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| 1 | 硫酸溶液中1,1′-硫代羰基二咪唑在碳钢上的吸附及缓蚀影响和碘离子的增强效应(英文)显示文摘The inhibition effect of 1,1′-thiocarbonyldiimidazole (TCDI) on the corrosion behaviors of mild steel (MS) in 0.5 mol·L-1 H2SO4 solution was studied with the help of potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and linear polarization resistance (LPR) techniques. The effect of immersion time on the inhibition effect of TCDI was also investigated over 72 h. For the long-term tests, hydrogen evolution with immersion time (VH2-t) was measured in addition to the three techniques already mentioned. The thermodynamic parameters, such as adsorption equilibrium constant (Kads) and adsorption free energy (△Gads) values, were calculated and discussed. To clarify inhibition mechanism, the synergistic effect of iodide ion was also investigated. The potential of zero charge (PZC) of the MS was studied by electrochemical impedance spectroscopy method, and a mechanism of adsorption process was proposed. It was demonstrated that inhibition efficiency increased with the increase in TCDI concentration and synergistically increased in the presence of KI. The inhibition efficiency was discussed in terms of adsorption of inhibitor molecules on the metal surface and protective film formation. | SOLMAZ R MERT M. E KARDA■ G YAZICI B ERBL M | 2008 | 物理化学学报2008，24，7： | 4 |
| 2 | Grain boundary character distribution and intergranular corrosion behavior in high purity aluminum显示文摘 | S.H Kim U Erb K.T Aust G Palumbo | 2001 | Scripta Materialia2001，，5： | 2 |
| 3 | Interface control for resistance to intergranular cracking 显示文摘 | Aust K T Erb U Palumbo G | 1994 | Mater Sci Eng A1994，176，12： | 1 |
| 4 | The effect of starting nanostructure on the thermal stability of electrodeposited nanocrystalline Co 显示文摘 | HIBBARD G D AUST K T ERB U | 2006 | Acta Materialia2006，54，9： | 1 |
| 5 | Practical applications for electrodeposited nanocrystalline materials 显示文摘 | Robertson A Erb U Palumbo G | 1999 | Nanostruct Mater1999，12，5： | 1 |
| 6 | Oscillation of discrete analogue of delay equations显示文摘 | B G Zhang | 1989 | Differential Integral Equations1989，，2： | 1 |
| 7 | Influence of grain boundary character distribution on sensitization and intergranular corrosion显示文摘 | LIN P PALUMBO G ERB U | 1995 | Scr Metall Mater1995，33，： | 1 |
| 8 | Kamenev type theorems for second order matrix differential systems显示文摘 | ERBE L H KONG Q K RUAN S G | 1993 | Proc Amer Math Soc1993，117，： | 1 |
| 9 | Influence of grain boundary character distribution on sensitization and intergranular corrosion of alloy 600 显示文摘 | Lin P Palumbo G Erb U | 1995 | Scripta Metal Mater1995，33，9： | 1 |
| 10 | Practical application for electrodeposited nanocrystalline materials显示文摘 | Robertson A Erb U Palumbo G | 1999 | Nanostructured Materials1999，12，58： | 1 |
| 11 | The role of lipololysaecharides in induction of plant defenee responses显示文摘 | Erbs G Newman M A | 2003 | Molecular Plant Pathology2003，4，5： | 1 |
| 12 | Synthesis, structure and properties of electroplated nanocrystalline materials显示文摘 | Erb U Elsherik A M Palumbo G | 1993 | Nanostr Mater1993，2，4： | 1 |
| 13 | Effects of grain boundary structure on carbide precipitation in 304L stainless steel显示文摘 | Zhou Y Aust K T Erb U Palumbo G | 2001 | Scripta Materialia2001，45，1： | 1 |
| 14 | The role of lipopolysaccharides in induction of plant defence responds显示文摘 | Erbs G Newman | 2003 | Mol Plant Pathol2003，4，： | 1 |
| 15 | The role of Th2type CD4+T cells and Th2type CD8+T cells in asthma显示文摘 | ERB K J LE GROS G | 1996 | Immunol Cell Biol1996，74，： | 1 |
| 16 | Comparison of a new bisphenol-a-glycidyl-dimethacrylate-based cortical bone void lIer with polymethyl methacrylate 显示文摘 | Erbe E Clineff T Gualltieri G | 2001 | Eur Spine2001，10，2： | 1 |
| 17 | Influence of gain boundary character distribution on sensitization and intergranular corrosion of alloy 600显示文摘 | LIN P PALUMBO G ERB U AUST K T | 1995 | Scr Metall Mater1995，33，9： | 1 |
| 18 | Influence of grain boundary character distribution on sensitization and intergranular corrosion of alloy 600 显示文摘 | Lin P Palumbo G Erb U | 1995 | Scripta Metall Mater1995，33，： | 1 |
| 19 | Canada's mobile servicing system 显示文摘 | | 1990 | Space Technology1990，10，1： | 1 |
| 20 | Accuracy of gamma-variate fits to concerntration-time curves from dynamic susceptibility-contrast enhanced MRI:influence of time resolution,maximal signal drop and signal-to-noise显示文摘 | Benner A Heiland S Erb G | 1997 | Magn Reson Imaging1997，15，： | 1 |
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