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| 1 | Microstructure, biodegradation, antibacterial and mechanical properties of ZK60-Cu alloys prepared by selective laser melting technique显示文摘Magnesium(Mg) alloys are receiving increasing attention for body implants owing to their good biocompatibility and biodegradability. However, they often suffer from bacterial infections on account of their insufficient antibacterial ability. In this study, ZK60-x Cu(x = 0, 0.2, 0.4, 0.6 and 0.8 wt%) alloys were prepared by selective laser melting(SLM) with alloying copper(Cu) to enhance their antibacterial ability.Results showed that ZK60-Cu alloys exhibited strong antibacterial ability due to combination of release of Cu ions and alkaline environment which could kill bacteria by destroying cellular membrane structure,denaturing enzymes and inhibiting deoxyribonucleic acid(DNA) replication. In addition, their compressive strength increased due to grain refinement and uniformly dispersing of short-bar shaped MgZnCu phases. Moreover, ZK60-Cu alloys also exhibited good cytocompatibility. In summary, ZK60-Cu alloys with antibacterial ability may be promising implants for biomedical applications. | Cijun Shuai Long Liu Mingchun Zhao Pei Feng Youwen Yang Wang Guo Chengde Gao Fulai Yuan | 2018 | Journal of Materials Science & Technology2018,34,10: | 12 |
| 2 | ^(14)C measurement of forest soils in Dinghushan Biosphere Reserve显示文摘Organic carbon in forest soils of Qingyunsi and Wukesong profiles can be divided into fast and slow components. Δ14C values of these profiles decrease with increasing of depth. The Δ14C values in 30—40 cm depth interval of Wukesong profile are decreasing sharply until a very low value,showing that a strong geological environment change occurred about 1 560 years ago. The 14C apparent ages of Wukesong profile show that the coniferous and broad-leaf mixed forests around Wukesong profile have been developing since 425 a BP, which is consistent with historical documents. The penetrating depths of 'bomb 14C' in Qingyunsi and Wukesong profiles are 10 and 20 cm, respectively. | SHEN Chengde , LIU Dongsheng (LIU Tungsheng) , PENG Shaolin, SUN Yanmin , JIANG Mantao , Yl Weixi , XING Changping , GAO Quanzhou , LI Zhi’an and ZHOU Guoyi Guangzhou Institute of Geochemisry, Chinese Academy of Sciences, Guangzhou 510640, China Institute of Geology, Chinese Academy of Sciences , Beijing 100029, China South China Institute of Botany, Chinese Academy of Sciences, Guangzhou 510650, China | 1999 | Chinese Science Bulletin1999,44,3: | 7 |
| 3 | The elemental carbon record in Weinan loess section since the last 21 ka显示文摘We studied the records of elemental carbon (EC) of the last 21 ka in the Weinan loess section, Shanxi Province. The variations of EC abundance and δ13CEC value along with depth (or age) were presented. There are four large peaks of EC abundance around the following years: 20.16 ka, 17.76 ka, 11.97 ka and 4.49 ka. Climatic situation was changed rapidly during these periods. The peaks around 11.97 ka and 20.16 ka are particularly sharp, occurring over intervals of tens to hundreds of years, which could represent short-duration intense events. δ13CEc values in the upper 4 m of the Weinan loess section vary between -11.71‰ and -21.34‰, which suggests that the vegetation pattern of the last 21 ka on the Loess Plateau is G4-dominated grasses. | YANG Ying SHEN Chengde YI Weixi SUN Yanmin LIU Dongsheng | 2001 | Chinese Science Bulletin2001,46,18: | 5 |
| 4 | ^(10)Be/~7Be implies the contribution of stratosphere-troposphere transport to the winter-spring surface O_3 variation observed on the Tibetan Plateau显示文摘10Be/7Be is a stratospheric sensitive tracer.In this paper,measurements of 10Be/7Be and surface O3 from October 2005 to May 2006 at Mt.Waliguan (hereafter WLG,100.898°E,39.287°N,3810 m,a.s.l.),China global atmospheric watch (GAW) observatory,are introduced and used to investigate the stratosphere-troposphere transport (STT) and its impact on surface O3 on the Tibetan Plateau.The results show that the magnitude of STT is weak in winter,followed by strengthening from the end of winter to the middle of spring (from mid February to mid April) with large increases in 10Be,7Be,10Be/7Be and surface O3.At the end of spring (from the end of April to mid May in this paper),the STT weakened,and the continuous increase of surface O3 at WLG is produced by tropospheric photochemistry reactions. | ZHENG XiangDong SHEN ChengDe WAN GuoJiang LIU KeXin TANG Jie XU XiaoBin | 2011 | Chinese Science Bulletin2011,56,1: | 5 |
| 5 | Influence of graphene oxide(GO)on microstructure and biodegradation of ZK30-xGO composites prepared by selective laser melting显示文摘Different graphene oxide(GO)contents were chosen as the addition to prepare ZK30-xGO composites by selective laser melting(SLM).The microstructure and biodegradation of the SLMed ZK30-xGO composites were investigated.The results indicated that(i)SLM effectively produced a small grain size,(ii)the incorporation of GO into ZK30 caused a further decrease in grain size,and(iii)GO has a strong effect on the formation of the MgZn2 precipitates.The SLMed ZK30-0.6GO had the lowest biodegradation rate,which is attributed to the fact that the effect of the increased grain refinement and decreased amount of the MgZn?precipitates counteracted the effect of the increased GO content on the biodegradation rate.Furthermore,the SLMed ZK30-xGO composites had good cytocompatibility.This work provided a novel approach to the composition design and fabrication of novel biodegradable GO reinforced Mg-based biomedical implants. | Jun-Xi Tao Ming-Chun Zhao Ying-Chao Zhao Deng-Feng Yin Long Liu Chengde Gao Cijun Shuai Andrej Atrens | 2020 | Journal of Magnesium and Alloys2020,8,3: | 4 |
| 6 | Carbon isotopic composition and its implications on paleoclimate of the underground ancient forest ecosystem in Sihui,Guangdong显示文摘We present the carbon isotopic composition of the total organic carbon(TOC) and fine roots in the sedimentary profile from the underground ancient forest in Sihui to study the climatic and environmental changes from 4.5 ka BP to 0.6 ka BP.Results show that C3 plant was the main vegetation from 4.5 ka BP to 0.6 ka BP in this region.The ancient forest began to develop in the wetland at around 4 ka BP and disappeared together with the wetland at about 3.0 ka BP,implying that the climate had changed greatly at around 3.0 ka BP.As indicated by the simulation results,the content of atmospheric CO2 increased slightly during 3.5 ka BP and 3.0 ka BP,implying climate warming during that period.The interval of radiocarbon age between 3.0 ka BP and 1.2 ka BP was possibly caused by the strong erosion when the block was lifted in the neotectonic movement.From 1.2 ka BP to 0.6 ka BP,the region remained in terrestrial sedimentary environment,and the surface plant biomass declined gradually.Drought caused by the climate change was the likely cause for the disappearance of the ancient forest.South transition of Intertropical Convergence Zone(ITCZ) was probably the main mechanism for the climate change. | Ping Ding ChengDe Shen Ning Wang WeiXi Yi KeXin Liu XingFang Ding DongPo Fu | 2009 | Science China Earth Sciences2009,52,5: | 4 |
| 7 | Numerical studies of static aeroelastic effects on grid fin aerodynamic performances显示文摘The grid fin is an unconventional control surface used on missiles and rockets. Although aerodynamics of grid fin has been studied by many researchers, few considers the aeroelastic effects.In this paper, the static aeroelastic simulations are performed by the coupled viscous computational fluid dynamics with structural flexibility method in transonic and supersonic regimes. The developed coupling strategy including fluid–structure interpolation and volume mesh motion schemes is based on radial basis functions. Results are presented for a vertical and a horizontal grid fin mounted on a body. Horizontal fin results show that the deformed fin is swept backward and the axial force is increased. The deformations also induce the movement of center of pressure, causing the reduction and reversal in hinge moment for the transonic flow and the supersonic flow,respectively. For the vertical fin, the local effective incidences are increased due to the deformations so that the deformed normal force is greater than the original one. At high angles of attack, both the deformed and original normal forces experience a sudden reduction due to the interference of leeward separated vortices on the fin. Additionally, the increment in axial force is shown to correlate strongly with the increment in the square of normal force. | Chengde HUANG Wen LIU Guowei YANG | 2017 | Chinese Journal of Aeronautics2017,30,4: | 4 |
| 8 | Carbon isotopic composition,turnover and origins of soil CO_2 in a monsoon evergreen broadleaf forest in the Dinghushan Biosphere Reservoir,South China显示文摘Carbon isotopic compositions of soil CO2 in rainy season (July) from two natural soil profiles (DHLS & DHS) in the monsoon evergreen broadleaf forest in the Dinghushan Biosphere Reservoir (DBR),South China,are presented.Turnover and origins of soil CO2 are preliminarily discussed in this paper.Results show that the content of soil CO2 varies between 6120 and 18718 ppmv,and increases with increasing depth until 75 cm,and then it declines.In DHLS,soil CO2 δ 13C ranges from -24.71‰ to -24.03‰,showing a significant inverse correlation (R2=0.91) with the soil CO2 content in the same layer.According to a model related to soil CO2 δ 13C,the soil CO2 is mainly derived from the root respiration (>80%) in DHLS.While in DHS,where soil CO2 δ 13C ranges from -25.19‰ to -22.82‰,soil CO2 is primarily originated from the decomposition of organic matter (51%–94%),excluding the surface layer (20 cm,90%).Radiocarbon data suggest that the carbon in soil CO2 is modern carbon in both DHLS and DHS.Differences in 14C ages between the 'oldest' and 'youngest' soil CO2 in DHLS and DHS are 8 months and 14 months,respectively,indicating that soil CO2 in DHLS has a faster turnover rate than that in DHS.The Δ14C values of soil CO2,which range between 100.0‰ and 107.2‰ and between 102.5‰ and 112.1‰ in DHLS and DHS,respectively,are obviously higher than those of current atmospheric CO2 and SOC in the same layer,suggesting that soil CO2 is likely an important reservoir for Bomb-14C in the atmosphere. | DING Ping SHEN ChengDe WANG Ning YI WeiXi DING XingFang FU DongPo LIU KeXin ZHAO Ping | 2010 | Chinese Science Bulletin2010,55,23: | 4 |
| 9 | Dual alloying improves the corrosion resistance of biodegradable Mg alloys prepared by selective laser melting显示文摘Mg alloys have been regarded as revolutionary metallic biomaterials for biodegradable bone implants,but their applications are mainly blocked by the too rapid degradation in physiological environment.This study explores the dual alloying effects of Mn and/or Sn on the performance of Mg alloys prepared by selective laser melting.The observed microstructure indicated remarkable refinement of both the grains and intermetallic phases in the Mn-and/or Sn-containing alloys during the rapid solidification process.Moreover,approximately a half decrease in corrosion rate was observed for AZ61-0.4Mn-0.8Sn alloy with respect to AZ61 alloy.The improved corrosion behavior was primarily due to the enhanced protective effects of surface layers,in which Mn-and/or Sn-rich phases acted as a helpful barrier against medium penetration and thereby alleviated the current exchange with the matrix.In addition,the solute Mn and/or Sn positively shifted the corrosion potential,which also brought about a better corrosion resistance.Furthermore,the strength and hardness of the alloys were also effectively improved and comparable to those of cortical bone.This could be ascribed to the dissolved Mn and/or Sn atoms and the finely dispersed intermetallic phases,which might cause lattice distortion and precipitation hardening.Besides,the Mn-and/or Sn-containing alloys showed good cytocompatibility as indicated by the normal morphology and increased viability of MG-63 cells.These findings suggest that the developed AZ61-Mn-Sn alloy is a promising candidate for biodegradable bone implants. | Chengde Gao Sheng Li Long Liu Shizhen Bin Youwen Yang Shuping Peng Cijun Shuai | 2021 | Journal of Magnesium and Alloys2021,9,1: | 3 |
| 10 | Achieving higher performances without an external curing agent in natural magnolol-based epoxy resin显示文摘Bio-based epoxy thermoset prepared from renewable biomass raw materials can alleviate fossil energy crisis and reduce environmental pollution,which satisfies the needs of sustainable social development.In this study,a bio-based epoxy thermoset precursor(MGOL-EP) was synthesized from a naturally occurring magnolol through a facile and efficient one-step process.And the fully bio-based epoxy thermoset(MGOL-EP-SC) was obtained by self-curing without adding any other hardener.MGOL-EP-SC revealed an extremely high glass-transition temperature(T_(g)) of 265℃ and char yield of 53.2%(in N;),which were at the highest level among the fully bio-based epoxy thermosets reported so far.In addition,when the MGOL-EP was cured with 4,4’-methylenedianiline(DDM),T_(g)of the MGOL-EP/DDM was decreased by 61℃ and the other comprehensive performance had also been decreased,which was due to a reduction in biphenyl structure content and cross-linking density by adding the external curing agents.Moreover,the MGOL-EP-SC presented certain killing rate(48.4%) to Staphylococcus aureus.These findings provide a new design strategy for engineering high-performance and functional epoxy thermoset with high biomass content. | Qi Cao Zhihuan Weng Yu Qi Jiahui Li Wentao Liu Chengde Liu Shouhai Zhang Zhiyong Wei Yousi Chen Xigao Jian | 2022 | Chinese Chemical Letters2022,33,4: | 2 |
| 11 | Research on System Control and Energy Management Strategy of Flux-Modulated Compound-Structure Permanent Magnet Synchronous Machine显示文摘The flux-modulated compound-structure permanent magnet synchronous machine (CS-PMSM), composed of a brushless double rotor machine (DRM) and a conventional permanent magnet synchronous machine (PMSM), is a power split device for plug-in hybrid electric vehicles. In this paper, its operating principle and mathematical model are introduced. A modified current controller with decoupled state feedback is proposed and verified. The system control strategy is simulated in Matlab, and the feasibility of the control system is proven. To improve fuel economy, an energy management strategy based on fuzzy logic controller is proposed and evaluated by the Urban Dynamometer Driving Schedule (UDDS) drive cycle. The results show that the total energy consumption is similar to that of Prius 2012. | Jiaqi Liu Chengde Tong Zengfeng Jin Guangyuan Qiao Ping Zheng | 2017 | CES Transactions on Electrical Machines and Systems2017,1,2: | 2 |
| 12 | Apparent ages of suspended sediment and soil erosion of the Pearl River (Zhujiang) drainage basin显示文摘The carbon isotopic composition (Δ 14 C,δ 13 C) and apparent ages of suspended sediment were determined in the Pearl River in the years 1998,2000 and 2005.These results indicate that suspended POC consists mostly of young carbon and some 'old carbon'.Apparent ages of suspended POC range from 540 to 2050 a BP.The apparent ages are older in the Xijiang and Beijiang Rivers,while these values are variable in the Dongjiang River,including old and young samples.The suspended POCδ 13 C values increase with increasing Δ 14 C in the Pearl River,indicating that its source is soil and bedrock from depths under 15 30 cm.Since the organic carbon of the surface soil is quickly decomposed when it enters the rivers,its carbon isotopic characteristics are insignificant in suspended sediment.In the Pearl River drainage basin,there are areas with more severe soil erosion than others.For example,erosion is much more severe in the Xijiang River drainage basin when compared to the light soil erosion in the Dongjiang River drainage basin. | WEI XiuGuo SHEN ChengDe LI NingLi WANG FuShun DING Ping WANG Ning GUO ZhiXing LIU KeXin | 2010 | Chinese Science Bulletin2010,55,15: | 2 |
| 13 | ~4C as a tool for evaluating riverine POC sources and erosion of the Zhujiang (Pearl River) drainage basin, South China 显示文摘 | Wei Xiuguo Yi Weixi Shen Chengde Yechieli Y Li Ningli Ding Ping Wang Ning Liu Kexin | 2010 | Nucl Instrum Methods Phys Res Sect B2010,268,7: | 1 |
| 14 | SYNTHESIS OF SOAP-FREE ACRYLIC HYDROSOLS显示文摘Poly(methyl methacrylate/ethyl acrylate/acrylic acid) hydrosols were prepared by employing soap-freepolymerization, and (acrylic acid/butyl acrylate) oligomer was used as the polymeric surfactant. The effect of reactioncondition on the morphology and particle size of the hydrosols was investigated. The minimum amount of acrylic acid in thehydrosols is 2%. The maximum weight average molecular weight (Mw) of polymer that assures soap-free emulsionconversion into hydrosol is about 1.2 × 105-1.3 × 105. The particle transforming process was investigated, and an obviouschange of particle diameter and morphology was observed. | Li Jia Zong-hui Liu De-qing Wei Chengd Institute of Organic Chemistry Chinese Academy of Sciences, Chengdu 610041, China | 2002 | Chinese Journal of Polymer Science2002,20,6: | 1 |
| 15 | En-hancement mechanisms of graphene in nano-58S bioactive glass scaffold: mechanical and biological performance 显示文摘 | GAO Chengde LIU Tingting SHUAI Cijun | 2014 | Sci Rep2014,4,: | 1 |
| 16 | Fluorescent carbon nanoparticles derived from candle soot 显示文摘 | LIU Haipeng YE Tao MAO Chengde | 2007 | Angew Chem Int Ed2007,46,34: | 1 |
| 17 | A Study of Eco-service Valuation of Saihanba Forest显示文摘The study made a monetized valuation of eco-service provided by forests at Saihanba Mechanic Forest Farm in terms of water conservancy, soil conversation, carbon sequestration, micro-climate adjustment, air quality improvement, protection for agriculture, biodiversity maintenance, and landscape & recreation. The results revealed that the total value of various eco-services is 3.061 billion yuan/a, while the eco-services of unit area forest values at 42 300 yuan/(ha·a). | LIU Chunyan1 WANG Dengju2 LIU Haiying1 Cheng Shun1 1. Sanhanba Mechanic Forest Farm, Hebei Province, Chengde 068450, P. R. China 2. Research Institute of Forestry Policy and Information, Chinese Academy of Forestry, Beijing 100091, P. R. China | 2010 | Chinese Forestry Science and Technology2010,9,4: | 1 |
| 18 | Increasing the Solubility of a Hydrophobic Molecule with Thymine-like Face by DNA via Supramolecular Interaction显示文摘Poor water-solubility of hydrophobic drugs greatly hampers drug design and creats delivery problems.The traditional way to improve the solubility is to add hydrotropes or excipients to supress aggregations.Here,a novel mechanisim has been proposed based on supramolecular interactions and demonstrated with a small molecule,pvromellitic diimide(PD).This compound contains thymine-like ‘face’ and can interact with adenines through Wat-son-Crick and Hoogsteen hydrogen-bonding.Given the high water solubility of poly adenines[poly(A)],it is expectec that poly(A)will greatly increase the PD solubility.Indeed,such an increased solubility was confirmed by ultraviolet-visible spectroscopy(UV-Vis)and polyacrylamide gel electrophoresis(PAGE)analysis.We believe that this strategy could be used to improve the solubility of other similar hydrophobic molecules. | SHI Peijun ZHANG Zhe LIU Mingchun SUN Teng HE Xiaoyan MAO Chengde FANG Liang ZUO Hua | 2020 | Chemical Research in Chinese Universities2020,36,2: | 0 |
| 19 | Processable Potassium Metal Anode for Stable Batteries显示文摘The future of high-energy density electrochemical energy storage systems relies on the advancement of rechargeable batteries that utilize reactive metals as anodes.In the alkaline metal,secondary battery systems because of abundant resource,high capacity and low redox potential,potassium(K)metal secondary battery(KMB)is expected to replace the existing lithiumion battery as a versatile platform for high-energy density,cost-effective energy storage devices.However,the difficulty in processing metal K results in nonstandard electrodes and hinders the development of KMBs.Furthermore,the mobility of the K metal anode due to its unique lowmelting point character at elevated temperatures in practical conditions leads to severe instability and risks in chemical/electrochemical processes.Herein,we fabricate a processable and moldable composite K metal anode by encapsulating K into reduced graphene oxide(rGO).The composite electrode can be engineered into various shapes discretionarily with precise sizes and stabilize the K metal anode at relatively high temperatures.Remarkably,the composite anode exhibits excellent cycling performance at high current density(8 mA cm^(-2)) with dendrite-free morphology.Paired with a Prussian blue cathode,the rGO-K composite anode shows much improved electrochemical performance and extended lifetime. | Zhenghang Wei Aoxuan Wang Xuze Guan Guojie Li Zhiwei Yang Chengde Huang Jing Zhang Libin Ren Jiayan Luo Xingjiang Liu | 2022 | Energy & Environmental Materials2022,5,4: | 0 |
| 20 | An in-situ spectroscopy investigation of alkali metal interaction mechanism with the imide functional group显示文摘Organic anode materials have attracted considerable interest owing to their high tunability by adopting various active functional groups.However,the interaction mechanisms between the alkali metals and the active functional groups in host materials have been rarely studied systematically.Here,a widely used organic semiconductor of perylene-3,4,9,10-tetracarboxylic diimide(PTCDI)was selected as a model system to investigate how alkali metals interact with imide functional groups and induce changes in chemical and electronic structures of PTCDI.The interaction at the alkali/PTCDI interface was probed by in-situ X-ray photoelectron spectroscopy(XPS),ultraviolet photoelectron spectroscopy(UPS),synchrotron-based near edge X-ray absorption fine structure(NEXAFS),and corroborated by density functional theory(DFT)calculations.Our results indicate that the alkali metal replaces the hydrogen atoms in the imide group and interact with the imide nitrogen of PTCDI.Electron transfer induced gap states and downward band-bending like effects are identified on the alkali-deposited PTCDI surface.It was found that Na shows a stronger electron transfer effect than Li.Such a model study of alkali insertion/intercalation in PTCDI gives insights for the exploration of the potential host materials for alkali storage applications. | Xu Lian Zhirui Ma Zhonghan Zhang Jinlin Yang Shuo Sun Chengding Gu Yuan Liu Honghe Ding Jun Hu Xu Cao Junfa Zhu Shuzhou Li Wei Chen | 2020 | Nano Research2020,13,12: | 0 |