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| 1 | Al_2O_3基Ni-Cu双金属催化剂上乙酰丙酸氢解(英)显示文摘Inexpensive γ-alumina-based nickel-copper bimetallic catalysts were studied for the hydrogenolysis of levulinic acid,a key platform molecule for biomass conversion to biofuels and other valued chemicals,into γ-valerolactone as a first step towards the production of 2-methyltetrahydrofurane.The activities of both monometallic and bimetallic catalysts were tested.Their textural and chemical characteristics were determined by nitrogen physisorption,elemental analysis,temperature-programmed ammonia desorption,and temperature-programmed reduction.The monometallic nickel catalyst showed high activity but the highest bγ-product production and significant amounts of carbon deposited on the catalyst surface.The copper monometallic catalyst showed the lowest activity but the lowest carbon deposition.The incorporation of the two metals generated a bimetallic catalyst that displayed a similar activity to that of the Ni monometallic catalyst and significantly low bγ-product and carbon contents,indicating the occurrence of important synergetic effects.The influence of the preparation method was also examined by studying impregnated- and sol-gel-derived bimetallic catalysts.A strong dependency on the preparation procedure and calcination temperature was observed.The highest activity per metal atom was achieved using the sol-gel-derived catalyst that was calcined at 450 ℃.High reaction rates were achieved;the total levulinic acid conversion was obtained in less than 2 h of reaction time,yielding up to 96%γ-valerolactone,at operating temperature and pressure of 250 ℃ and 6.5 MPa hydrogen,respectively. | Iker Obregón Eriz Corro Urko Izquierdo Jesus Requies Pedro L.Arias | 2014 | 催化学报2014，35，5： | 8 |
| 2 | An XPS evidence of PP+ present on sulfated Pt/Al2O3 and its effect on propane combustion显示文摘 | Corro G Fierro J L G Odilon V C | | 0，，08： | 1 |
| 3 | SO2 Reactions over /-A1203, Pt/'/-A12 O3, Stl/--AI2 03 and Pt-Sn/'v-A12 03 显示文摘 | Corro G Velasco A Montiel R | 2001 | Catalysis Communications2001，，2： | 1 |
| 4 | Catalytic performance of Pt-Sn/-A1203 for diesel soot oxidation 显示文摘 | Corro G Fierro J L G Romero F B | 2006 | Catalysis Communications2006，，7： | 1 |
| 5 | Generation of biogas from coffee-pulp and cow-dung co-digestion:Infrared studies of postcombustion emissions显示文摘 | Grisel Corro Laura Paniagua Umapada Pal | 2013 | Energy Conversion and Management2013，74，： | 1 |
| 6 | Successful of catheter-related right atrial thrombosis with recombinant tissue plasminogen activator and heparin显示文摘 | Cesaro S Paris M Corro R | 2002 | Support Care Cancer2002，10，3： | 1 |
| 7 | Sulfur impact on diesel emission control - A review显示文摘 | Griselda Corro | 2002 | Reaction Kinetics and Catalysis Letters2002，75，1： | 1 |
| 8 | Dynamics of two-component BoseEinstein condensates in rotating traps显示文摘 | Corro I | | 0，，： | 1 |
| 9 | Vessel shrinkage as a sign of atherosclerosis progression in type 2 diabetes: a serial intravascular ultrasound analysis 显示文摘 | Jim6nez-Quevedo P Suzuki N Corros C | 2009 | Diabetes2009，58，1： | 1 |
| 10 | Radiofrenquency-assited liver resection in patients with Hepatocellular carcinoma and cirrhosis:preliminary results显示文摘 | Corro G Habiib N Jiao L | | 0，，10： | 1 |
| 11 | Quercetin improves hepatic fibrosis reducing hepatic stellate cells and regulating pro‐fibrogenic/anti‐fibrogenic molecules balance显示文摘 | Luis Daniel Hernández‐Ortega Blanca Estela Alcántar‐Díaz Luis Alberto Ruiz‐Corro Ana Sandoval‐Rodriguez Miriam Bueno‐Topete Juan Armendariz‐Borunda Adriana María Salazar‐Montes | 2012 | J Gastroenterol Hepatol2012，，12： | 1 |
| 12 | Vessel shrinkage as a sign of atheroselerosis progression in type 2 diabe-tes:a serial intravascular ultrasound analysis 显示文摘 | JIMI:NEZ QUEVEDO P SUZUKI N CORROS C | 2009 | Diabetes2009，58，1： | 1 |
| 13 | Measurements of surface acidity of solid catalysts for free fatty acids esterification in Jatropha curcas crude oil for biodiesel production显示文摘 | Corro G BafiuJLOs F Vidal E Cebada S | 2014 | Fuel2014，625，： | 1 |
| 14 | Modes of innovation in knowledge inten- sive business services evidence from Lombardy显示文摘 | NICOLETTA CORRO{CHER LUCIA CUSMANO ANDREA MORRISON | 2009 | J Evol Econ2009，，19： | 1 |
| 15 | Antipsychotie-induced weight gain in chronic and first-episode psychotic disorders: A systematic critical reap- praisal显示文摘 | ALVAREZ-JIMENEZ M GONZALEZ-BLANCH C CRESPOFA- CORRO B | 2008 | CNS Drugs2008，22，7： | 1 |
| 16 | Assessment of dynamic coronary plaque changes and the clinical consequences in type-lI diabetic patients: a serial intracoronary ultrasound study 显示文摘 | Jim6nez-Quevedo P Suzuki N Corros C | 2011 | RevEsp Cardiol2011，64，7： | 1 |
| 17 | VesseI shrinkage as a sign of atherosclerosis progression in type 2 diabetes : a serial intra- vascular ultrasound analysis显示文摘 | Jim6nez-Quevedo P Suzuki N Corros C | 2009 | Diabetes2009，58，1： | 1 |
| 18 | Measurements of surfaceacidity of solid catalysts for free fatty acids esterificationin Jatropha curcas crude oil for biodiesel production显示文摘 | Corro G Ba-uelos F Vidal E | 2014 | Fuel2014，115，： | 1 |
| 19 | Single Layer Mol-ybdenum Disulfideunder Direct Out-of-Plane Compression: Low-Stress Band-Gap Engi-neering 显示文摘 | Miriam Pea-/lvarez Elena del Corro /ngel Morales- Garcfa | 2015 | Nano Lett2015，15，5： | 1 |
| 20 | Rapid reversal of left ven- tricular hypertrophy and intracardiac volume overload in patients with resistant hypertension and hyperaldosteronism: a prospective clinical study 显示文摘 | Gaddam K Corros C Pimenta E | 2010 | Hypertension2010，55，5： | 1 |
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