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| 1 | Engineering Cu^(+)/CeZrO_(x) interfaces to promote CO_(2) hydrogenation to methanol显示文摘Cu-based catalysts are widely employed for CO_(2) hydrogenation to methanol,which is expected as a promising process to achieving carbon neutrality.However,most Cu-based catalysts still suffer from low methanol yield with a passable CO_(2) conversion and lack insight into its reaction mechanism for guiding the design of catalysts.In this work,Cu^(+)/CeZrO_(x) interfaces are engineered by employing a series of ceria-zirconia solid solution catalysts with various Ce/Zr ratios,forming a Cu^(+)-O_(v)-Ce^(3+)structure where Cu^(+)atoms are bonded to the oxygen vacancies(O_(v))of ceria.Compared to Cu/CeO_(2) and Cu/ZrO_(2),the optimized catalyst(i.e.,Cu_(0.3)Ce_(0.3)Zr_(0.7))exhibits a much higher mass-specific methanol formation rate(192g_(MeOH)/kg_(cat)/h)at 240℃and 3 MPa.Through a series of in-situ and ex-situ characterization,it is revealed that oxygen vacancies in solid solutions can effectively assist the activation of CO_(2) and tune the electronic state of copper to promote the formation of Cu^(+)/CeZrO_(x) interfaces,which stabilizes the key*CO intermediate,inhibits its desorption and facilitates its further hydrogenation to methanol via the reverse watergas-shift(RWGS)+CO-Hydro pathway.Therefore,the concentration of*CO or the apparent Cu^(+)/(Cu^(+)+Cu^(0))ratio could be employed as a quantitative descriptor of the methanol formation rate.This work is expected to give a deep insight into the mechanism of metal/support interfaces in CO_(2) hydrogenation to methanol,offering an effective strategy to develop new catalysts with high performance. | Jingpeng Zhang Xiaohang Sun Congyi Wu Wenquan Hang Xu Hu Dawei Qiao Binhang Yan | 2023 | Journal of Energy Chemistry2023，，2： | 3 |
| 2 | Cryopreservation of Pollen by Vitrification in Brassica显示文摘CryopreservationofPolenbyVitrificationinBrasicaXuBingfang,HanHongmei,ZhengCongyi,SunMengxiangColegeofLifeSciences,WuhanUnive... | Xu Bingfang Han Hongmei Zheng Congyi Sun Mengxiang | 1997 | Wuhan University Journal of Natural Sciences1997，2，1： | 2 |
| 3 | Construction of the Vero cell culture system that can produce infectious HCV particles显示文摘 | Jia Guo Ran Yan Guodong Xu Weiyun Li Congyi Zheng | 2009 | Molecular Biology Reports2009，，1： | 1 |
| 4 | Structure-function analysis of mutant RNA-dependent RNA polymerase complexes with VPg显示文摘 | Chaojiang Gu Tao Zeng Yong Li Zhenghui Xu Zhongxi Mo Congyi Zheng | 2009 | Biochemistry (Moscow)2009，，10： | 1 |
| 5 | Influence of degree of deacetylation on critical concentration of chitosan/dichloroacetic acid liquid-crystalline solution显示文摘 | Yanming Dong Congyi Xu Jianwei Wang | 2002 | Journal of Applied Polymer Science2002，83，6： | 1 |
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