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| 1 | Efficient conversion of benzene and syngas to toluene and xylene over ZnO-ZrO_(2)&H-ZSM-5 bifunctional catalysts显示文摘A series of ZnO-ZrO_(2) solid solutions with different Zn contents were synthesized by the urea coprecipitation method,which were coupled with H-ZSM-5 zeolite to form bifunctional catalysts.As a new benzene alkylation reagent,syngas was used instead of methanol to realize the efficient conversion of syngas and benzene into toluene and xylene.A suitable ratio of ZnO-ZrO_(2) led to the significant improvement in the catalytic performance,and a suitable amount of acid helped to increase the selectivity of toluene/xylene and reduce the selectivity of the by-products ethylbenzene and C^(9+) aromatics.The highest benzene conversion of 89.2%and toluene/xylene selectivity of 88.7%were achieved over 10%ZnO-ZrO_(2)&H-ZSM-5(Si/Al=23)at a pressure of 3 MPa and a temperature of 450℃.In addition,the effect of the zeolite framework structure on product distribution was examined.Similar to the molecular dynamics of aromatic hydrocarbons,H-ZSM-5 zeolites comprise 10-membered-ring pores,which are beneficial to the activation of benzene;hence,the conversion of benzene is higher.H-ZSM-35 and HMOR zeolites exhibited small eight-membered-ring channels,which were not conducive to the passage of benzene;hence,the by-product ethylbenzene exhibits a higher selectivity.The distance between the active centers of the bifunctional catalysts was the main factor affecting the catalytic performance,and the powder mixing method was more conducive to the conversion of syngas and benzene. | Xiao Zhao Xuan Shi Zhongshun Chen Long Xu Chengyi Dai Yazhou Zhang Xinwen Guo Dongyuan Yang Xiaoxun Ma | 2022 | Chinese Journal of Chemical Engineering2022，35，5： | 2 |
| 2 | Controlled direct synthesis of single- to multiple-layer MWW zeolite显示文摘The minimized diffusion limitation and completely exposed strong acid sites of the ultrathin zeolites make it an industrially important catalyst especially for converting bulky molecules.However,the structure-controlled and large-scale synthesis of the material is still a challenge.In this work,the direct synthesis of the single-layer MWW zeolite was demonstrated by using hexamethyleneimine and amphiphilic organosilane as structure-directing agents.Characterization results confirmed the formation of the single-layer MWW zeolite with high crystallinity and excellent thermal/hydrothermal stability.The formation mechanism was rigorously revealed as the balanced rates between the nucleation/growth of the MWW nanocrystals and the incorporation of the organosilane into the MWW unit cell,which is further supported by the formation of MWW nanosheets with tunable thickness via simply changing synthesis conditions.The commercially available reagents,well-controlled structure and the high catalytic stability for the alkylation of benzene with 1-dodecene make it an industrially important catalyst. | Jie-Qiong Chen Yu-Zhao Li Qing-Qing Hao Huiyong Chen Zhao-Tie Liu Chengyi Dai Jianbo Zhang Xiaoxun Ma Zhong-Wen Liu | 2021 | National Science Review2021，8，7： | 1 |
| 3 | Modification of small-crystal titanium silicalite-1 with organic bases: Recrystallization and catalytic properties in the hydroxylation of phenol 显示文摘 | Zuo Yi Song Wancang Dai Chengyi | 2013 | Applied Catalysis A: General2013，453，27： | 1 |
| 4 | Fluoride-mediated nano-sized high-silica ZSM-5 as an ultrastable catalyst for methanol conversion to propylene显示文摘Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivity(45%) was similar to ZSM-5-OH synthesized via a hydroxide route. However, ZSM-5-F showed much longer lifetime(305 h) compared with ZSM-5-OH(157 h) in spite of similar crystal size and aluminum content. Characterization by NH_3-TPD, Py-IR, OH-IR, SEM, TG-DTA, XRD and ~1H MAS NMR techniques indicated that the enhanced catalytic performance of ZSM-5-F is attributed to the fewer structural defects in the form of internal silanol groups and silanol nests. | Junjie Li Min Liu Xinwen Guo Chengyi Dai Chunshan Song | 2018 | Journal of Energy Chemistry2018，27，4： | 1 |
| 5 | Green synthesis of Au@WSe_(2) hybrid nanostructures with the enhanced peroxidase-like activity for sensitive colorimetric detection of glucose显示文摘We report a colorimetric method for glucose detection based on Au nanoparticle-decorated WSe_(2)(Au@WSe_(2))hybrid nanostructures.These hybrid structures are easily synthesized by simply stirring HAuCl_(4) precursor with WSe_(2) nanosheets in aqueous solution.Owing to strong synergistic catalytic effects of Au nanoparticles and WSe_(2) nanosheets,the Au@WSe_(2) hybrid nanostructures exhibit enhanced peroxidase-like activity(about 2-fold higher compared to WSe_(2) nanosheets alone)for 3,3',5,5'-tetramethylbenzidine oxidation by H_(2)O_(2).Based on the highly catalytical property,the colorimetric method for glucose detection is established by coupling glucose oxidase(GOx).The detection limit of glucose is 3.66 pM.Moreover,the proposed colorimetric method is applicable to glucose detection in serum samples and is promising for applications in biomedical fields. | Chengyi Hong Lingling Chen Chenyue Wu Dan Yang Jia-Yong Dai Zhiyong Huang Ren Cai Weihong Tan | 2022 | Nano Research2022，15，2： | 0 |
| 6 | On the long-term joint distribution of characteristic wave height and period and its application显示文摘By analysing the scatter diagrams of characteristic the wave height H and the period T on the basis of instrumental data from various ocean wave stations, we found that the conditional expectation and standard deviation of wave period for a given wave height can be better predicted by using the equations of normal linear regression rather than by those based on the log- normal law. The latter was implied in Ochi’ s bivariate log-normal model(Ochi. 1978) for the long-term joint distribution of H and T. With the expectation and standard deviation predicted by the normal linear regression equations and applying proper types of distribution, we have obtained the conditional distribution of T for given H. Then combining this conditional P(T / H) with long-term marginal distribution of the wave height P(H) we establish a new parameterized model for the long-term joint distribution P(H,T). As an example of the application of the new model we give a method for estimating wave period associated with an extreme | Fang Zhongsheng, Dai Shunsun and Jin Chengyi China Ship Scientific Research Center, Wuxi, China | 1989 | Acta Oceanologica Sinica1989，8，3： | 0 |
| 7 | Ultralow Interfacial Thermal Resistance of Graphene Thermal Interface Materials with Surface Metal Liquefaction显示文摘Developing advanced thermal interface materials(TIMs)to bridge heat-generating chip and heat sink for constructing an efficient heat transfer interface is the key technology to solve the thermal management issue of high-power semiconductor devices.Based on the ultra-high basal-plane thermal conductivity,graphene is an ideal candidate for preparing high-performance TIMs,preferably to form a vertically aligned structure so that the basal-plane of graphene is consistent with the heat transfer direction of TIM.However,the actual interfacial heat transfer efficiency of currently reported vertically aligned graphene TIMs is far from satisfactory.In addition to the fact that the thermal conductivity of the vertically aligned TIMs can be further improved,another critical factor is the limited actual contact area leading to relatively high contact thermal resistance(20-30 K mm^(2) W^(−1))of the“solid-solid”mating interface formed by the vertical graphene and the rough chip/heat sink.To solve this common problem faced by vertically aligned graphene,in this work,we combined mechanical orientation and surface modification strategy to construct a three-tiered TIM composed of mainly vertically aligned graphene in the middle and micrometer-thick liquid metal as a cap layer on upper and lower surfaces.Based on rational graphene orientation regulation in the middle tier,the resultant graphene-based TIM exhibited an ultra-high thermal conductivity of 176 W m^(−1) K^(−1).Additionally,we demonstrated that the liquid metal cap layer in contact with the chip/heat sink forms a“liquid-solid”mating interface,significantly increasing the effective heat transfer area and giving a low contact thermal con-ductivity of 4-6 K mm^(2) W^(−1) under packaging conditions.This finding provides valuable guidance for the design of high-performance TIMs based on two-dimensional materials and improves the possibility of their practical application in electronic thermal management. | Wen Dai Xing-Jie Ren Qingwei Yan Shengding Wang Mingyang Yang Le Lv Junfeng Ying Lu Chen Peidi Tao Liwen Sun Chen Xue Jinhong Yu Chengyi Song Kazuhito Nishimura Nan Jiang Cheng-Te Lin | 2023 | Nano-Micro Letters2023，15，1： | 0 |
| 8 | Dynamic reconstruction of Ni-Zn alloy solid-electrolyte interface for highly stable Zn anode显示文摘Aqueous zinc ion batteries(AZIBs)are ideal candidates for large-scale battery storage,with a high theoretical specific capacity,ecological friendliness,and extremely low cost but are strongly hindered by zinc dendrite growth.Herein,Ni-Zn alloy is artificially constructed as a solid-electrolyte interface(SEI)for Zn anodes by electrodeposition and annealing.The Ni-Zn alloy layer acts as a dynamic shield at the electrode/electrolyte interface.Interestingly,the zinc atoms migrate out of the electrode body during zinc stripping while merging into the electrode body during the plating.In this way,the Ni-Zn alloy is able to guide the zinc deposition in the horizontal direction,thereby suppressing the formation of dendrite.Benefiting from those,the Ni-Zn alloy symmetric cell shows a greatly improved cycle life and is able to operate stably for 1,900 h at a current density of 0.5 mA·cm^(−2).The present study is a strategy for negative electrode protection of AZIBs. | Qian Zhang Yuhang Dai Kangning Zhao Chengyi Zhang Ruihu Lu Jinghao Li Shuhan Jin Lei Zhang Qinyou An Liqiang Mai | 2023 | Nano Research2023，16，9： | 0 |
| 9 | Confined space synthesis of Ni(OH)_(2)-impregnated three-dimensional ordered mesoporous carbon as a high-performance supercapacitor electrode显示文摘Regulable loading of Ni(OH)_(2) crystals by using three dimensionally ordered mesoporous carbon(3DOMC)as a support is achieved through a confined growth strategy accompanied by steam-assisted crystallization.Dual forms of high-crystalline nanosheet-like Ni(OH)_(2) severally distribute within mesopores or over the outer surface of 3DOMC particles depending on the loading amount(3%^(−1)5%)of Ni(OH)_(2).Benefitted from the highly hybrid combination and efficient electrolyte diffusion,the obtained Ni(OH)_(2)/carbon nanocomposites exhibit an excellent electrochemical performance,and the optimal sample of 6%_Ni(OH)_(2)/3DOMC with confined extrasmall Ni(OH)_(2) nanosheets as dominant shows the highest specific capacitance of 552.5F.g^(−1) at 1.0A⋅g^(−1),which is 330%higher than the contrast sample by using actived carbon as the support.Furthermore,the assembled hybrid supercapacitor by using 6%_Ni(OH)_(2)/3DOMC and 3DOMC as positive and negative electrodes displays an energy density of 11.7 Wh.kg^(−1) at 288.1 W.kg^(−1) and a superior charge/discharge stability.It is expected that the flexible component,well-defined structure,and superior electrochemical performance could promote a great application potential of Ni(OH)_(2)/3DOMC nanocomposites as supercapacitor electrodes and in other energy storage devices. | Huiyong Chen Xin Yang Wencheng Yang Siyu Zhang Xingrui Wang Baoyu Liu Chengyi Dai Jianbo Zhang Xiaoxun Ma | 2022 | Carbon Resources Conversion2022，5，2： | 0 |
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