great significance in exploration of Ordovician. In over 50 years of exploration, oil and gas totaling over 1.6 billion tonnes oil-equivalent has been discovered in the Ordovician carbonate formation. The accumulation mechanisms and distribution rules are quite complicated because of the burial depth more than 3,500 m, multi-source, and multi-stage accumulation, adjustment, reconstruction and re-enrichment in Ordovician. In this paper, we summarized four major advances in the hydrocarbon accumulation mechanisms of Ordovician carbonate reservoirs. First, oil came from Cambrian and Ordovician source rocks separately and as a mixture, while natural gas was mainly cracked gas generated from the Cambrian-Lower Ordovician crude oil. Second, most hydrocarbon migrated along unconformities and faults, with different directions in different regions. Third, hydrocarbon migration and accumulation had four periods: Caledonian, early Hercynian, late Hercynian and Himalayan, and the latter two were the most important for oil and gas exploration. Fourth, hydrocarbon accumulation and evolution can be generally divided into four stages: Caledonian (the period of hydrocarbon accumulation), early Hercynian (the period of destruction), late Hercynian (the period of hydrocarbon reconstruction and re-accumulation), and Himalayan (the period of hydrocarbon adjustment and re-accumulation). Source rocks (S), combinations of reservoir-seal (C), paleo-uplifts (M), structure balance belt (B) matched in the same time (T) control the hydrocarbon accumulation and distribution in the Ordovician formations. Reservoir adjustment and reconstruction can be classified into two modes of physical adjustment and variation of chemical compositions and five mechanisms. These mechanisms are occurrence displacement, biodegradation, multi-source mixing, high-temperature cracking and late gas invasion. Late hydrocarbon accumulation effects controlled the distribution of current hydrocarbon. The T-BCMS model is a basic geological model to help understanding the control of reservoirs. At present, the main problems of hydrocarbon accumulation focus on two aspects, dynamic mechanisms of hydrocarbon accumulation and the quantitative models of oil-bearing in traps, which need further systemic research. | Pang Xiongqi Tian Jun Pang Hong Xiang Caifu Jiang Zhenxue Li Sumei | 2010 | Petroleum Science2010，7，2： | 10 |
| 8 | Characteristics of petroleum accumulation in syncline of the Songliao basin and discussion on its accumulation mechanism显示文摘The relation between oil and water in reservoirs with low and ultra-low permeability is very complicated. Gravitational separation of oil and water is not obvious. Normal reservoirs are located in depression and structural high spot, oil and water transitions are located in their middle. Stagnation is the key fact of oil-forming reservoir in the axis of a syncline based on the research of oil, gas and water migration manner, dynamics and non-Darcy flow in the Songliao basin. In low and ultra-low permeable reservoir, gas and water migrate easily through pore throats because their molecules are generally smaller than the pore throats; but the minimum diameter of oil droplets is larger than pore throats and they must be deformed to go through. Thus, gas and water migrate in advance of oil, and oil droplets remain behind. Pressure differential and the buoyancy force in a syncline reservoir are a main fluid driving force; and capillary force is the main resistance to flow. When the dynamics force is less than resistance, oil is immobile. When the buoyancy force is less than the capillary force, a gravitational separation of oil and water does not occur. The reservoir in the mature source rock of a syncline area with the low and ul- tra-low permeability belongs to an unconventional petroleum reservoir. | WU HeYong LIANG XiaoDong XIANG CaiFu WANG YueWen | 2007 | Science China Earth Sciences2007，50，5： | 9 |
| 9 | Kinetics simulation and experimental observation of fine microstructure of 9%Ni cryogenic steel processed by QLT heat treatment显示文摘Thermo-Calc and Dictra commercial calculation software programs have been used to simulate the formation of fine microstructure of 9%Ni cryogenic steel processed by quench–lamellarize–temper(QLT)heat treatment.The calculations show many compositional fluctuations in each single-martensite lath after QLT treatment;the peak concentrations of carbon and nickel reach about 0.40%and 18%,respectively.The width of the C or Ni element-enriched zone increases when the critical lamellarizing temperature decreases or the temper temperature increases.Extending the temper time has a similar effect on the element profiles.The simulation results are in accordance with the observed fine microstructures. | Tao Pan Jing Zhu Caifu Yang Hang Su | 2014 | Chinese Science Bulletin2014，59，15： | 8 |
| 10 | Timing of Metamorphism and Provenance of the Metamorphic Basement of the Xiangshan Uranium Orefield, Jiangxi Province, China显示文摘The origin, age and evolution of the Precambrian metamorphic basement of southern China provide useful insights into early crustal development. Here, we present new laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) U–Pb age data for detrital zircons from five samples of the Precambrian metamorphic basement of the Xiangshan uranium orefield. Two of these samples, from the northern Xiangshan volcanic basin, yielded a total of 140 U–Pb ages that cluster within the Neoproterozoic(773–963 Ma; 79.3% of data points), with the rest being scattered through the Paleoproterozoic and Mesoproterozoic, along with a single Archean age. These ages indicate that this basement material is associated with the Cathaysia Block. In comparison, the 172 concordant ages from the other three samples from the southern part of the Xiangshan volcanic basin cluster within the Neoproterozoic(767–944 Ma; 59.8%) as well as the Proterozoic(37.8%) and the Archean(2502–2712 Ma; 14.5%). These samples are also free of zircons with Grenvillian ages, indicating that these units are associated with the southeastern Yangtze Block. Combining these data with the geochemistry of these units, which suggests that the metamorphosed sedimentary rocks within the northern and southern parts of the Xiangshan basin have a common component from a magmatic island arc that formed during the early Neoproterozoic, we infer that the basin was located along the boundary between the Cathaysian and Yangtze blocks. In addition, the zircons within the samples from the southern and northern parts of the Xiangshan basin show different pre-Neoproterozoic(963 Ma) age populations but similar postNeoproterozoic zircon populations, indicating that the amalgamation of the Cathaysian and Yangtze blocks occurred after the Neoproterozoic(960 Ma), with magmatism peaking at 830 Ma and rifting starting at ~770 Ma, leading to the subsequent deposition(from bottom to top) of the Shenshan, Kuli, and Shangshi formations. | GUO Fusheng SHI Guo YANG Qingkun ZHANG Wanliang XIE Caifu ZHOU Wanpeng ZHANG Jiewei | 2018 | Acta Geologica Sinica(English Edition)2018，92，1： | 6 |
| 11 | Thermochemical Sulfate Reduction in the Tazhong District,Tarim Basin,Northeast China:Evidence from Formation Water and Natural Gas Geochemistry显示文摘形成水和天然气地球化学在的系统的分析中央在迟了的阶段的煤气的侵略被天然气的 H2S 和 CO2 的内容的增加伴随的 Tarim 盆( CUTB )表演高举,由形成高全部的溶解固体形成流水,由 HCO 的内容的增加? 3 ,相对 Cl ?,由第二家庭离子的增加(Ca2+,Mg2+,Sr2+和Ba2+)并且由 SO2 的内容的减少? 4 ,相对 Cl ?。上述现象能仅仅由 thermochemical 硫酸盐减小(TSR ) 的方法被解释。TSR 经常发生在油和水的转变地区并且经常在下列反应公式被描述:CH+CaSO4+H-2OH2S+CO2+CaCO3。(1 ) 溶解了 SO2 ? 当 H2S 和 CO2 被产生时, 4 在上述反应在形成水里被消费,导致 SO2 的减少 ? 4 在形成水和在天然气的 H2S 和 CO2 的增加里。如果形成水存在,产生 CO2 将继续与碳酸盐反应形成酸式碳酸盐,它能在形成水里被溶解,因此导致 Ca2+ 和 HCO 的丰富 ? 3。上述反应能被下列方程描述:CO2+H2O+CaCO3Ca2++2HCO ? 3。在 CUTB 的寒武纪、更低的奥陶纪的 stratigraphic 温度超过了 120 整瑣湯捩栠獩潴祲漠?桚橥慩杮?畆楪湡?湡?楊湡硧?牰癯湩散?景猠畯桴?楨慮椠?浩潰瑲湡?潦?湵敤獲慴摮湩?桴?整瑣湯捩攠潶畬楴湯漠?潓瑵?桃湩?畢?瑩?慭浧瑡捩愠瑣癩瑩?瀠瑥潲敧敮楳?猠牴瑡杩慲桰捩猠煥敵据?景琠敨?浡慩獮慨?片畯?獩猠楴汬猠牴湯汧?潣瑮潲敶獲慩??牥?敷瀠敲敳瑮渠睥猠湥楳楴敶栠杩?敲潳畬楴湯椠湯洠捩潲瀭潲敢???偍??A稠物潣?敧'覡睖珱K杯捩污搠瑡?潦?桴?慍業湡桳湡?潲灵愠摮瀠瑥潲牧灡楨慣?慤慴琠?潣獮牴楡?桴?...桴? | XIANG Caifu PANG Xiongqi WANG Jianzhong LI Qiming WANG Hongping ZHOU Changqian YANG Haijun | 2010 | Acta Geologica Sinica(English Edition)2010，84，2： | 4 |
| 12 | Key factors controlling hydrocarbon accumulations in Ordovician carbonate reservoirs in the Tazhong area, Tarim basin, western China显示文摘 | Hong Pang Junqing Chen Xiongqi Pang Luofu Liu Keyu Liu Caifu Xiang | 2013 | Marine and Petroleum Geology2013，，： | 4 |
| 13 | Pseudocapacitance boosted N-doped carbon coated Fe7S8 nanoaggregates as promising anode materials for lithium and sodium storage显示文摘Herein,the core-shell structured N-doped carbon coated Fe7S8 nano-aggregates(Fe7S8@NC)were controllably prepared via a simple three-step synthesis strategy.The appropriate thickness of N-doped carbon layer outside Fe7S8 nano-aggregates can not only inhibit the particle pulverization induced by the big volume changes of Fe7S8,but can increase the electron transfer efficiency.The hierarchical Fe7S8 nano-aggregates composed of some primary nanoparticles can accelerate the lithium or sodium diffusion kinetics.As anode materials for Li-ion batteries(LIBs),the well-designed Fe7S8@NC nanocomposites exhibit outstanding lithium storage performance,which is better than that of pure Fe7S8,Fe3O4@NC and Fe7S8@C.Among these nanocomposites,the N-doped carbon coated Fe7S8 with carbon content of 26.87 wt.%shows a high reversible specific capacity of 833 mAh·g^−1 after 1,000 cycles at a high current density of 2 A·g^−1.The above electrode also shows excellent high rate sodium storage performance.The experimental and theoretical analyses indicate that the outstanding electrochemical performance could be attributed to the synergistic effect of hierarchical Fe7S8 nanostructure and conductive N-doped carbon layer.The quantitative kinetic analysis indicates that the charge storage of Fe7S8@NC electrode is a combination of diffusion-controlled battery behavior and surface-induced capacitance behavior. | Yanli Zhou Ming Zhang Qi Wang Jian Yang Xingyun Luo Yanlu Li Rong Du Xinsheng Yan Xueqin Sun Caifu Dong Xiaoyu Zhang Fuyi Jiang | 2020 | Nano Research2020，13，3： | 4 |
| 14 | Co-catalyst-free large ZnO single crystal for high-efficiency piezocatalytic hydrogen evolution from pure water显示文摘Piezocatalytic materials have been widely used for catalytic hydrogen evolution and purification of organic contaminants.However,most studies focus on nano-size and/or polycrystalline catalysts,suffering from aggregation and neutralization of internal piezoelectric field caused by polydomains.Here we report a single crystal ZnO of large size and few bulk defects crafted by a hydrothermal method for piezocatalytic hydrogen generation from pure water.It is noteworthy that single-side surface areas of both original as-prepared ZnO and Ga-doped ZnO bulk crystals are larger than 30 cm^(2).The high quality of ZnO and Ga-doped ZnO bulks are further uncovered by high-resolution transmission electron microscope(HRTEM),photoluminescence(PL)and X-ray diffraction(XRD).Remarkably,an outstanding hydrogen production rate of co-catalyst-free Ga-doped ZnO bulk crystal(i.e.,a maximum rate of 5915μmol h^(-1) m^(-2))is observed in pure water triggered by ultrasound in dark,which is over 100 times higher than that of its powder counterpart(i.e.,52.54μmol h^(-1) m^(-2)).The piezocatalytic performance of ZnO bulk crystal is systematically studied in terms of varied exposed crystal facet,thickness and conductivity.Different piezocatalytic performances are attributed to magnitude and distribution of piezoelectric potential,revealed by the finite element method(FEM)simulation.The density functional theory(DFT)calculations are employed to investigate the piezocatalytic hydrogen evolution process,indicating a strong H_(2)O adsorption and a low energy barrier for both H_(2)O dissociation and H2 generation on the stressed Znterminated(0001)ZnO surface. | Biao Wang Qian Zhang Jiaqing He Feng Huang Caifu Li Mengye Wang | 2022 | Journal of Energy Chemistry2022，31，2： | 4 |
| 15 | Carbon-coated Li_4Ti_5O_(12) Anode Materials Synthesized Using H_2TiO_3 as Ti Source显示文摘Two low-cost synthesis routes have been developed to fabricate carbon-coated Li4Ti5O12 by using H2 Ti O3instead of anatase Ti O2 as Ti source through solid-state reaction process. One route is a direct solid mixture of H2 Ti O3, Li2CO3 and pitch followed by high-temperature solid-state reaction. The other includes mixture of H2 Ti O3and Li2CO3 with pitch dissolved in furanidine under vacuum and the same solid-state reaction procedure is followed after the mixture is totally dried. Microstructural investigations indicate that H2 Ti O3exhibits secondary aggregates morphology with primary particle sizes of 10e20 nm. Carbon-coating layers with thickness of 2e3 nm have been observed on Li4Ti5O12 synthesized by the two routes. Cyclic performance, rate capability and electrochemical impedance spectrum of the two Li4Ti5O12/C composites have been performed, which indicate that Li4Ti5O12/C obtained by furanidine-assisted mixture exhibits better electrochemical performance than Li4Ti5O12/C synthesized by direct solid mixture. The possible reasons have been discussed. The low-cost synthesis routes of Li4Ti5O12/C using H2 Ti O3as Ti source are expected to be more competitive than the traditional one for practical applications. | Lijun Gong Yuxi Chen Hongjiang Yu Hongbo Liu Caifu Li Zhi-Quan Liu | 2014 | Journal of Materials Science & Technology2014，30，11： | 3 |
| 16 | Integrated materials design and informatics platform within the materials genome framework显示文摘The fundamental idea of materials genome initiative is the integration of computing platform,experimental platform,and data platform to speed up the material innovation hence reduce time and cost.This paper describes the basic concept of building an integrated computational platform and data platform for material innovation from the perspective of high-throughput simulation and materials knowledge management.The material data platform that can integrate material database,heterogeneous material data,various scripts,and open-source material simulation code together is particularly discussed.Taking metallic materials as an example,a brief introduction to metallic materials data management is given,and how to manage the semi-structure and unstructured iron and steel material data is also presented. | Zhuo Wang Xiaoyu Yang Yufei Zheng Qilong Yong Hang Su Caifu Yang | 2014 | Chinese Science Bulletin2014，59，15： | 3 |
| 17 | Hydrocarbon enrichment characteristics and difference analysis in the TZ1-TZ4 well block of the Tarim Basin显示文摘The reservoirs in the TZ1-TZ4 well block of the Tarim Basin are complex, and the hydrocarbon enrichment shows differences. The three Carboniferous oil layers are characterized by 'oil in the upper and lower layers and gas in the middle' in profile and 'oil in the west and gas in the east' in plane view. In order to discuss the complex reservoir accumulation mechanisms, based on the petroleum geology and reservoir distribution, we studied the generation history of source rocks, the fault evolution and sealing, the accumulation periods and gas washing, and reconstructed the accumulation process of the TZ1-TZ4 well block. It is concluded that the hydrocarbon enrichment differences of oil layers CIII, CII and CI were caused by multiple sources and multi-period hydrocarbon charging and adjustment. The CII was closely related to CIII, but CI was formed by reservoir adjustment during the Yanshan period and was not affected by gas washing after it was formed. During the Himalayan period, different degrees of gas washing in the east and west led to hydrocarbon enrichment differences on the plane. The Carboniferous accumulation process of two-stage charging and one-stage adjustment is summarized: oil charging during the late Hercynian period is the first accumulation period of CIII and CII; oil reservoirs were adjusted into CI in the Yanshan period; finally gas washing in the Himalayan period is the second accumulation period of CIII and CII, but CI was not affected by gas washing. This complex accumulation process leads to the hydrocarbon enrichment differences in the TZ1-TZ4 well block. | Jiang Zhenxue Pang Xiongqi Yang Haijun Li Zhuo Xiang Caifu Gu Qiaoyuan | 2010 | Petroleum Science2010，7，2： | 3 |
| 18 | Where are the Volcanic Calderas in the Xiangshan Volcanic Basin of Jiangxi? Implications from Anisotropy of Magnetic Susceptibility显示文摘Objective As the world's third largest volcanic type uranium ore field,the Xiangshan volcanic basin has attracted much attention for its large industrial value.The ore hosting rocks are mainly the early Cretaceous rhyodacite and porphyroclastic lava,as well as small amounts of high level intrusive acidic rocks and metamorphic rocks.The vertical alteration of polymetallic | GUO Fusheng LI Guangrong LIU Linqing WU Zhichun YANG Qingkun XIE Caifu | 2017 | Acta Geologica Sinica(English Edition)2017，91，1： | 2 |
| 19 | HREM Observation of Age-Precipitated Particles in Practical Cu-bearing Ultra-Low Carbon Steels显示文摘Morphology,distribution and crystal structures of age-precipitated particles in practical Cu-bearing steels with ultra-low carbon were studied by high resolution electron microscopy(HREM).The age-precipitation behavior was explored when poly-microalloying elements Cu,Nb,Cr,Mo and Ni were used and ε-Cu particles coexisted with carbides(carbonitrides) in steels.The fine dispersed ε-Cu particles and carbides of microalloying element Nb,Cr,Mo being about 10 nm only in size were observed in peak aging specimens and over-aging specimens.The twin structures and stacking faults in the particles and the transient structures formed in the early stage of the particle precipitation were also observed.The crystal structure of three types of age-precipitation particles was firstly identified by lattice streaks in HREM images of the single particles.The experimental method identifying crystal structure of fine and dispersed particles using HREM images of single particle was proposed. | Guiquan Yin Caifu Yang Yinong Lu | 2010 | Journal of Materials Science & Technology2010，26，5： | 2 |
| 20 | Ordovician Carbonate Reservoir Bed Characteristics and Reservoir-Forming Conditions in the Lungudong Region of the Tarim Basin显示文摘在 Tarim 盆的东北部分的 Lungudong 区域的奥陶纪碳酸盐水库床的基本特征详细被描述,油和气体的形成水库的条件被收集并且整理大量数据 preliminarily 在这份报纸讨论。碳酸盐水库床主要被开发在开站台并且站台边缘的外形;水库床有大变化在并且物理性质的低平均价值;主要类型第二是有破裂多孔的类型的折断的水库床。水库床发展被沉积外形,构造活动和 karstification 的分发主要控制。而在这个区域的烃的累积和分发被一个有益的结构的地点,好 reservoir-caprock 联合和一个有利搬运系统控制,与地区水平地描绘的分发和带垂直地,油和气体主要在区域被集中与结构高举,浓密地发达的破裂,并且表面石灰岩地区常见的地形,一个垂直 vadose 地区,和水平潜流 palaeokarst 系上带子。 | GU Qiaoyuan PANG Xiongqi LIU Luofu YANG Haijun WANG Ying JIANG Zhenxue XIANG Caifu HAN Jianfa | 2010 | Acta Geologica Sinica(English Edition)2010，84，5： | 2 |
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