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| 1 | Synthesis and kinetics investigation of meso-microporous Cu-SAPO-34 catalysts for the selective catalytic reduction of NO with ammonia显示文摘A series of meso-microporous Cu-SAPO-34 catalysts were successfully synthesized by a one-pot hydrothermal crystallization method, and these catalysts exhibited excellent NH_3-SCR performance at low temperature. Their structure and physic chemical properties were characterized by means of X-ray diffraction patterns(XRD), Scanning electron microscopy(SEM), Transmission electron microscopy(TEM), N_2 sorption-desorption, nuclear magnetic resonance(NMR), Inductively Coupled Plasma-Atomic Emission spectrometer(ICP-AES), X-ray absorption spectroscopy(XPS),Temperature-programmed desorption of ammonia(NH_3-TPD), Ultraviolet visible diffuse reflectance spectroscopy(UV-Vis DRS) and Temperature programmed reduction(TPR).The analysis results indicate that the high activities of Cu-SAPO-34 catalysts could be attributed to the enhancement of redox property, the formation of mesopores and the more acid sites. Furthermore, the kinetic results verify that the formation of mesopores remarkably reduces diffusion resistance and then improves the accessibility of reactants to catalytically active sites. The 1.0-Cu-SAPO-34 catalyst exhibited the high NO conversion(> 90%) among the wide activity temperature window in the range of 150–425℃. | Jixing Liu Fuhong Yu Jian Liu Lifeng Cui Zhen Zhao Yuechang Wei Qianyao Sun | 2016 | Journal of Environmental Sciences2016，28，10： | 8 |
| 2 | How Do Variable Substitution Rates Influence Ka and Ks Calculations?显示文摘The ratio of nonsynonymous substitution rate (Ka) to synonymous substitution rate (Ks) is widely used as an indicator of selective pressure at sequence level among different species, and diverse mutation models have been incorporated into several computing methods. We have previously developed a new γ-MYN method by capturing a key dynamic evolution trait of DNA nucleotide sequences, in consideration of varying mutation rates across sites. We now report a further improvement of NG, LWL, MLWL, LPB, MLPB, and YN methods based on an introduction of gamma distribution to illustrate the variation of raw mutation rate over sites. The novelty comes in two ways: (1) we incorporate an optimal gamma distribution shape parameter a into γ-NG, γ-LWL, γ-MLWL, γ-LPB, γ-MLPB, and γ-YN methods; (2) we investigate how variable substitution rates affect the methods that adopt different models as well as the interplay among four evolutional features with respect to Ka/Ks computations. Our results suggest that variable substitution rates over sites under negative selection exhibit an opposite effect on ω estimates compared with those under positive selection. We believe that the sensitivity of our new methods has been improved than that of their original methods under diverse conditions and it is advantageous to introduce novel parameters for Ka/Ks computation. | Dapeng Wang Song Zhang Fuhong He Jiang Zhu Songnian Hu Jun Yu | 2009 | Genomics, Proteomics & Bioinformatics2009，7，3： | 2 |
| 3 | Rational construction of multiple hollow silicalite-1 zeolite with enhanced quasi acidity for robust vapor-phase Beckmann rearrangement显示文摘Developing efficient and stable zeolites for vapor-phase Beckmann rearrangement of cyclohexanone oxime is still a great challenge to realizeε-caprolactam(CPL)green production.In this work,the hierarchical porous silicalite-1 zeolites with multiple hollow structure(S-1-M)are explored by in-situ desilication−recrystallization post-treatment of spongy highway-like zeolites(S-1-S),which are synthesized through silanization synthesis of conventional bulky silicalite-1(S-1).Compared to S-1,S-1-M achieves superior catalytic performance,with improving the CPL selectivity from 85.7%to 94.1%and prolonging the catalyst lifetime from 74 to 126 h at a weight hourly space velocity(WHSV)of 6 h^(−1).Comprehensive physiochemical studies demonstrate that the highly dispersed intracrystalline cavities within S-1-M endow greater mass diffusion and better quasi acidity inducing by the enhanced H-bonds among abundant H-bonded silanols,which is cooperatively responsible for its superior catalytic performance. | Peng Zhang Xianfeng Yi Changjiu Xia Xinxin Peng Shuai Zhang Chengxiang Li Anmin Zheng Xiaoxin Zhang Yibin Luo Lifeng Cui Fuhong Yu Xingtian Shu | 2023 | Nano Research2023，16，5： | 1 |
| 4 | Genesis and significance of quartz cement in sandstones显示文摘Quartz cement as syntaxial overgrowths is one of the most abundant cements in sandstones. Distribution of quartz cement in time and space indicates that the more younger the stratigraphy is, the more smaller the amount of quartz cement, and the amount of quartz cement increases with increasing of depth and basin type also is a factor which controls the amount of quartz cement. The sources of silica for quartz cement have many different opinions, but there is one or more dominant sources. Temperature and pH of fluid are major factors which influence the precipitation of quartz cement. There exist three hypotheses on the flow of pore fluid and transport and precipitation of silica, that is, the hypothesis of cycle of shallow underground water, the hypothesis of high concentration of fluid driven by compaction and the hypothesis of diffusion and recycle of local fluid. The research of quartz cement is significant for the timing of paleotemperature, heterogeneity of reservoir, physical property of reservoir and the timing of oil immersion, etc. | Yu Junmin, Liu li, Gao Fuhong and Zou Haifeng (Changchun University of Science and Technology, Changchun 130026) Yang Yongchang, Sun Xiaoming and Zhang Liqin (Geology and Development Institute,Dagang Oil Field Group Ltd., Tianjin 300280) | 1999 | Global Geology1999，4，1： | 0 |
| 5 | The optimization research on the coupled of active and passive energy supplying in public institutions in China显示文摘The building sector is one of the largest energy user and carbon emitters globally.To increase the utilization rate of renewable energy and reduce carbon dioxide emissions,the optimal technical scheme of active public institutions and coupled utilization of renewable energy is studied.In this study,the energy consumption of three types of public institutions in various regions of China was simulated by using DeST building energy consumption software,combined with energy conversion efficiency and data released by the National Bureau of Statistics,and the total energy demand and total energy supply of public institutions were predicted using the load density method.Based on the coupling mechanism of the MARKAL model,the optimal proportion of renewable energy in the energy supply of public buildings in different regions is determined.Through the study of the number of public institutions in various regions of China,energy consumption characteristics,construction area,and other related data,the reverse energy flow method is creatively proposed,and the active and renewable energy coupling algorithm from the energy demand side of public institutions to the energy supply side is established.The results show that the central region has the highest utilization rate of renewable energy in the public sector,reaching 36.18%.The use of renewable energy in public buildings in hot summer and warm winter zones decreased to 35.08%,and it was 12.82% in cold zones.By 2025,the proportion of renewable energy resources in China is expected to reach 29.2%.The energy coupling model and algorithm constructed in this paper can provide a basis for the coupling macro configuration of renewable energy in public institutions in China. | Shui Yu Xueyan Liu Jianghui Yang Fuhong Han Jiashuai Wei | 2024 | Energy and Built Environment2024，5，2： | 0 |
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