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| 1 | 磷酸盐玻璃固化体化学耐蚀性研究显示文摘以在美国Washington州Hanford市存放的17类不同组成的高放射性核废料(highlevelradioactivenuclearwaste,HLW)为研究对象,设计了含Cr2O3为4%(质量分数,下同)的模拟HLW。采用25%~35%磷酸盐与含Cr2O3的65%~75%的HLW模拟组成相混合,经1150~1250℃加热处理数小时,能熔化成为均质玻璃体,然后冷却成固化体。用试样坚固法(productconsistencytest,PCT)测试包容70%和75%HLW的2种玻璃固化体的各元素,在90℃放置7d,元素沥析量总和分别为小于1.5g/m2和2.0g/m2。用蒸汽水化侵蚀法(vaporhydrationtest,VHT)对此2种试样在200℃的水蒸汽中进行水化侵蚀,经7d处理,平均被侵蚀的速率分别小于0.2g/(m2·d)和3.5g/(m2·d)。晶化处理后的此2种试样的PCT和VHT测试结果与晶化前基本相近。对HLW不同包容量的玻璃固化体的红外光谱分析表明:在较高的HLW包容量的玻璃固化体的结构中,容易被水化的(PO3)-结构转化为分离的(P2O7)4-或(PO4)3-。X射线衍射分析表明:玻璃固化体中分离的(P2O7)4-和(PO4)3-阴离子团被金属离子Al3+,Fe3+,Cr3+和Zr4+等所连接,形成O—Me—O—P键,不仅提高了玻璃的抗析晶的能力,而且也大大地提高了其化学稳定性。样品O/(Si+P)的摩尔比为3.7~4.1,从结构上也表明核废料包容量高达70%~75%的玻璃固化体有优良的? | 黄文旵 周萘 DAY D E RAY C S | 2004 | 硅酸盐学报2004，32，4： | 6 |
| 2 | Synthesis, Crystal Structure and Calculated β Value of a Tetrahedral Zinc (II) Complex——Zn(2-NH_2py)_2Br_2显示文摘A new zinc(II) complex, Zn(2-NH2py)2Br2 (py=pyridine), has been synthesized, and its molecular structure has been confirmed by IR, elemental analysis and -ray crystal structure analysis. Its space group is P21/n with Mr=413.43 (C10H12Br2N4Zn), a=7.435(2), b=12.865(3), c=14.186(4)? b=94.08(2)? V=1353.5(5) 3, Z=4, Dc=2.029 g/cm3, F(000)=328, ?2.378mm-1, R=0.0283, wR=0.0501. The total observed reflections with I≥2?I) were 5314, of which the independent reflections were 3106. The complex structure contains a distorted tetrahedron formed by four atoms coordinated to zinc atom, namely two bromide atoms and two nitrogen atoms. The two ZnBr bond lengths within one molecule, 2.3763(6) and 2.4002(5)? respectively, are not equal; and so are the two ZnN bond lengths, which are 2.031(2) and 2.044(2)?respectively. The calculation results using PM3 method through MOPAC software package in Chem 3D show that its first molecular hyperpolarizability b value is 5.210-30esu, which is comparable with that of p-nitroaniline. No bulk SHG effect has been detected due to the centrosymmetric space group. | REN Peng a SU Nan-Bing a QIN Jin-Gui a Michael W. Day b CHEN Chuang-Tianc ( aDepartment of Chemistry, Wuhan University, Wuhan 43007, China) ( bBeckman Institute, California Institute of Technology, Pasadena, CA91125, USAQ ) ( cBeijing R & D Center | 2002 | Chinese Journal of Structural Chemistry2002，21，1： | 3 |
| 3 | The relationship between career motivation and self-efficacy with protégé career success显示文摘 | Rachel Day Tammy D Allen | 2003 | Journal of Vocational Behavior2003，，1： | 2 |
| 4 | Macrorules for Summarizing Text: The Development of Expertise显示文摘 | Brown A L Day J D | 1983 | Journal of Verbal Learning and Verbal Behavior1983，22，1： | 1 |
| 5 | Oxidation protection for carbon fiber composites 显示文摘 | Westwood M E Webster J D Day R J | 1996 | Material Science1996，31，6： | 1 |
| 6 | Complete genomes of two clinical Staphylococcus aureus strains:evidence for the rapid evolution of virulence and drug resistance显示文摘 | Holden MT Feil EJ Lindsay JA Peacock SJ Day NP Enright MC Foster TJ Moore CE Hurst L Atkin R Barron A Bason N Bentley SD Chillingworth C Chillingworth T Churcher C Clark L Corton C Cronin A Doggett J Dowd L Feltwell T Hance Z Harris B Hauser H Holroyd S Jagels K James KD Lennard N Line A Mayes R Moule S Mungall K Ormond D Quail MA Rabbinowitsch E Rutherford K Sanders M Sharp S Simmonds M Stevens K Whitehead S Barrell BG Spratt BG Parkhill J | 2004 | Proc Natl Acad Sci USA2004，101，26： | 1 |
| 7 | The response of tropospheric circulation to perturbations in lower-stratospheric temperature显示文摘 | HAIGH J D BLACKBURN M DAY R | 2005 | J Clim2005，18，17： | 1 |
| 8 | Maternal care,hippocampal synaptogenesis and cognitive development in rats显示文摘 | Liu D Diorio J Day JC | 2000 | Nat Neurosci2000，3，8： | 1 |
| 9 | A Double Blind,Randomized,Multicenter,Parallel Group Stydy of the Effectiveness and Tolerance of Intraarticular Hyaluronam in Osteoarthritis of the Knee显示文摘 | DAY d BROOKS P CONAGHAN P G | 2004 | J Rheumatol2004，31，4： | 1 |
| 10 | Methylmercury photodegradation influenced by sea-ice cover in arctic marine eco- systems显示文摘 | Point D Sonke J E Day R D | 2011 | Nature Geoscience2011，4，3： | 1 |
| 11 | Phenotypic and genotypic diversity in Phytophthora infestans on potato in Great Britain, 1995-1998 显示文摘 | DAY J P WA271'IER R SHAW D S | 2004 | Plant Pathol2004，53，3： | 1 |
| 12 | Direct,facile synthesis of acyo azides and nitriles from carboxylic acids using bis(2-methoxyethyl)aminosulfur trifluoride显示文摘 | Kangani CO Day B W Kelley D E | 2007 | Tetrahedron Lett2007，48，： | 1 |
| 13 | Improved survival with ipilimumab in patients with metastatic melanoma显示文摘 | HODI F S O'DAY S J MCDERMOTT D F | | 0，，08： | 1 |
| 14 | Ultrasound imaging in the management of bleeding and pain in early pregnancy 显示文摘 | Knez J Day A Jurkovic D | 2014 | Best Practice & Research Clinical Obstetrics & Gynaecology2014，28，5： | 1 |
| 15 | Ultrasound imaging in the management of bleeding and pain in early pregnancy显示文摘 | Knez J Day A Jurkovic D | 2014 | Best Pract Res Clin Obstet Gynaecol2014，28，5： | 1 |
| 16 | Transgene in- tegration into the same chromosome location can produce alleles that express at a predictable level, or alleles that are differentially silenced 显示文摘 | DAY C D LEE E KOBAYASHI J | 2000 | Genes Dev2000，14，22： | 1 |
| 17 | Meta - analytic Review of Leader - member Exchange Theory: Correlates and Construct Issues 显示文摘 | Gerstner C R Day D V | 1997 | Journal of Applied Psychology1997，82，： | 1 |
| 18 | Human a-defensins block papillornavirus infection 显示文摘 | Christopher B Buck Patricia M Day Cynthia D Thompson | 2006 | PNAS2006，103，5： | 1 |
| 19 | A novel medium throughput quantitative competitive PCR technology to simultaneously measure mRNA levels from multiple genes显示文摘 | Junlong Z Ian N M Day and Christopher D B | 2002 | Nucleic Acids Research2002，30，5： | 1 |
| 20 | Microanatomical study of the extradural middle fossa approach to the petroclival and posterior cavernous sinus region: description constnwt 显示文摘 | Day J D Fukushima T Giannotla S L | 1994 | Neurosurgery1994，34，6： | 1 |
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