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| 1 | A perspective on carbon materials for future energy application显示文摘Nanocarbon materials play a critical role in the development of new or improved technologies and devices for sustainable production and use of renewable energy. This perspective paper defines some of the trends and outlooks in this exciting area, with the effort of evidencing some of the possibilities offered from the growing level of knowledge, as testified from the exponentially rising number of publications, and putting bases for a more rational design of these nanomaterials. The basic members of the new carbon family are fullerene, graphene, and carbon nanotube. Derived from them are carbon quantum dots, nanohorn, nanofiber, nano ribbon, nanocapsulate, nanocage and other nanomorphologies. Second generation nanocarbons are those which have been modified by surface functionalization or doping with heteroatoms to create specific tailored properties. The third generation of nanocarbons is the nanoarchitectured supramolecular hybrids or composites of the first and second generation nanocarbons, or with organic or inorganic species. The advantages of the new carbon materials, relating to the field of sustainable energy, are discussed, evidencing the unique properties that they offer for developing next generation solar devices and energy storage solutions. | Dang Sheng Su Gabriele Centi | 2013 | Journal of Energy Chemistry2013,22,2: | 16 |
| 2 | Porous V_2O_5-SnO_2 /CNTs composites as high performance cathode materials for lithium-ion batteries显示文摘Vanadium pentoxide (V2O5 ) exhibits high theoretical capacities when used as a cathode in lithium ion batteries (LIBs), but its application is limited by its structural instability as well as its low lithium and electronic conductivities. A porous composite of V2O5 -SnO2 /carbon nanotubes (CNTs) was prepared by a hydrothermal method and followed by thermal treatment. The small particles of V2O5 , their porous structure and the coexistence of SnO2 and CNTs can all facilitate the diffusion rates of the electrons and lithium ions. Electrochemical impedance spectra indicated higher ionic and electric conductivities, as compared to commercial V2O5 . The V2O5 -SnO2 /CNTs composite gave a reversible discharge capacity of 198 mAh g-1 at the voltage range of 2.05 4.0 V, measured at a current rate of 200 mA g-1 , while that of the commercial V2O5 was only 88 mAh g-1 , demonstrating that the porous V2O5 -SnO2 /CNTs composite is a promising candidate for high-performance lithium secondary batteries. | Qi Guo Zhenhua Sun Man Gao Zhi Tan Bingsen Zhang Dang Sheng Su | 2013 | Journal of Energy Chemistry2013,22,2: | 3 |
| 3 | Carboxyl groups trigger the activity of carbon nanotube catalysts for the oxygen reduction reaction and agar conversion显示文摘臭氧处理是到有象 carboxyl,酚和内酯一样的各种各样的氧功能的商业多围的碳 nanotubes (CNT ) 组织的 functionalize 的一条普通的路,以便提高他们的组织上性质和化学活动。以便详细说明每个功能的组的效果,我们相关有每个组的表面密度的活动,并且发现 carboxyl 组在二重要催化反应起一个枢轴的作用,也就是电气化学的氧减小反应( ORR )和到 5-hydroxymethylfurfural ( HMF )的琼脂变换。在这些过程期间,当改进的孔允许反应物和产品的有效散开时,吸水的表面为反应底层提供一种强壮的亲密关系。而且,为琼脂变换的 functionalized CNT 的活动在反应的九个周期期间仍然保持几乎未改变。这个工作为为电气化学的 ORR 和琼脂变换反应改进 CNT 的活动加亮策略,也是的 carboxyl 富有的 CNT 的有希望的应用生产高纯净的 HMFan 的稳固的酸催化剂重要化学中介。 | Yexin Zhang Chunlin Chen Lixia Peng Zhongsen Ma Yajie Zhang Hengheng Xia Aili Yang Lei Wang Dang Sheng Su Jian Zhang | 2015 | Nano Research2015,8,2: | 2 |
| 4 | Palladium and carbon synergistically catalyzed room-temperature hydrodeoxygenation(HDO) of vanillyl alcohol–A typical lignin model molecule显示文摘Vanillyl alcohol,which is made up of an aromatic ring,an alcoholic hydroxyl group,a phenolic hydroxyl group and a methoxy group,was selected as the model molecule of lignin.Various carbon materials supported Pd catalysts were chosen to catalyze the HDO of vanillyl alcohol.The catalysts were characterized via TEM,TPD,XRD,XPS and CO-chemisorption.It was found that different carbon materials could obviously influence the particle sizes,dispersion and distribution of Pd or Pd O particles.Palladium and carbon can synergistically catalyze the room-temperature HDO of vanillyl alcohol even at room temperature,and the carboxyl group was found to be the effective active acid site during the reaction.Possible reaction mechanism was also proposed.The existence of the effective active acid sites on the carbon supports could obviously lower the reaction temperature without decreasing the selectivity,as a result,making the production of renewable fuels by HDO much more economically feasible,which is of much importance. | Qi Wang Neeraj Gupta Guodong Wen Sharifah Bee Abd Hamid Dang Sheng Su | 2017 | Journal of Energy Chemistry2017,26,1: | 1 |
| 5 | Aromatic sulfide, sulfoxide, and sulfone mediated mesoporous carbon monolith for use in supercapacitor显示文摘 | Xiaochen Zhao Qiang Zhang Cheng-Meng Chen Bingsen Zhang Sylvia Reiche Aiqin Wang Tao Zhang Robert Schl?gl Dang Sheng Su | 2012 | Nano Energy2012,,4: | 1 |
| 6 | Surface-Modified Carbon Nanotubes Catalyze Oxidative Dehydrogenation of n-Butane显示文摘 | Jian Zhang Xi Liu Raoul Blume Aihua Zhang Robert SchliSgl Dang Sheng Su | 2008 | Science2008,322,5898: | 1 |
| 7 | Oxidative dehydrogenation of 9,10-dihydroanthracene using multi-walled carbon nanotubes显示文摘 | Dominique Bégin Gilles Ulrich Julien Amadou Dang Sheng Su Cuong Pham-Huu Raymond Ziessel | 2008 | Journal of Molecular Catalysis A Chemical2008,,1: | 1 |
| 8 | Oxidative dehydrogenation of 1-butene to butadiene over carbon nanotube catalysts显示文摘 | Xi Liu Dang Sheng Su Robert Schl?gl | 2007 | Carbon2007,,3: | 1 |
| 9 | Metal-Free Heterogeneous Catalysis for Sustainable Chemistry显示文摘 | Su Dang Sheng Zhang Jian Frank Benjamin et at | 2010 | ChemSusChem2010,,3: | 1 |
| 10 | Preface to Special Issue on Carbon Materials for Energy Application显示文摘The rising cost and limited availability of fossil fuels, and the increasing concerns related to their role on global pollution and greenhouse effect have pushed considerably the need to accelerate the transition to a more sustainable use of energy | Dang Sheng Su Gabriele Centi | 2013 | Journal of Energy Chemistry2013,22,2: | 0 |
| 11 | Reinforcing epoxy resin with nitrogen doped carbon nanotube:A potential lightweight structure material显示文摘The outstanding mechanical properties of nanocarbon materials, especially carbon nanotube(CNT), make them one of the most promising reinforcing nanofillers for the high-performance lightweight structural material. However, the complicated but not eco-friendly surface functionalization processes(e.g. HNO_3 oxidation) are generally necessary to help disperse nanocarbon materials into epoxy or build chemical bonds between them. Herein, nitrogen doped carbon nanotube(NCNT) was used to replace CNT to reinforce the epoxy resin, and the mechanical properties of the NCNT/epoxy nanocomposite showed significant superiorities over the CNT/epoxy nanocomposites. The fabrication process was simple and environmentally friendly, and avoided complicated, polluting and energy intensive surface functionalization processes. Moreover, the NCNT/epoxy suspension exhibited a relative low viscosity, which was favorable for the subsequent application. The reinforcing mechanism of NCNT was also proposed. The present work gives out an easy solution to the preparation of a high-performance nanocomposite as a potential lightweight structure material. | Qi Wang Guodong Wen Junnan Chen Dang Sheng Su | 2018 | Journal of Materials Science & Technology2018,34,11: | 0 |