|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Fe-based metallic glass:An efficient and energy-saving electrode material for electrocatalytic degradation of water contaminants显示文摘Excessive consumption of electrical energy has hampered the widespread application of electrochemical technology for degradation of various contaminants. In this paper, a Fe-based metallic glass(MG) was demonstrated as a new type of electrocatalyst to effectively and economically degrade an azo dye. In comparison to other typical electrodes, Fe-based MG electrodes exhibit a minimized degradation time, and the specific energy is 4-6 orders of magnitude lower than that of dimensionally stable anode(DSA), metal-like boron-doped diamond(BDD) and other electrodes. As sacrificial electrode materials, Fe-based MGs have less specific electrode mass consumption than iron electrodes. The use of Fe-based MGs will promote the practical application of electrochemical technology and the use of MGs as functional materials. | Xindong Qin Zhengkun Li Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2018 | Journal of Materials Science & Technology2018，34，12： | 3 |
| 2 | Self‐suspended rare‐earth doped up‐conversion luminescent waveguide:propagating and directional radiation显示文摘Near-infrared excited rare-earth(RE)-doped up-conversion(UC)-luminescent materials have attracted enormous attention because of their unique emission properties,such as narrow emission bands,long luminescence lifetimes,and multiple colors.However,current development of RE-doped luminescent material is hindered by weak and narrowband absorption problems and low photon-conversion quantum efficiencies.In addition to conventional approaches to enhance fluorescence intensity,controlling emission directivity to improve detection efficiency has become a promising approach to obtain higher luminescence brightnesses.In this paper,a self-suspended RE-doped UC luminescent waveguide is designed to realize directional emissions.Benefitting from the special morphology of the crown-like NaYF4:Yb3+/Er3+microparticle,the points contact between the waveguide and substrate can be obtained to decrease energy loss.An attractive UC luminescent pattern accompanied by powerful and controllable directional emissions is observed,and the spatial emission angle and intensity distribution are explored and analyzed in detail by introducing Fourier imaging detection and simulation.This work provides a new method for achieving controllable directional fluorescence emissions and obtaining improved detection efficiency by narrowing emission directivity,which has potential applications in 3-dimensional displays and micro-optoelectronic devices,especially when fabricating self-fluorescence micron lasers. | Changjian Zhang Chengyun Zhang Zhenglong Zhang Tao He Xiaohu Mi Ting Kong Zhengkun Fu Hairong Zheng Hongxing Xu | 2020 | Opto-Electronic Advances2020，3，6： | 3 |
| 3 | Correlation Between Dynamic Compressive Strength and Fracture Behaviors of Bulk Metallic Glasses显示文摘The mechanical behaviors of Zr43.5Cu43.5Ni4Al8Nb1,Zr55.4Cu31.6Ni4Al8Nb1,Ti32.8Zr30.2Ni5.3Cu9Be22.7(at.%)metallic glass at different strain rates were studied.For all the present alloys,the dispersion over 700 MPa was observed on the strength in the repeated dynamic compressions,which was much stronger than that of the quasi-static compressive strength.Such the dispersion of the dynamic compressive strength was well correlated with the corresponding fracture behaviors.The area of fracture surface was calculated and also showed a strong dispersion for all the fractured specimens tested at the strain rate of 500 s^-1 and 1000 s^-1.All the specimens showed a linear relationship between the square of dynamic compressive strength and the area of fracture surface in the dynamic compression tests.This phenomenon was mainly thought to be related to the difference of mean initial free volume concentration of different samples,stress concentration caused by the split Hopkinson pressure bar experimental setup and high sensitivity of defects under dynamic deformation.These findings were beneficial to deeply understand the effect of strain rate on the mechanical properties of the metallic glass. | Wenqing Li Zhengwang Zhu Guojie Li Long Zhang Zhengkun Li Huameng Fu Hongwei Zhang Hong Li Aimin Wang Haifeng Zhang | 2020 | Acta Metallurgica Sinica(English Letters)2020，33，10： | 2 |
| 4 | Co_(78)Si_(8)B_(14)metallic glass:A highly efficient and ultra-sustainable Fenton-like catalyst in degrading wastewater under universal pH conditions显示文摘Overcoming the pH limitation and increasing the catalyst reusability remain pressing demands for metal-lic glass(MG)in wastewater remediation.Herein,Co_(78)Si_(8)B_(14)MG ribbons are used to degrade dye wastew-ater by activating hydrogen peroxide(H_(2)O_(2))as Fenton-like catalysts.The Co-based MG catalysts exhibit high degradation efficiency under both acidic and alkaline conditions,and the kinetic reaction rate at pH 10(0.176 min^(−1)) and pH 4(0.089 min^(−1)) is 5.9 and 1.2 times higher than that of the extensively studied Fe-based MG catalysts,respectively.Impressively,the Co-based MG catalysts can be reused up to 20-60 times at universal pH conditions,demonstrating fairly good reusability.The newly discovered Co-based MG catalysts do not follow the classical Fenton reactions with H_(2)O^(2) the way Fe-based MGs do.In an acid environment,hydroxyl radicals play a dominant role in the degradation,while in an alkaline environ-ment,the effect of hydroxyl radicals is weakened,and Co^(3+) ions exert a relatively major function on the degradation.The excellent performance in catalytic activity and reusability at universal pH conditions of the Co-based MGs will inspire the development of MGs in wastewater treatment. | Xindong Qin Jiliang Xu Zhengwang Zhu Zhengkun Li Dawei Fang Huameng Fu Shiming Zhang Haifeng Zhang | 2022 | Journal of Materials Science & Technology2022，，18： | 2 |
| 5 | Mechanism and kinetics of treatment of acid orange II by aged Fe-Si-B metallic glass powders显示文摘The mechanism and kinetics of acid orange II(AOII) treated by aged gas-atomized Fe-Si-B metallic glass(MG) powders were investigated in this study. The decolorization reaction is shown to obey the pseudofirst-order kinetic model, and the treatment processes could be divided into two stages: a slow step followed by a rapid one. This observation is in accordance with the following results, the azo dye is simply adsorbed onto the Fe-based MG powders in the initial stage, because the oxide layer coated on the powder surface depresses the degradation reaction by covering the activity sites, and then the degradation occurs with the desquamation of the powders. The AOII could be degraded with a rapid reaction rate when the Fe-based MG powders are applied to the treatment process again, because of the consumption of the oxide layer and the unchanged core of the Fe-based MGs. These findings will promote the practical application of MGs in degrading azo dyes. | Xindong Qin Zhengkun Li Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2017 | Journal of Materials Science & Technology2017，33，10： | 2 |
| 6 | Corrosion mechanisms of Zr-based bulk metallic glass in NaF and NaCl solutions显示文摘So far,some investigations related to the corrosion mechanism of Zr-based metallic glasses in solutions containing Cl-have been developed.However,few attentions have been paid to the situation in F--containing solution.This paper describes the corrosion behaviours of Zr52Al10Ni6Cu32 bulk metallic glass(BMG)in Na F and Na Cl aqueous solutions.The corrosion mechanism of Zr-based BMG in F–containing solution was proposed for the first time.It was found that in Na Cl solutions,Zr-based BMG samples underwent typical pitting corrosion.Selective dissolution of Zr,Al and enrichment of Cu were observed in corrosion pits.However,corrosion occurred in the form of general breakdown of passive film in Na F solutions.Such difference is interpreted in terms of the binding ability of anions to surrounding molecules,i.e.,Cl-with loose surrounding water passes through the passive film to cause pitting;F-with a tight surrounding molecules layer absorbs on passive film then coordinates with cations from matrix. | Zhangweijia Qiu Zhengkun Li Huameng Fu Hongwei Zhang Zhengwang Zhu Aimin Wang Hong Li Long Zhang Haifeng Zhang | 2020 | Journal of Materials Science & Technology2020，42，11： | 1 |
| 7 | Spin-orbit coupled degenerate fermi gases显示文摘 | Wang Pengjun Yu Zengqiang Fu Zhengkun | | 0，，： | 1 |
| 8 | Spin-orbit coupled degenerate Fermi gases 显示文摘 | Wang Pengjun Yu Zengqiang Fu Zhengkun | 2012 | Physical Review Letters2012，109，09： | 1 |
| 9 | Spinorbit coupled degenerate Fermi gases显示文摘 | Wang Pengjun Yu Zengqiang Fu Zhengkun | 2012 | Physical Review Letters2012，109，9： | 1 |
| 10 | High-temperature Mechanical Properties and Dynamic Recrystallization Mechanism of in situ Silicide-reinforced MoNbTaTiVSi Refractory High-entropy Alloy Composite显示文摘The hypoeutectic composite material composed of BCC phase and in situ precipitated Ti_(5)Si_(3) was prepared by adding Si into MoNbTaTiV high-entropy alloy.The obvious oriented in situ Ti_(5)Si_(3) phase formed eutectic phase with BCC phase in the inter-dendritic area,which leads to excellent properties of the composite.The alloy exhibits ultra-high yield stress of 718 MPa at 1200℃ and obvious compression plasticity.After reaching the maximum strength,dynamic recovery(DRV)and dynamic recrystallization(DRX)caused soften phenomena.The DRX mechanism of the dual-phase eutectic structure is analyzed by electron backscatter diffraction.The DRX of the BCC phase conforms to the discontinuous DRX and continuous DRX mechanisms,while the Ti_(5)Si_(3) phase has a geometric DRX mechanism in addition to the above two mechanisms.The high performance of this composite has enough potential high-temperature applications such as nuclear and aero engine. | Shaofan Ge Shifeng Lin Huameng Fu Long Zhang Tieqiang Geng Zhengwang Zhu Zhengkun Li Hong Li Aimin Wang Hongwei Zhang Haifeng Zhang | 2022 | Acta Metallurgica Sinica(English Letters)2022，35，10： | 1 |
| 11 | Preparation,Performance and Slag Resistant Mechanism of Low Thermal Conductivity Microporous Corundum显示文摘The microporous corundum material was prepared using alumina micro-powder as the main raw material,alumina sol and starch as binders by a wet process,achieving the bulk density of 3. 05 g·cm^(-3),the apparent porosity of 9. 1%,the closed porosity of 12. 3%,the median pore diameter of 0. 43 μm,and the thermal conductivity of 6. 5 W·m^(-1)·K^(-1)at 800 ℃ which is41. 6% lower than that of common corundum. The slag resistance of the microporous corundum material was studied by immersion and compared with that of the common corundum aggregate, and the slag resistant mechanism of microporous corundum material was revealed. The results show that the slag resistance of the microporous corundum material is superior to that of the common corundum aggregate,the SEM and EDX show that on the reaction interface between microporous corundum and molten slag,a continuous isolation layer with a large quantity of CA_2 and CA_6columnar crystals is formed; while the common corundum aggregate reacts with the molten slag interface to form a discontinuous isolation layer of columnar crystals,through which a lot of molten slag corrodes or permeates into the aggregate. The mechanism is mainly that the microporous structure is more advantageous to nucleation and growth of CA_2 and CA_6 columnar crystals; in the reaction with the aggregate,the molten slag gets saturated and the critical solution thickness of the microporous corundum and the common corundum is 0. 16 μm and 0. 34 μm,respectively,this is caused by the smaller microporous corundum aggregate pores; and the smaller pores also increase the second phase ripening rate of microporous corundum,which is 9. 7 times of that of the common corundum. | FU Lyuping HUANG Ao GU Huazhi ZHANG Meijie LI Zhengkun ZHAO Yi | 2015 | China's Refractories2015，24，4： | 0 |
| 12 | Simultaneous enhancement of strength and ductility of body-centered cubic TiZrNb multi-principal element alloys via boron-doping显示文摘Body-centered cubic(BCC)multi-principal element alloys(MPEAs)have intrinsic high strength but poor ductility,which greatly limits their potential applications.Here we present the boron-doping strategy to enhance the strength and ductility of TiZrNb MPEAs simultaneously.The yield strength and ductility of the TiZrNb MPEA with boron addition of 500 ppm are increased by 19.0%and 48.7%compared to the boron-free TiZrNb MPEA,respectively.Boron-doping induced high efficiency in grain refinement from~96.0μm to~16.2μm is the main factor for strengthening.Dislocation dominated deformation mechanism involving cross slip and dislocation pining in the TiZrNb containing 500 ppm boron serves to enhance the strain-hardening capacity,resultant the enhancement of ductility from 7.8%to 11.6%.While the planar slip of dislocations is the dominated deformation mechanism for the boron-free TiZrNb. | Jingyu Pang Hongwei Zhang Long Zhang Zhengwang Zhu Huameng Fu Hong Li Aimin Wang Zhengkun Li Haifeng Zhang | 2021 | Journal of Materials Science & Technology2021，，19： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员